Basf Se Corporation

Basf Corporation

Karl R Gust

Andre Kamm

Lyle Andrew Caillouette

Jeffrey A Dodge

Joseph P Borst

Thomas C Balch

Charles E Jones

Heinz P Plaumann

R Merritt Sink

Julia Liese

David R Phelps

Joann Lanza

Charles Elwood Jones

Stephen Smith

Dominick A Burlone

A composite article includes a low surface energy polymer layer, a poly(meth)acrylate layer, an epoxide layer, and a hydrolytically resistant layer. The poly(meth)acrylate layer is disposed on and in direct contact with the low surface energy polymer layer and includes the reaction product of at least one acrylate that is polymerized in the presence of an organoborane initiator, such that the poly(meth)acrylate includes boron. The epoxide layer is disposed on and in direct contact with the poly(meth)acrylate layer. The hydrolytically resistant layer is disposed on and in direct contact with the epoxide and is the reaction product of an isocyanate component and an isocyanate-reactive component reacted in the presence of a curing agent. The isocyanate-reactive component includes a polydiene polyol and the curing agent crosslinks the carbon-carbon double bonds of the polydiene polyol.

Composite article

A system for forming an elastomeric composition for application to a substrate includes an isocyanate component and an isocyanate-reactive component. The isocyanate component includes a polymeric polyisocyanate and optionally an isocyanate-terminated prepolymer. The isocyanate-reactive component is reactive with the isocyanate component and includes a polyol component and a polyetheramine. The polyol component is a mixture of (a) a hydrophobic polyol; (b) a polyether polyol different than the hydrophobic polyol and having a weight average molecular weight greater than 500 g/mol; and (c) a polyaminopolyol. The elastomeric composition is formed as the reaction product of the isocyanate component and the isocyanate-reactive component and may be applied as an elastomeric coating layer on a substrate such as a steel pipe. The steel pipe having the applied elastomeric coating layer satisfies the standard for use in the water supply industry as set forth in AWWA C222.

System for forming elastomeric compositions for application to metal

A polyurethane elastomeric composition includes the reaction product of an isocyanate component and an isocyanate-reactive component. The isocyanate-reactive component includes a polydiene polyol present in the isocyanate-reactive component in an amount of greater than 0 and less than about 95 parts by weight based on 100 parts by weight of the isocyanate-reactive component. The polydiene polyol has an average hydroxy functionality of no greater than about 3 and a number average molecular weight of from about 1000 to less than about 2000 g/mol.

Polyurethane elastomeric composition and method of preparing the same

A process for producing a polyurethane-coated conduit element includes mixing a) a mixture of aromatic and aliphatic polyisocyanate with, b) at least one polymeric compound having at least two hydrogen atoms which are reactive toward isocyanate, c) at least one chain extender, d) a catalyst, and e) optionally at least one other auxiliary, additive, or both, to form a reaction mixture; applying the reaction mixture to a conduit element; and allowing the reaction mixture to react to form a polyurethane layer. The polyurethane-coating conduit element is suitable for maritime applications in the oil and gas industry, which polyurethane has improved hydrolysis stability at high temperatures and nevertheless satisfies the high mechanical demands in the oil and gas industry.

Hydrolysis-stable polyurethane for coating elements in maritime applications

Oxidation of an alkane to an alkanone in a process stream forms aldehyde-based impurities. A method of minimizing the aldehyde-based impurities introduces an amine into the process stream to minimize the aldehyde-based impurities. The amine interacts with the alkanone and the aldehyde-based impurities thereby forming heavy products. The method separates the heavy products from the alkanones to reduce a level of the aldehyde-based impurities. The process stream preferably includes cyclohexyl ketone as the alkanone and n-hexanal as the aldehyde-based impurity. The method is typically involved in synthesis of a caprolactam.

Method of minimizing aldehyde-based impurities in a process stream

A method of reducing a content of a residual styrene monomer in a polyol utilizes a polyol, a peroxide, an adjustment of temperature, and an application of a vacuum to separate the residual styrene monomer from the polyol. The residual styrene monomer is classified as a volatile organic compound. The peroxide includes monoperoxycarbonates and peroxyketals. Peroxide radicals, present in the peroxide, react with and polymerize the residual styrene monomer to form a polymer having decreased volatility. Applying the vacuum physically separates the residual styrene monomer from the polyol by increasing a vapor pressure of the residual styrene monomer. Separating the residual styrene monomer from the polyol forms an improved polyol which includes less than 20 parts per million of the residual styrene monomer in the polyol.

Method of reducing a content of a residual styrene monomer in a polyol

Coating composition comprising (a) radiation curable component that polymerizes upon exposure to actinic radiation comprising at least two functional groups comprising at least one bond that is activatable upon exposure to actinic radiation, optionally, at least one isocyanate-reactive functional group, and optionally, at least one hydroxyl-reactive functional group; (a) thermally curable binder component that polymerizes upon exposure to heat comprising at least two functional groups that are reactive with functional groups of component (a), wherein at least 5% by weight based on a nonvolatile weight of component (a) is component (X) that is a polymer with at least two functional groups (a), a Tg of less than 0&#xb0; C., and an equivalent weight of greater than 225; (a) thermally curable crosslinking component comprising at least two functional groups that are reactive with functional groups of (a); and (a) optionally, at least one reactive diluent.

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Clawson, MI, United States of America

Karl R Gust