Panasonic Intellectual Property Management Co., Ltd.

Sanyo Electric Co., Ltd.

Panasonic Holdings Corporation

Toyota Jidosha Kabushiki Kaisha

Panasonic Energy Co., Ltd.

Katsunori Yanagida

Masanori Sugimori

Fumiharu Niina

Toshiyuki Nohma

Nobuhiro Hirano

Atsuhiro Funahashi

Atsushi Yanai

Yuki Morikawa

Yasunori Baba

Takashi Ko

Ikuo Yonezu

Kouhei Tsuzuki

Yoshinori Kida

Takeshi Maeda

Kouhei Tuduki

Akihiko Takada

Hirokazu Wada

Koji Nishio

Naoya Nakanishi

Masanobu Takeuchi

Natsumi Goto

Yoshito Chikano

Yo Kato

Masahisa Fujimoto

Harunari Shimamura

Takao Inoue

Kazunari Ohkita

Atsushi Fukui

Takeshi Ogasawara

Tetsuji Omura

Shinya Suzuki

Yoshiyuki Muraoka

Keisuke Ohara

Takanobu Chiga

Goro Fujita

Hideki Kitao

Takaaki Ikemachi

Naoto Onodera

Sho Tsuruta

Motoharu Saito

Junichi Sugaya

Manabu Takijiri

Yoshitaka Minamida

Atsushi Ogata

Denis Yau Wai Yu

Kaori Ishikawa

Sho Urata

Takuya Asari

Yuta Matsuo

Koh Masahara

Kohei Masai

Shinnosuke Ichikawa

In a nonaqueous electrolyte secondary battery, a separator includes a substrate, a first filler layer disposed on one side of the substrate and containing phosphate salt particles, and a second filler layer disposed on the other side of the substrate and containing inorganic particles. The separator is disposed between a positive electrode and a negative electrode in such a manner that the side of the substrate which bears the first filler layer is directed to the positive electrode side.

Nonaqueous electrolyte secondary battery including separator with filler layers on opposite sides of substrate

A negative electrode for a nonaqueous electrolyte secondary battery, said negative electrode comprising a negative-electrode current collector, and a negative-electrode active material layer provided upon the negative-electrode current collector, wherein the negative-electrode active material layer includes a negative-electrode active material and a styrene-butadiene rubber, and the glass transition temperature (Tg) of the styrene-butadiene rubber in an area that extends 10% in the thickness direction from the surface of the reverse side of the negative-electrode active material layer from the negative-electrode current collector is higher than that of the styrene-butadiene rubber in an area that extends 10% in the thickness direction from the surface of the negative-electrode current collector side of the negative-electrode active material layer.

Negative electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery

A positive electrode active material for nonaqueous electrolyte secondary batteries contains a lithium transition metal composite oxide that contains not less than 80% by mole of Ni relative to the total number of moles of metal elements other than Li; and Ti is present at least in the surfaces of particles of the composite oxide. With respect to this positive electrode active material, if particles having a volume-based particle diameter more than the 70% particle diameter (D70) are taken as first particles and particles having a volume-based particle diameter less than the 30% particle diameter (D30) are taken as second particles, the molar fraction (A2) of Ti relative to the total number of moles of metal elements in the surfaces of the second particles is higher than the molar fraction (A1) of Ti relative to the total number of moles of metal elements in the surfaces of the first particles.

Positive electrode active material for nonaqueous electrolyte secondary batteries, and nonaqueous electrolyte secondary battery

A separator for use in a non-aqueous electrolyte secondary battery according to the present invention comprises a porous substrate and a filler layer disposed upon the substrate. The filler layer includes phosphate particles and a reticulated polyvinylidene fluoride resin. The filler layer has a polyvinylidene fluoride resin content of 15 mass % to 40 mass %, inclusive. The D10 particle size (D) of the phosphate particles on a volume basis is 0.02 μm to 0.5 μm, inclusive, and is smaller than the average pore size of the pores in the substrate. The BET specific surface area of the phosphate particlesis 5 m/g to 100 m/g, inclusive.

Non-aqueous electrolyte secondary battery

This non-aqueous electrolyte secondary battery comprises a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode. The separator includes; a porous base material; a first filler layer which contains phosphate particles as a primary component and is arranged on one surface of the base material; and a second filler layer which is arranged on the other surface of the base material and which contains at least one type of compound selected from the group consisting of an aromatic polyamide, an aromatic polyimide and an aromatic polyamideimide. The BET specific surface area of the phosphate particles is 5-100 m/g. The content of the aforementioned compounds in the second filler layeris 15 mass % or more.

A negative electrode for a nonaqueous electrolyte secondary battery, said negative electrode comprising a negative-electrode current collector, and a negative-electrode active material layer provided upon the negative-electrode current collector, wherein the negative-electrode active material layer includes a negative-electrode active material and carboxymethyl cellulose, wherein the molecular weight of the carboxymethyl cellulose in an area that extends 10% in the thickness direction from the surface of the negative-electrode current collector side of the negative-electrode active material layer is smaller than that of the carboxymethyl cellulose in an area that extends 10% in the thickness direction from the surface of the reverse side of the negative-electrode active material layer from the negative-electrode current collector.

