Bayer Aktiengesellschaft

Karl-Arnold Weber

Harro Traubel

Karl H Pisaric

Josef Pedain

Dieter Brauner

Manfred H Pahl

Hans-Josef Buysch

Kuno Wagner

Dieter Dieterich

Helmut Reiff

Klaus Wunderlich

Hermann Henk

Wilhelm Thoma

Klaus Kunde

Eberhard Konig

Manfred Hajek

Lothar Kahl

Walter Schroer

Karl-Ludwig Noble

Jochen Westphal

Siegfried Klipfel

Joseph Pedain

The present invention is directed to polyisocyanates containing a stabilizing amount of a carboxylic acid corresponding to the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 represent hydrogen or C.sub.1 -C.sub.5 -alkyl and

Stabilized polyisocyanates

Colorants are obtained by reacting a dyestuff which is free from ionic groups and has.gtoreq.2 NH.sub.2 groups which are preferably arranged in such a manner that they do not participate in the resonance of the chromophore with such an amount of a (cyclo)aliphatic diisocyante so as to form an adduct that still contains at least two free NCO groups, and subsequently reacting this adduct with a (cyclo)aliphatic diamine, to form an adduct suitable for dyeing and pigmenting macromolecular substances, in particular for coloring PUR-based paints, coatings and laminates.

Colorants obtained by reacting a NH.sub.2 -containing dyestuff with a

The present invention is directed to polyurethane ureas which may be obtained by the reaction of a hydrophilic NCO prepolymer, which has been prepared from a polyhydroxy component based on about 9 to 100% by weight of a polyether containing about 30 to 100% by weight of ethylene oxide, or a mixture of this hydrophilic NCO prepolymer and a hydrophobic NCO prepolymer, the mixture containing .gtoreq.30% by weight of the hydrophilic prepolymer, with an aldimine or ketimine-containing hardener mixture in the presence of water and organic solvents, approximately 30 to 70% of the NCO groups of the prepolymers being reacted with the amino groups of the hardener and the remainder reacting with water. The present invention is also directed to a process for the preparation of these polyurethane ureas and to coated substrates prepared from these polyurethane ureas.

Polyurethane ureas

The present invention is directed to a process for the production of light-stable, solvent-resistant polyurethane urea elastomer coatings by the reactive coating process wherein NCO prepolymers are reacted with 4,4'-diamino-C.sub.1 -C.sub.4 -tetraalkyldicyclohexylalkanes containing up to 4 carbon atoms in the alkyl group with continuous mixing and continuous discharge of the reaction mixture.

Process for the production of light-stable, solvent-resistant

The invention disclosed herein is concerned with a process for mixing a plurality of viscous rapidly reacting, fluid materials and an apparatus with which to perform this process. In this process the fluid materials are initially introduced into a mixing chamber and mixed with a gas, preferably in such a way that an angular momentum is imparted to the mixture. The mixture is then fed into a static mixer which has a short residence time spectrum. The apparatus comprises a cylindrical mixing chamber with a gas inlet and at least one nongaseous fluid material inlet arranged to direct flow tangentially to the interior surface of the mixing chamber. Other inlets may be provided downstream of these initial inlets but before a static mixing apparatus with which said mixing chamber communicates. An outlet is provided downstream of said static mixing apparatus which preferably has intersecting baffle plates, a low pressure loss and a short residence time spectrum.

Apparatus for the mixing and application of reactive materials

The invention disclosed herein is concerned with a process for mixing a plurality of viscous rapidly reacting, fluid materials and an apparatus with which to perform this process. In this process the fluid materials are initially introduced into a mixing chamber and mixed with a gas, preferably in such a way that an angular momentum is imparted to the mixture. The mixture is then fed into a static mixer which has a short residence time spectrum. The apparatus comprises a cylindrical mixing chamber with a gas inlet and at least one nongaseous fluid material inlet arranged to direct flow tangentially to the interior surface of the mixing chamber. Other inlets may be provided downstream of these initial inlets but before a static mixer with which said mixing chamber communicates. An outlet is provided downstream of said static mixer which preferably has intersecting baffle plates, a low pressure loss and a short residence time spectrum.

Process and apparatus for the mixing and application of reactive

The present invention relates to a process for the production of polyurethane ureas from a prepolymer which contains isocyanate groups and a mixture of hardeners containing amino groups, in the presence of water, and optionally in the presence of solvents, characterized in that the mixture of hardeners comprises compounds corresponding to the following general formulae:

Preparation of polyurethane ureas using as hardeners mixtures of water,

The instant invention relates to thermoplastic polyurea powders, optionally containing urethane groups, characterized by

Colored poly (urethane) urea powders

A substrate to be used as a support for a release coating is provided with a powdery release support with a release agent which is substantially non-tacky by applying on the support an aqueous solution, dispersion or paste containing a lactam compound which is water soluble, swells in water or forms a paste with water, drying the resulting coating. The process comprises treating the release agent, drying the release agent, applying a polyurethane coating over the release support and then removing the polyurethane coating from the release support. The release agent is selected from lactams and addition compounds of lactams with water, oximes, amines, monofunctional or polyfunctional alcohol or thioalcohols and mixture thereof.

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Leverkusen, Germany

Karl-Arnold Weber