Daikin Industries, Ltd.

Kae Fujiwara

Takaya Yamada

Junpei Terada

Akinori Tani

Provided are a composite that can be suitably used as an electrolyte in polymer-based solid-state batteries, and various electrochemical devices using the composite. The composite includes a fluorine-containing elastomer and an alkali metal salt as essential components, wherein the fluorine-containing elastomer is an amorphous fluorine-containing elastomer having a glass transition temperature of 25° C. or less, and the composite has a volatile content of 0.1 mass % or less with respect to the entire composite.

Polymer electrolyte including amorphous fluorine-containing elastomer and alkali metal salt, electrochemical device, polymer-based solid-state battery, and actuator including the same

An oxide-based solid-state secondary battery and a binder for a solid-state secondary battery using an oxide-based solid electrolyte that contains a fluorine-containing polymer including a vinylidene fluoride unit and a fluorinated monomer unit other than the vinylidene fluoride unit. The fluorinated monomer unit is at least one copolymerization unit (A) selected from a monomer unit having a structure represented by formula (1) and a monomer unit having a structure represented by formula (2): wherein Rfand Rfare each a linear or branched fluorinated alkyl or fluorinated alkoxy group with 1 to 12 carbon atoms, which optionally contains an oxygen atom between carbon-carbon atoms when the number of carbon atoms is 2 or more.

Binder for solid-state secondary battery, slurry for solid-state secondary battery, method for forming layer for solid-state secondary battery and solid-state secondary battery

A binder and a slurry suitable for use in the production of an electrode in a sulfide-based solid-state battery. The binder contains sulfide-based solid electrolyte particles, and is a polymer including a vinylidene fluoride unit and at least one copolymerization unit (A) selected from a monomer unit having a structure represented by formula (1) below and a monomer unit having a structure represented by formula (2) below: where Rfand Rfare each a linear or branched fluorinated alkyl or fluorinated alkoxy group with 1 to 12 carbon atoms, which optionally contains an oxygen atom between carbon-carbon atoms when the number of carbon atoms is 2 or more. The slurry contains sulfide-based solid electrolyte particles, the binder and a solvent. Also disclosed is an electrode including an electrode active material layer formed using the slurry and a lithium-ion secondary solid state battery including the electrode.

Binder, slurry for solid-state battery, electrode for solid-state battery, and secondary solid-state battery

A binder and a slurry suitable for use in the production of an electrode in a sulfide-based solid-state battery. The binder contains sulfide-based solid electrolyte particles, and is a fluorine-containing elastomer in which resin end functional groups satisfy:0.01≤([—CHOH]+[—COOH])/([—CH]+[—CFH]+[—CHOH]+[—CHI]+[—OC(O)RH]+[—COOH]≤0.25where R represents an alkyl group with 1 to 20 carbon atoms. Also disclosed is an electrode including an electrode active material layer formed using the slurry and a lithium-ion secondary solid state battery including the electrode.

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Osaka, Japan

Kae Fujiwara