Other

Exxonmobil Chemical Patents Inc.

Advanced Elastomer Systems, L.p.

Kang-Bo Wang

Maria Dolores Ellul

Sudhin Datta

Trazollah Ouhadi

Jianya Cheng

Prasadarao Meka

Krishna Venkataswamy

Kuo-Shein Shen

Paul Edward McDaniel

Craig Allen Chmielewski

Yu-Feng Wang

A TPV composition having improved fabricability and surface appearance is achieved by a process for preparing a thermoplastic vulcanizate composition having a dispersed, cross-linked rubber phase in a continuous thermoplastic polypropylene phase comprising: a) providing into melt processing equipment at least the following components; i) at least one thermoplastic polypropylene homopolymer or copolymer having a melt temperature greater than 120&#xb0; C.; ii) 6-12 wt. %, based on the total weight of the thermoplastic vulcanizate composition, at least one propylene copolymer having from 7 to 30 wt. % ethylene, based upon the weight of the random propylene copolymer, and a melting point less than 120&#xb0; C.; iii) at least one cross-linkable rubber, where, if including an ethylene copolymer rubber, said copolymer rubber having equal to or more than 40 wt. % the total copolymer rubber weight; b) melt processing the blend of i), ii), and iii) of a); c) dynamically vulcanizing the cross-linkable rubber iii) in the presence of the thermoplastic i) and random copolymer ii); and d) removing a thermoplastic vulcanizate product of c) from the melt processing equipment, wherein the dispersed, cross-linked rubber phase of the product thermoplastic vulcanizate d) consists of particles having an effective diameter not greater than 2 millimicrons.

Thermoplastic vulcanizates having improved fabricability

The present invention provides a thermoplastic vulcanizate prepared by a process comprising the steps of dynamically vulcanizing rubber within a blend that includes the rubber and a thermoplastic resin, where the rubber comprises an elastomeric copolymer of ethylene, at least one &#x3b1;-olefin, and optionally one or more diene monomers, where the elastomeric copolymer is characterized by having a crystallinity, as measured by differential scanning calorimetry, of less than 10 J/g, an ethylene content that is less than 90 mole percent based upon the entire copolymer, a weight average molecular weight that is greater than about 20,000 as measured by GPC with polystyrene standards, a molecular weight distribution that is less than 7, and an ethylene compositional distribution that is less than about 4 percent for the closest 90 percent of fractioned samples.

Thermoplastic elastomers having improved low temperature properties

Thermoplastic elastomer compositions having improved processabillity while maintaining good physical properties are prepared from a mixture of olefinic rubber and a polypropylene composition having a melt flow rate in the range of from about 0.5 to about 5 dg/min. and a molecular weight distribution Mw/Mn of greater than 5.5 up to about 20. The rubber component of the mixture may be at least partially cured by dynamic vulcanization.

Polypropylene thermoplastic elastomer compositions having improved processing properties and physical property balance

Processes for the preparation of a thermoplastic elastomer comprising a triblend of engineering resin, dynamically vulcanized alloy of thermoplastic olefin polymer and elastomeric copolymer, and a compatibilizer for the engineering resin and alloy. The compatibilizer can be formed in a separate step or in-situ in a one step process. The processes produce compositions which retain structural integrity at high temperature, and have good tensile properties, elongation and fluid resistance.

Processes for producing thermoplastic elastomers having improved

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Copley, OH, United States of America

Kang-Bo Wang