Kabushiki Kaisha Toyoda Jidoshokki Seisakusho

Katsushi Abe

Shinya Morishita

Hiroshi Kawase

Kenichi Suzuki

Shinichi Towata

Shin-ichi Towata

Kazuhiko Itoh

Shunsuke Yamakawa

Yutaka Ohya

Steam is contacted with a hydrogen absorbing alloy in a temperature range from 200.degree. C. to 400.degree. C. With a contact catalytic reaction of water, a metal contained in the hydrogen absorbing alloy is changed to an oxide or a hydroxide. Hydrogen produced causes the Ni compound to be reduced and thereby the Ni metal that is catalytically active is produced. Thus, the surface of the hydrogen absorbing alloy is activated. The steam is contained in an inert gas or a reductive gas. This treatment method is suitable as an activation treatment for a hydrogen absorbing alloy used as an active material of a negative electrode of a secondary battery.

Surface treatment method of hydrogen absorbing alloy

An electrode for a sealed nickel/metal hydride battery and a method of manufacturing the same, which is capable of suppressing a decrease in the charging reserve of a hydrogen-storage alloy electrode (negative electrode) and an increase in the internal pressure of the battery, is provided. The hydrogen-storage alloy electrode is formed using a tackifier or a binder which is prepared from an organic polymer material containing the ether linkage (--O--), for example, polyethylene oxide, polypropylene oxide , or polybutylene oxide. The specified material is suitably hydrophilic, and it exhibits an oxidation resistance which is much higher than that of a conventional material containing the hydroxyl group (--OH). Therefore, the specified material is especially resistant to oxidation and decomposition at the positive electrode of the battery and can significantly reduce the production of hydrogen attributed to the oxidation and decomposition.

Sealed

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Aichi-ken, Japan

Katsushi Abe