A negative electrode for a nonaqueous electrolyte secondary battery, said negative electrode comprising a negative-electrode current collector, and a negative-electrode active material layer provided upon the negative-electrode current collector, wherein the negative-electrode active material layer includes a negative-electrode active material and polyvinylpyrrolidone, and an area that extends 10% in the thickness direction from the surface of the reverse side of the negative-electrode active material layer from the negative-electrode current collector has a higher polyvinylpyrrolidone content than an area that extends 10% in the thickness direction from the surface of the negative-electrode current collector side of the negative-electrode active material layer.

In a nonaqueous electrolyte secondary battery a separator includes a porous substrate, a first filler layer, and a second filler layer. The first filler layer comprises phosphate particles having a BET specific surface area of 5 to 100 m/g and polyvinylidene fluoride and is formed on a first surface that faces the positive electrode side of the substrate and contacts the positive electrode. The second filler comprises inorganic particles which have a melting point higher than that of the phosphate particles and is formed on at least one of a second surface that faces the negative electrode side of the substrate and the area between the substrate and the first filler layer. The content of the polyvinylidene fluoride in the first filler layer is 10 to 50 mass % and is higher in a region on the positive electrode side than in a region on the substrate side.

Nonaqueous electrolyte secondary battery

A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The separator has a multilayer structure in which a first filler layer containing phosphate particles, a porous resin substrate, and a second filler layer containing inorganic particles having higher heat resistance than the phosphate particles are stacked in this order from the negative electrode side. The first filler layer is disposed on the porous resin substrate in such a manner that the surface of the first filler layer faces the surface of the negative electrode. The phosphate particles have a BET specific surface area in the range of 5 m/g or more and 100 m/g or less.

Non-aqueous electrolyte secondary battery having separator with multilayer structure

In a nonaqueous electrolyte secondary battery, a negative electrode mix layer includes a first layer and a second layer disposed successively from a negative electrode collector. The first layer contains a first carbon-based active material having a 10% compressive strength of 3 MPa or less and a silicon-based active material containing Si. The second layer contains a second carbon-based active material having a 10% compressive strength of 5 MPa or more and has a lower content (mass ratio) of the silicon-based active material than the first layer.

Negative electrode including first layer having low compressive strength carbon active material and silicon active material and second layer having high compressive strength carbon active material and nonaqueous electrolyte secondary battery including the same

The present disclosure relates to a secondary battery module including a nonaqueous electrolyte secondary battery and an elastic body. The elastic body has a compressive elastic modulus of 5 MPa to 120 MPa. The nonaqueous electrolyte secondary battery includes a positive electrode and a negative electrode. The positive electrode includes a positive electrode collector containing Ti as a main component and having a thickness of 1 &#x3bc;m to 8 &#x3bc;m. The negative electrode includes a first layer and a second layer sequentially formed from a side with the negative electrode collector. The first layer contains negative electrode active material particles containing first carbon-based active material particles with a 10% proof stress of 3 MPa or less. The second layer contains negative electrode active material particles containing second carbon-based active material particles with a 10% proof stress of 5 MPa or greater.

Nonaqueous electrolyte secondary battery and secondary battery module

An advantage of the present invention is to suppress an increase in resistance during high-rate charge and discharge and a reduction in capacity during a charge and discharge cycle. An electrical storage module of the present embodiment includes: an electrical storage device, and an elastic body that is placed with the electrical storage device and receives a load from the electrical storage device in a placement direction. The electrical storage device includes a positive electrode, a negative electrode, and a separator. The negative electrode includes a negative-electrode active material layer. The negative-electrode active material layer includes a first layer formed on the negative-electrode current collector, and a second layer that is formed on the first layer and has a higher compression modulus than the first layer. The separator has a lower compression modulus than the first layer, and the elastic body has a lower compression modulus than the separator.

Electrical storage device and electrical storage module

In a non-aqueous electrolyte secondary battery according to one exemplary embodiment, a separator includes a substrate, a first filler layer containing phosphate particles and formed on at least one surface of the substrate, and a second filler layer containing inorganic particles and formed on a surface of the first filler layer on the side of the at least one surface of the substrate. The phosphate particles have a BET specific surface area of 5 m/g or more and 100 m/g or less.

This negative electrode comprises an electrode current collector, and an electrode mixture layer provided on a surface of the electrode current collector. When, with respect to the thickness direction of the electrode mixture layer, a range from the surface on the side of the electrode current collector to 40% of the thickness of the electrode mixture layer is defined as a first region, and a range from the surface on the side opposite to the electrode current collector to 40% of the thickness of the electrode mixture layer is defined as a second region, the first region and the second region have different volume change ratio upon charge and discharge, and the region having the larger volume change ratio upon charge and discharge has a higher content of a solid inorganic filler and a lower content of a hollow inorganic filler than the region having the smaller volume change ratio.

Negative electrode for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery

In a nonaqueous electrolyte secondary battery, a separator includes a substrate, a first filler layer containing phosphate salt particles, and a second filler layer interposed between the substrate and the first filler layer and containing inorganic particles. The separator is disposed between a positive electrode and a negative electrode in such a manner that the first filler layer and the second filler layer are directed to the positive electrode side. Further, a resin layer is disposed between the positive electrode and the first filler layer.

Nonaqueous electrolyte secondary battery including separator having substrate, phosphate salt layer, inorganic particle layer, and resin layer between separator and positive electrode

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Hyogo, Japan

Katsunori Yanagida