Hoechst Aktiengesellschaft

Karl Waldmann

Hans-Jerg Kleiner

Gerd Walz

Gerhard Brindopke

Manfred Schon

Manfred Seidel

Herbert Ramloch

Joachim Lause

Gerhard Pfahler

Georg Schaeffer

Hans D Hermann

Manfred Bohshar

Gunther Semler

Dieter Grote

Gunter Schnabel

A process for the preparation of organophosphorus derivatives of 2,4-di-tert-butylphenol with a high proportion of organophosphorus derivatives of biphenyl, which comprises reacting, in a first step, a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35, under Grignard conditions with magnesium to form the corresponding Grignard compound and this is further reacted in a second step with bis(2,4-di-tert-butylphenyl) chlorophosphite with the formation of a mixture in which at least 50% by weight of the phosphorus is combined in the form of tetrakis(2,4-di-tert-butylphenyl) 4,4'-biphenylenediphosphonite. The invention further relates to a polyolefin molding composition containing tetrakis(2,4-di-tert-butylphenyl) 4,4'-biphenylenediphosphonite which was prepared by reaction of a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35 with magnesium to form the Grignard compound and by subsequent reaction with bis(2,4-di-tert-butylphenyl) chlorophosphite. The invention furthermore relates to a process for the preparation of 4,4'-dihalomagnesium compounds of biphenyl by reacting a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35 in the absence of an entrainer, with fine-particle magnesium which is held in suspension.

Process for the preparation of organophosphorus derivatives of

A 3-component lacquer composed of A) compounds containing at least two R.sup.1 R.sup.2 C.dbd.CR.sup.3 --X groups (I) wherein R.sup.1 denotes hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms, R.sup.2 and R.sup.3 are individually hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, an ester group containing the radical R.sup.4 of a monohydric alcohol having up to 12 carbon atoms, --CN, --NO.sub.2 or a --CO--NHR.sup.1 or --CO--R.sup.1 group, X is --CO-- which is attached to a further R.sup.1 R.sup.2 C.dbd.CR.sup.3 -- group either directly or via the radical of a polyhydric alcohol or of an amine and B) compounds containing:

Reaction product of olefinically unsaturated compounds with compounds

Ceramic green films having advantageous isotropic distribution of the inorganic pigment can be obtained by casting and drying a slip containing finely divided inorganic pigment, organic solvents, polyvinylbutyral, plasticizer and dispersing agent if compounds which contain in their molecules at least one structural unit of the formula Z ##STR1## in which A and B, which must be different, stand for either the oxyalkylene unit --C.sub.3-4 H.sub.6-8 O-- or the oxyalkylene unit --C.sub.2 H.sub.4 O-- and x and y, which can be identical or different, each denote a number from 1 to 200, are used as dispersing agents. Ceramic green films produced according to the invention can be converted to isotropic ceramic substrates by subsequent heat treatment and sintering.

Process for the production of ceramic green films

A reaction product of (A) compounds containing at least two R.sup.1 R.sup.2; C.dbd.CR.sup.3 --X groups (I) with (B) compounds which contain

Compound of the formula ##STR1## in which n denotes a number from 4 to 12, preferably 6 to 8, R.sub.1 denotes hydrogen or methyl, preferably hydrogen, R.sub.2 and R.sub.3 denote C.sub.1 -C.sub.6 -alkyl, preferably propyl or butyl, and X denotes halogen, HSO.sub.4 or anions of organic acids having 1 to 4 carbon atoms, or CH.sub.3 OSO.sub.3, and preferably denotes chlorine. These compounds are used on their own or together with non-ionic surfactants as an emulsifier for the production of aqueous polymer dispersions of fluorine-containing acrylic acid esters. Polymer dispersions of this type, formed from fluorine-containing acrylic acid esters, are used for imparting an oleophobic and hydrophobic finish to textile materials.

Salts, containing fluoroalkyl groups, of beta-alkylamino-propionic acid

Salts, containing fluoroalkyl groups, of .beta.-alkylamino-propionic

Copolymers containing perfluoroalkyl groups

Process for preparing carboxylic acid chlorides by reaction of carboxylic acids or carboxylic anhydrides with phosgene at temperatures of from 0.degree. to 180.degree.C in the presence of a catalyst, wherein 0.01 to 10 weight percent, calculated on the carboxylic acid or the carboxylic anhydride, of trisubstituted phosphine oxides or trisubstituted phosphine sulfides or reaction products of these compounds with phosgene and/or acids or acid anhydrides or mixtures of these compounds are used as catalyst.

Growing community of inventors

Bad Soden am Taunus, Germany

Karl Waldmann