Kanzaki Paper Manufacturing Co., Ltd.

New Oji Paper Co, Ltd.

Kanzaki Paper Mfg. Co., Ltd.

Kanzaki Paper Manufacturing Limited

Katsuhiko Ishida

Tosaku Okamoto

Tomoyuki Okimoto

Ritsuo Mandoh

Masaharu Nojima

Hiroo Hayashi

Takehiro Minami

Hisayoshi Mitoh

Mitsuru Kondo

Nobuo Kanda

Yoshitaka Oeda

Yoshihiro Shimizu

Hisashi Tani

Takuji Tuji

Gensuke Matoba

Toshimitsu Arikawa

Takashi Kawasaki

Munetaka Morita

Kazumi Maki

The present invention provides a heat sensitive recording material comprising a recording layer formed on a substrate and containing a colorless or light-colored basic dye and a color acceptor, the material being characterized in that the basic dye is 3-(N-ethyl-N-p-tolyl)amino-6-methyl-7-p-toluidinofluoran, the color acceptor is bis(3-allyl-4-hydroxyphenyl)sulfone and/or 4-hydroxy-4'-isopropoxydiphenylsulfone.

Heat sensitive recording material

The present invention provides a heat sensitive recording material comprising a substrate, a recording layer formed over the substrate and containing a colorless or light-colored basic dye and a color acceptor, and a protective layer formed over the recording layer, the recording material being characterized in that microcapsules having an ultraviolet absorber enclosed therein and having substantially no color forming ability are incorporated in the protective layer. Further, the present invention provides microcapsules having an ultraviolet absorber and as required an organic solvent enclosed therein, which have capsule wall film of synthetic resin and mean particle size of 0.1 to 3 .mu.m.

Microcapsule containing ultraviolet absorber

The present invention provides a heat sensitive recording material comprising a recording layer formed on a substrate and containing a colorless or light-colored basic dye and a color acceptor, the material being characterized in that the basic dye is 3-diethylamino-7-[m-(trifluoromethyl)phenylamino]fluoran and/or 3-di-n-pentylamino-6-methyl-7-phenylaminofluoran, the color acceptor being 4,4'-dihydroxydiphenylsulfone.

Heat sensitive recording material using microcapsules containing

An improved heat-sensitive recording material of the type having a substrate and a heat-sensitive recording layer formed on said substrate, said heat-sensitive recording layer containing a color former and a color developer to color said color former upon contact by heating, characterized in that said substrate comprises an adiabatic foamed polyester resin film containing minutes cavities with an apparent specific gravity in the range of 0.9 to 1.2.

Heat-sensitive recording material with a substrate comprising a foamed

A heat-sensitive recording material comprising a support and a recording layer provided on the support, said recording layer containing a colorless or pale-colored basic dye and a color developer capable of forming a color upon application of heat, wherein a smectite clay or a combination of a synthetic hectorite clay and soap-free emulsion type binder is incorporated in at least one of layers constituting the recording material.

Heat-sensitive recording material

Disclosed is a heat-sensitive recording material comprising a support and a heat-sensitive recording layer, characterized in that an intermediate layer is formed between the support and the heat-sensitive recording layer wherein the intermediate layer comprises a pigment having an apparent specific gravity of about 0.7 g/cm.sup.3 or less and a polymeric substance having a glass transition temperature of 0.degree. C. or lower as a binder.

Heat-sensitive recording materials

In a multi-color heat sensitive recording material comprising a substrate and two or more heat sensitive color-forming layers thereon capable of forming different colors from each other, at least one of the heat sensitive color-forming layers containing a leuco dye and an acidic substance, the recording material characterized in that at least one piperidine derivative represented by the formula [I] ##STR1## wherein R.sub.1 is C.sub.1.about.30 aliphatic group residue which may have C.sub.2.about.20 alkoxycarbonyl group, or C.sub.1.about.30 aliphatic group residue which has ether linkage and oxycarbonyl group; R.sub.2, R.sub.3, R.sub.4, R.sub.5 and X are each methyl group or hydrogen atom; and l is an integer of 1 to 6, is incorporated at the position where a decolorizing function can be effected against the color-forming system comprising a leuco dye and an acidic substance.

Multi-color heat sensitive recording material

In a heat-sensitive recording material which comprises a substrate and a heat-sensitive recording layer thereon containing a diazonium salt and coupler compound, the heat-sensitive recording material characterized in that the coupler compound comprises at least one compound represented by the formula [I] below ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are each hydrogen atom, halogen atom, alkyl or alkoxyl; R.sub.9 is hydrogen atom or alkyl; X and Y are each hydrogen atom, --OR.sub.10 or --N(R.sub.11)(R.sub.12), R.sub.10, R.sub.11 and R.sub.12 being each hydrogen atom, alkyl, alicyclic group, aryl or aralkyl, these R.sub.10, R.sub.11 and R.sub.12 may have a substituent selected from among halogen atom, alkyl and alkoxy, R.sub.11 and R.sub.12 may link together to form a heteroring, or, one or both of R.sub.11 and R.sub.12 may form a heteroring together with an adjacent benzene ring; n is 0 or 1.

Heat-sensitive diazo recording material with diphenyl alkene coupler

A heat-sensitive recording material comprising a substrate and a heat-sensitive recording layer thereon, the heat-sensitive recording layer containing a diazonium salt, coupler compound, heat-fusible basic compound and at least one of the compounds represented by the formula [I] below ##STR1## wherein X is --O-- or --CONH--, R.sub.1 and R.sub.2 are each hydrogen, halogen, alkyl having 1 to 8 carbon atoms, cycloalkyl, aryl, aralkyl or alkoxyl and n is an integer of 1 to 10.

Heat-sensitive recording diazo material with recording sensitizer

This invention provides a heat-sensitive recording material comprising a substrate and a heat-sensitive recording layer which is formed over the substrate and which contains a diazonium salt, a coupler and at least one of specific heat-fusible basic amidine and diamidine compounds in which the nitrogen atom(s) of ##STR1## moiety(moieties) has(have) a substituent and the nitrogen atom(s) or ##STR2## moiety(moieties) has(have) at least one substituent, the substituent being independently selected from the group consisting of phenyl, naphthyl, phenyl-C.sub.1 -C.sub.4 alkyl and naphthyl-C.sub.1 -C.sub.4 alkyl, each optionally substituted with C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, phenyloxy, nitro or halogen, and in which amidine compounds are other than formamidines. The heat-sensitive recording material is especially excellent in storage stability.

Heat and light-sensitive recording materials with dialonium compound,

This invention provides a multicolor record material comprising a plurality of color forming systems each containing a color forming material and a color developing material and adapted to produce different colors individually, the multicolor record material being characterized in that each of the systems contains a substance which absorbs an infrared beam of specified wavelength for causing the system to produce its color but which substantially does not absorb an infrared beam of different wavelength for causing another system to produce the color thereof.

Multicolor record material

A heat-sensitive record material for use with an infrared laser containing

Heat-sensitive record material

In a heat-sensitive record material comprising a base sheet having a color developing layer which includes finely divided particles of colorless chromogenic material and finely divided particles of acceptor, the colorless chromogenic material exists in the color developing layer in an amorphous state.

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Takatsuki, Japan

Katsuhiko Ishida