Bayer Aktiengesellschaft

Jurgen Lewalter

Rudolf Merten

Willi Dunwald

Wilfried Zecher

Ludwig Rottmaier

Bernhard Schulte

Hans Rudolph

Hans J Rosenkranz

Jurgen Hocker

Karl-Heinrich Meyer

Hans-Jurgen Muller

Birger Knickel

Wolf-Dieter Last

A process for the production of modified polyhydantions by reacting polyglycine acid derivatives with optionally masked polyisocyanates with the addition of cyclic anhydride compounds containing at least one further functional group capable of condensation in lactones as solvents.

Process for the preparation of polymers containing hydantoin groups

Heat resistant polymers connected by ester and/or urethane groups and optionally amide- and/or imide groups and/or hydantoin and/or isocyanurate rings are obtained by crosslinking the polymers with trishydroxy alkyl triazolidine -3,5-diones.

Heat-resistant cross-linked polymers and the use thereof as binders

Poly(thio)hydantoins are prepared by reacting an iso(thio)cyanate having at least two iso(thio)cyanate moieties with a compound of the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and each represents hydrogen, halogen, a C.sub.1 -C.sub.20 aliphatic group, a C.sub.7 -C.sub.20 aliphatic-aromatic group, a C.sub.6 -C.sub.20 aromatic group or a heterocyclic group having from 4 to 16 ring members and at least one N, O or S atom;

Polyhydantoins from unsaturated carboxylic acids and

In non-phenolic solvents soluble Polyamid-hydantoins optionally containing ester and/or imide and/or isocyanurate groups are obtained by reacting polyisocyanates with polyfunctional amino carboxylic acid derivatives and a compound containing at least a carboxylic group preferably in the presence of a non-phenolic solvent.

Coating compositions obtained by reacting amino carboxylic acids

A process for the production of compounds containing hydantoin groups by reacting .alpha.-amino-carboxylic acid derivatives and organic isocyanates in the presence of acid groups and either in absence of any solvent or in the presence of a non-phenolic solvent.

A process for the preparation of a poly(thio)hydantoin, which comprises reacting an organic isocyanate or isothiocyanate having two or more isocyanate or isothiocyanate moieties with an unsaturated dicarboxylic acid of the formula: ##STR1## at a temperature of from -20.degree. C. to +500.degree. C., wherein R.sub.1 and R.sub.2 are hydrogen, halogen, substituted or unsubstituted aliphatic, aliphatic-aromatic, aromatic or heterocyclic.

Process for the preparation of poly(thio)hydantoins

Polyiso(thio)cyanates containing a (thio)hydantoin ring substituted by carboxylic acid amide groups in the molecule are obtained by reacting optionally substituted ethylene- 1,2-dicarboxylic acid anhydrides with amino alcohols and an excess of polyiso (thio) cyanates.

Polyisocyanates with at least one hydantoin or thiohydantoin ring

This invention relates to a new process for the preparation of oligourethanes having isocyanate end groups blocked with alkanol and/or cycloalkanol groups, the compounds which can be obtained by this process and their use for the production of polyurethane resins by the isocyanate polyaddition process.

Process for the preparation of oligourethanes

A process for the low solvent or solvent free coating of heat resistant substrates by using a coating substance which has a melting point or range below about 200.degree. C and which is heat crosslinkable. The substrate is coated at temperatures between about 20.degree. and 250.degree. C and the coating is subsequently heated to more elevated temperatures to effect crosslinking. The coating substance contains active hydrogen, preferably hydroxyl bearing compounds and blocked polyisocyanates which become reactive when the coating substance is heated to effect cross-linking. In a preferred embodiment, the blocked polyisocyanates consist of at least 40 equivalent percent alkanol or cycloalkanol blocked polyisocyanates. Also a coating substance containing at least 50 wt.% of a combination of active hydrogen, preferably hydroxyl bearing compounds and blocked isocyanates. The combination has a melting point of less than 200.degree. C and a blocked isocyanate group to active hydrogen ratio of about 1:2 to 1:9. At least 40 equivalent percent of the blocked polyisocyanates are alkanol or cycloalkanol blocked and the remainder are blocked such that they are reactive at temperatures at least 30.degree. C lower than the alkanol or cycloalkanol blocked polyisocyanates. The coating substance has a viscosity of less than about 40,000 cP at or below about 250.degree. C.

Melt coating composition and coating process

Asymmetric, semipermeable membranes of polyhydantoins or polyparabanates.

Asymmetric, semipermeable membranes of cyclic polyureas

Process for the preparation of polyhydantoins or polyparabanic acids, characterized in that bis- or polyglycine derivatives or bis- or poly-monoamidooxalic acid derivatives are heated to temperatures of 20.degree. to 250.degree. C with di- or polyiso(thio)cyanate derivatives without solvents and the highly fluid melt which has a melt viscosity of at the most 40,000 m.Pa.s. is optionally subjected to a shaping process and is polycondensed by adjustment to the reaction of 80.degree. to 700.degree. C.

Process for the preparation of polyhydantoins and polyparanic acids

A process for preparing compounds which contain hydantoin groups, which is characterized in that compounds which contain isocyanate or isothiocyanate groups are reacted with compounds which contain an .alpha.-halocarboxylic acid group or derivatives thereof at least once in the molecule.

Process for the preparation of compounds which contain hydantoin groups

A process for preparing compounds containing hydantoin groups, wherein compounds which contain isocyanate or isothiocyanate groups are reacted with compounds which contain at least one, preferably two .alpha.-halocarboxylic acid amide groups or one .alpha., .alpha.'-dihalodicarboxylic acid diamide group.

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Odenthal, Germany

Jurgen Lewalter