Hoya Corporation

Katsuhisa Itoh

Hisayoshi Toratani

Hiroaki Yanagita

Hiromasa Tawarayama

Etsuko Hayashi

Akiyoshi Tanaka

In a laser device and a light signal amplifying device with an optical fiber containing a laser activating substance in the inside for emitting a light beam from the end part in the case the laser activating substance is excited, fixed in a dense state at least partially by an optical medium, a polysilsesquioxane including a repeating unit represented by a general formula RSiO (wherein R represents an alkyl group, a hydroxyl group, a phenyl group, a vinyl group, a 2-chloroethyl group, a 2-bromoethyl group, a hydrogen, a heavy hydrogen, a fluorine, or an oxygen. However, one having R entirely as an oxygen is excluded. Moreover, R may be different per each repeating unit.) is used as the optical medium.

Laser device and light signal amplifying device using the same

In a method of manufacturing an optical medium, an extended optical conductor containing active substance is formed to a predetermined shape by the use of resin by repeatedly folding or winding the optical conductor. A laser light beam or an amplified light beam is outputted from an edge portion of the optical conductor by absorbing an excitation light beam incident from the side surface of the optical conductor into the active substance through the resin. Thermoplastic resin is used as the resin. The thermoplastic resin transmits the excitation light beam. The resin is heated up to a glass transition temperature or higher. The optical conductor and the resin are bonded to each other so as to constitute a predetermined shape. The resin is cured.

Method of manufacturing optical medium

A method for manufacturing a glass preform from a metal sulfide chalcogenide glass to which a large amount of light emitting substances can be added includes steps of etching a surface made of the chalcogenide glass or oxychalcogenide glass of disc shape core and clad forming glass starting materials by an etchant including an acid and a compound reacting with a hydrogen chalcogenide, and forming the core forming glass starting material and the clad forming glass starting material into a united body serving as a glass preform. In a method for manufacturing a single-mode glass fiber using a preform method by drawing the glass preform whose outer round surface is made of a chalcogenide glass or oxychalcogenide glass, the outer round surface of the glass preform is etched using an etchant including an acid and a compound reacting with a hydrogen chalcogenide and then drawn into the glass fiber. In another method for manufacturing a glass fiber by drawing a rod-in-tube in which an outer round surface of the rod and inner and outer round surfaces of the tube are made of a chalcogenide glass or oxychalcogenide glass, the round surfaces made of the chalcogenide glass or oxychalcogenide glass are etched by the etchant including an acid and a compound reacting with a hydrogen chalcogenide and then drawn into the glass fiber.

Method for manufacturing glass preform and glass fiber

An etchant for chalcogenide glass or oxychalcogenide glass contains an acid and a compound, e.g., an oxidizing agent, which reacts with hydrogen chalcogen to guarantee safe etching of sulfuric glasses in rendering the glass surface smooth and free from surface defects. The etchant is used for an etching method in which a member made of chalcogenide glass or oxychalcogenide glass is dipped in the prepared etchant. The member can make a glass optical member having a surface, substantially free from latent scratch, whose surface roughness difference is one micron meter or less in a length of 0.1 micron meter taken along the surface.

Etchant and method for etching chalcogenide glass and optical member

A method for manufacturing a glass fiber includes a process of drawing a starting glass material partially or entirely made of chalcogenide glass or oxychalcogenide glass, such as preform rod, rod-in-tube, or jacketing tube, into a glass fiber in an atmosphere containing sulfur. The concentration of the sulfur in the atmosphere is set at sulfur's vapor pressure or greater around the glass surface at a maximum temperature of the glass fiber while the glass fiber is drawn, thereby fabricating the glass fiber without forming substantially any crystallization on the glass surface.

Drawing a chalcogenide glass fiber in a sulfur atmosphere

Disclosed are an optical fiber comprising a core and a cladding wherein the core is composed of a In-Ga-Cd-Pb halide glass and the clad composed of a halide glass possesses a refractive index of 1.515 or less, which has a large specific refractive index difference (.DELTA.n) and a large numerical aperture, and such an optical fiber as mentioned above wherein the core contains one or more activating ions as well as an optical fiber amplifier comprising a pumping source, a laser glass fiber and a means for introducing pumping light and signal light into the above laser glass fiber, wherein the laser glass fiber is the optical fiber of the present invention mentioned above.

Optical fibers and optical fiber amplifiers

Disclosed are laser glasses composed of a Ga--Na--S glasses doped with one or more kinds of activating ions, laser glass fibers comprising a core and a clad wherein the core is composed of the above-mentioned laser glasses of the present invention and optical fiber amplifiers comprising a pumping source, a laser glass fiber and a means for introducing pumping light and signal light into the laser glass fiber wherein the laser glass fiber is the above-mentioned laser glass fiber of the present invention. The laser glasses of the present invention show high radiative quantum efficiency and host glass stability and can be produced easily.

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Tokyo, Japan

Katsuhisa Itoh