Nissan Motor Company Limited

Nihon Parkerizing Co., Ltd.

Nippon Paint Compnay, Ltd.

Nippon Oil Fats Co., Ltd.

Shinto Paint Co., Ltd.

Katsuya Yamamoto

Tsuneo Sakauchi

Hitoshi Kimura

Hiroyuki Kishi

Yoshinobu Tamura

Masahide Nagaoka

Eisaku Nakatani

Shosaku Yamamoto

Masayuki Takemoto

Yoichi Masubuchi

Tsuneo Saito

Norifumi Hatano

Shinichi Inoue

Akihiko Hasebe

Akitoshi Shirasaka

Naoya Sakai

Michiaki Wake

Kazuyuki Oyama

Kenichi Fukuya

Nagaoka

Yasuyu Tsuchiya

Masaya Kawabata

Makoto Efumi

A colorless chromate coating film is formed on a bright aluminum wheel by subjecting the surface of an aluminum wheel to a cathodic electrolytic treatment in an acidic aqueous solution containing not less than 2 g/l of hexavalent chromium ions, 20 to 2,000 ppm of sulfate ions, 10 to 400 ppm of fluorine (F) as fluoride and not less than 20 ppm of zirconium ions at a pH of 0.6 to 1.7 at a current density of 0.5 to 15 A/dm.sup.2 for at least 30 seconds, thereby forming a coating film with a chromium coating amount of 50 to 250 mg/m.sup.2.

Process for forming colorless chromate coating film on bright aluminum

A phosphate treatment solution for composite structures which is here disclosed is characterized by containing 0.3-2.0 g/l of zinc ions, 0.3-4.0 g/l of nickel ions, 0.3-2.0 g/l of manganese ions, 3-10 g/l of sodium ions, 0.1-10 g/l of potassium ions, 5.0-25.0 g/l of phosphate ions, 0.1-20 g/l of total fluorine ions, 4.0 g/l or more of nitrate ions and 0.01-1.0 g/l of nitrite ions as main components, the aforesaid treatment solution having a pH of 2.0-3.5.

Phosphate treatment solution for composite structures and method for

A composite paint for an automotive outer panel comprises an electrodeposition paint film coated on the surface of a steel sheet. The electrodeposition paint film has a minimum melt viscosity not less than 0.2 during hardening and consists essentially of a water paint composition in an amount ranging from 50 to 85 parts by weight upon conversion to a solid content, and a partially cross-linked resin in an amount ranging from 15 to 50 parts by weight upon conversion to a solid content. Additionally, an intermediate paint film is coated on the electrodeposition paint film and has a hardening starting time ranging from 15 to 20 minutes.

Composite paint

A composite paint film coating formed on a steel sheet of an automotive vehicle body. The composite paint film coating is comprised of an electrodeposition paint film (I) coated on the steel sheet, and an intermediate paint film (II) coated on the first paint film. The electrodeposition paint film has a minimum melt viscosity not less than 0.2 during hardening. The electrodepositon paint film is formed of cathodic electrodeposition paint composition which includes a cationic thermosetting resin (1), and an already cross-linked particulate resin (2). The particlate resin is an addition-polymer formed between a fist compound (A) having at least two primary amino groups in a molecule, and a second compound (B) having at least two .alpha.,.beta.-ethylenic unsaturated groups. The particulate resin has an average particle size ranging from 0.01 to 1 .mu.m. The weight ratio ((2)/(1)) in solid content between the particulate resin (2) cationic thermosetting resin (1) is within a range from 0.03 to 0.15. The intermediate paint film (II) has hardening starting time ranging from 5 to 20 minutes.

Composite paint film coating

A paint film arrangement formed on an outer panel of an automotive vehicle. The paint film arrangement comprises a film of an electrodeposition paint formed on the surface of a steel plate of the automotive vehicle outer panel. The surface of the electrodeposition paint film has a center line average height Ra within a range of 0.3.mu..ltoreq.Ra.ltoreq.0.8.mu.. The total of values of power spectrum of the surface of the electrodeposition paint film is not more than 80 .mu.V.sup.2 within a wavelength range not more than 0.5 mm. Additionally, a film of an intermediate coat paint is formed on the surface of the electrodeposition paint film. The intermediate coat paint has a hardening starting time ranging from 15 to 20 minutes. The hardening starting time is determined according to a logarithmic decrement of the intermediate coat paint by an oscillated pendulum type viscoelasticity measuring device.

Paint film arrangement

A composite paint film formed on a steel sheet of an automotive vehicle body. The composite paint film comprises an electrodeposition paint film (I) coated on the steel sheet, and an intermediate coat paint film (II) coated on the first paint film. The electrodeposition paint film is formed of an epoxy-based cationic electrodeposition paint composition and has a minimum melt viscosity not less than 0.2 during hardening. The epoxy-based cationic electrodeposition paint composition includes an amine-added epoxy resin (1) of the type which may be hardened with a blocked isocyanate, a colloidal silica-containing gelled particulate (2), and an alkyltin ester compound of a liquid aliphatic carboxylic acid. The above-mentioned colloidal silica-containing gelled particulate is formed by dispersing a mixture of an acrylic copolymer having a hydrolizable alkoxysilane group and a cationic group and a cationic acidic colloidal silica in water to carry out a cross-linking reaction in particles of the colloidal silica. The second paint film (II) has a hardening starting time ranging from 15 to 20 minutes.

Composite paint film

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Yokohama, Japan

Katsuya Yamamoto