Bp Chemicals Limited

Ineos Europe Limited

Karen Small

Peter Simpson Bell

Eric Nicholas Coker

Jeremy B Cooper

Nigel Keith Potter

The invention relates to a process for the selective recovery of olefins from a mixture of gases by: a) bringing a gaseous mixture having olefins and hydrogen into contact with silver nitrate solution whereby the olefins are absorbed into the silver nitrate solution as a complex; b) separating the solution having complexed olefins from the non-absorbed gases; c) depressurising and heating the olefin complex solution from (b) so as to release the olefins from the complex and regenerate the silver nitrate solution; d) passing the regenerated silver nitrate solution through a bed containing silver oxide so as to maintain the pH value of the silver nitrate at between 3 and 6; and e) recycling the silver nitrate solution regenerated in (d) to step (a).

pH control method of reducing nitrogen oxides emission

Ethylene and propylene are recovered from a mixture thereof with other hydrocarbons by: (a) feeding the mixture to a separation zone with a top and a bottom; (b) feeding to the top above the mixture an aqueous complexing solution to form Cu(I) complexes of ethylene and propylene; (c) feeding below the mixture ethylene to strip propylene from the propylene complex; (d) removing from the bottom below the stripping gas a first liquid stream containing the Cu (I) ethylene complex; (e) recovering ethylene from the Cu(I) complex using reduced pressure and/or elevated temperature; (f) removing from the separation zone between the the gaseous mixture and the complexing solution, a second liquid stream comprising Cu (I) propylene complex; (g) recovering propylene from the Cu(I) complex and producing a liquid recycle stream comprising copper (I) salt; and (h) recycling the liquid recycle stream from step (g) to the separation zone.

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West Lothian, United Kingdom

Karen Small