Korea Institute of Geoscience and Mineral Resources

Korea Institute of Geoscience and Mineral Resources (Kigam)

Kang-Sup Chung

Byoung-Gyu Kim

Hye-Jin Hong

In-Su Park

Jae-chun Lee

Tae Gong Ryu

Jungho Ryu

Taegong Ryu

Jung Ho Ryu

Jae Chun Ryu

Byoung Gyu Kim

Jin-Ki Jeong

Hwan No Lee

Byung-Gyu Kim

Tae-Gong Ryu

Kyoung Chul Lee

Yang-Soo Kim

Hee-Jin Kim

The invention relates to a lithium adsorption-desorption apparatus including a plurality of reaction tanks arranged in a row; a guide rail disposed at an upper portion of the reaction tank; a movable driving unit coupled to a moving means that moves along the guide rail; and a reaction housing which is mounted to the driving unit, and can be vertically moved or rotated in a state in which the lithium adsorbent is fixed thereto, and after immersing in the reaction tank, accelerates adsorption or desorption of lithium, and after being lifted, discharges residual solution from the lithium adsorbent by rotation movement. Therefore, the lithium adsorption desorption apparatus can fix a large amount of lithium adsorbent and immerse it in a lithium-containing solution to effectively adsorb lithium and then quickly desorb lithium in a desorption solution, and can efficiently wash the lithium adsorbent in a cleaning solution.

Lithium adsorption-desorption apparatus and lithium adsorption-desorption method using the same

The present disclosure relates to an onshore lithium-recovering device for a lithium ion adsorption and desorption process including a supply unit for supplying lithium-containing water in which lithium is dissolved, a composite unit, a washing unit, a desorbing liquid unit, an extract liquid unit, a pressure adjusting unit, a discharge unit, and a control unit. Therefore, the lithium adsorption means is moved onshore so it is possible to significantly reduce the plant installation cost and the operating cost as compared to the lithium recovery process that operates the conventional offshore plant.

Onshore lithium-recovering apparatus for lithium ion adsorption and desorption process and lithium-recovering method using the same

Provided is a recovery method of useful resources in seawater and brine, and more particularly, a recovery method of useful resources in seawater and brine capable of improving adsorption efficiency and recovery efficiency of trace amounts of useful resources such as strontium, lithium, boron, or the like, present in brine at low cost by using a magnetic adsorbent composite and a solid-liquid separation process which uses magnetic force.

Recovery method of useful resources in seawater and brine

Provided is an underwater holding-type lithium recovering apparatusincluding: an underwater holderinstalled on an offshore sea bed; a lithium adsorbentheld in the underwater holderand adsorbing lithium ions contained in seawater; a moving shipinstalled with a cleaning tankcleaning the lithium adsorbenttransferred from the underwater holderand a desorbing tankdesorbing lithium ions adsorbed in the lithium adsorbenttransferred from the cleaning tank, and moved to a coastline when lithium ions of a reference value or more are filled in the desorbing tank; and a transfer pumptransferring lithium ions filled in the desorbing tankto a reservoirinstalled at the coastline.

Underwater holding-type lithium recovering apparatus and method thererof

Provided are a lithium adsorbent prepared using an aerosol deposition method, including (a) synthesizing lithium manganese oxide powder, and (b) coating the lithium manganese oxide powder on a surface of a substrate by the aerosol deposition method, and a method of preparing the same. The lithium adsorbent is characterized in that the lithium manganese oxide powder may be directly coated on various substrates using the aerosol deposition method, thereby greatly reducing a decrease of a lithium recovery rate even after a long time has lapsed. Further, the lithium adsorbent having a large surface area prepared by the preparation method of the present invention is characterized by being easily handled, being selectively reacted with lithium ions, having a larger adsorption area, being physically and chemically stable, and being used reversibly.

Method of preparing lithium adsorption structure having large surface area

The present invention relates to a lithium recovery device and recovery method. The lithium recovery device of the present invention includes: a first electrode; a second electrode; and a power supply device. In the lithium recovery device of the present invention, since lithium is attached to an adsorbent of the first electrode by applying a current to the first and second electrodes in a state in which the first and second electrodes are immersed in a lithium-containing fluid, the first electrode including a carrier made of a stainless steel material in a form of an iron mesh or perforated sheet and having a surface coated with the adsorbent containing a manganese oxide, and the second electrode facing the first electrode, it is possible to increase a size of the device and have excellent energy efficiency and economic feasibility.

Lithium recovery device and recovery method

The present invention relates to a method for manufacturing an electrode module for recovery of metal ions, an electrode module for recovery of metal ions, and an apparatus for recovery of metal ions including the same. The present invention provides a method for manufacturing an electrode module for recovery of metal ions, the method including the steps of: a) preparing a first electrode part and a second electrode part for electrically adsorbing or desorbing metal ions contained in a liquid; and b) interposing an insulating layer, through which the liquid passes, between the first electrode part and the second electrode part, an electrode module for recovery of metal ions manufactured by the method, and an apparatus for recovery of metal ions including the same. According to the present invention, it is possible to significantly reduce the time required for the adsorption and desorption of ions when specific valuable metal ions are recovered from an aqueous solution in which various valuable metal ions are dissolved.

Method for manufacturing electrode module for recovery of metal ions, electrode module for recovery of metal ions, and apparatus for recovery of metal ions including the same

The present invention relates to a porous manganese oxide-based lithium absorbent and a method for preparing the same. The method includes the steps of preparing a mixture by mixing a reactant for the synthesis of a lithium-manganese oxide precursor powder with an inorganic binder, molding the mixture, preparing a porous lithium-manganese oxide precursor molded body by heat-treating the molded mixture, and acid-treating the porous lithium-manganese oxide precursor molded body such that lithium ions of the porous lithium-manganese oxide precursor are exchanged with hydrogen ions, wherein pores are formed in the lithium-manganese oxide precursor molded body by gas generated in the heat treatment. The porous manganese oxide-based lithium adsorbent according to the present invention is easy to handle and has many more adsorption reaction sites compared to existing molded adsorbents, thus providing high lithium adsorption efficiency.

Porous manganese oxide absorbent for lithium having spinel type structure and a method of manufacturing the same

The present invention relates to a lithium recovery device comprising a separator reservoir and manganese oxide, a lithium recovery method using the same, and a lithium adsorption/desorption system. The separator reservoir includes a vacant space therein and an outer wall made of a polymer or a membrane of other useful materials. The manganese oxide is contained, as an adsorbent, in the vacant space inside the separator reservoir. The lithium adsorption/desorption system enables lithium recovery through adsorption and desorption of lithium dissolved in seawater using a lithium adsorbent prepared with the manganese oxide in one system, wherein the manganese oxide can be used as a lithium adsorbent with high lithium selectivity. The invention uses a separator reservoir including an outer wall made of a porous polymer or a membrane of other useful materials. As a result, the invention can be directly applied to seawater by enabling free movement of the solution, especially seawater, without additional pressure from the outside. The invention ensures strong stability in seawater and the acidic solution using a polymer with high chemical resistance and mechanical strength, or other useful materials. Therefore, the invention can be widely used in technical fields requiring lithium recovery.

Lithium recovery device using separator reservoir, lithium recovery method and lithium adsorption/desorption system using the same

There is provided Lithium-manganese oxides expressed as the following chemical formula 1,LiMnMO,&#x2003;&#x2003;[Chemical Formula 1]

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Daejeon, South Korea

Kang-Sup Chung