Daikin Industries, Ltd.

Junpei Terada

Shoji Fukuoka

Tatsuya Morikawa

Daisuke Ota

Masanori Kitaichi

Shigeru Morita

Yutaka Ueta

Takahiro Furutani

Takaya Yamada

Kazuyoshi Kawasaki

Hirokazu Komori

Kae Fujiwara

Yuki Ueda

Hiroyuki Yoshimoto

Akinori Tani

Masaji Komori

Hiroyuki Hamada

Toshio Miyatani

Tadahiro Yabu

Tomohiro Shiromaru

Masahiro Kondou

Hiroyuki Sendan

Yukihiro Fukagawa

Kenta Murayama

Hirokazu Aoyama

Meiten Koh

Haruhiko Mohri

Yuuki Kuwajima

Masaki Irie

Takuji Ishikawa

Mayuko Taeda

Hideto Nakagawa

Hiroshi Aihara

Satoshi Kawai

Kozue Komazawa

Rumi Takeuchi

Eisaku Sumino

Yusuke Kamiya

Hiroyuki Sagami

Takayuki Matsuo

Rina Tamai

Morita Shigeru

Provided are a composite that can be suitably used as an electrolyte in polymer-based solid-state batteries, and various electrochemical devices using the composite. The composite includes a fluorine-containing elastomer and an alkali metal salt as essential components, wherein the fluorine-containing elastomer is an amorphous fluorine-containing elastomer having a glass transition temperature of 25° C. or less, and the composite has a volatile content of 0.1 mass % or less with respect to the entire composite.

Polymer electrolyte including amorphous fluorine-containing elastomer and alkali metal salt, electrochemical device, polymer-based solid-state battery, and actuator including the same

An oxide-based solid-state secondary battery and a binder for a solid-state secondary battery using an oxide-based solid electrolyte that contains a fluorine-containing polymer including a vinylidene fluoride unit and a fluorinated monomer unit other than the vinylidene fluoride unit. The fluorinated monomer unit is at least one copolymerization unit (A) selected from a monomer unit having a structure represented by formula (1) and a monomer unit having a structure represented by formula (2): wherein Rfand Rfare each a linear or branched fluorinated alkyl or fluorinated alkoxy group with 1 to 12 carbon atoms, which optionally contains an oxygen atom between carbon-carbon atoms when the number of carbon atoms is 2 or more.

Binder for solid-state secondary battery, slurry for solid-state secondary battery, method for forming layer for solid-state secondary battery and solid-state secondary battery

A binder and a slurry suitable for use in the production of an electrode in a sulfide-based solid-state battery. The binder contains sulfide-based solid electrolyte particles, and is a polymer including a vinylidene fluoride unit and at least one copolymerization unit (A) selected from a monomer unit having a structure represented by formula (1) below and a monomer unit having a structure represented by formula (2) below: where Rfand Rfare each a linear or branched fluorinated alkyl or fluorinated alkoxy group with 1 to 12 carbon atoms, which optionally contains an oxygen atom between carbon-carbon atoms when the number of carbon atoms is 2 or more. The slurry contains sulfide-based solid electrolyte particles, the binder and a solvent. Also disclosed is an electrode including an electrode active material layer formed using the slurry and a lithium-ion secondary solid state battery including the electrode.

Binder, slurry for solid-state battery, electrode for solid-state battery, and secondary solid-state battery

A laminate, including a fluororesin sheet; and a base material. The fluororesin sheet including a fluororesin composition containing: a melt moldable fluororesin; and a silica. The fluororesin is a tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer and/or a tetrafluoroethylene-hexafluoropropylene copolymer having 25 or more carbonyl group-containing functional groups per 10main-chain carbon atoms; the silica is a spherical silica; a blending ratio of the spherical silica to a total amount of the fluororesin and the silica is 50% by mass or higher and 70% by mass or lower; the fluororesin composition has a linear expansion coefficient of 100 ppm/° C. or lower and a melt flow rate (MFR) of 1.0 g/10 min or higher and 30 g/10 min or lower. Also disclosed is a substrate for circuits including the fluororesin sheet used as a part in a multilayer structure.

Fluororesin composition, fluororesin sheet, laminate and substrate for circuits

A binder and a slurry suitable for use in the production of an electrode in a sulfide-based solid-state battery. The binder contains sulfide-based solid electrolyte particles, and is a fluorine-containing elastomer in which resin end functional groups satisfy:0.01≤([—CHOH]+[—COOH])/([—CH]+[—CFH]+[—CHOH]+[—CHI]+[—OC(O)RH]+[—COOH]≤0.25where R represents an alkyl group with 1 to 20 carbon atoms. Also disclosed is an electrode including an electrode active material layer formed using the slurry and a lithium-ion secondary solid state battery including the electrode.

A composition including a fluorine-containing polymer and a cross-linking agent, wherein the fluorine-containing polymer contains a vinylidene fluoride unit, a unit of a fluorine-containing monomer (1) represented by the following general formula (1):CHX═CXRf  (1)wherein one of Xand Xis H, the other is F, and Rf is a linear or branched fluoroalkyl group having 1 to 12 carbon atoms, and a unit of a monomer providing a crosslinking site. The monomer providing a crosslinking site is a monomer having at least one crosslinkable group selected from a cyano group, a carboxyl group, an alkoxycarbonyl group and a hydroxyl group. Also disclosed is a crosslinked rubber molded article obtained by crosslinking the composition.

Composition, crosslinked rubber molded article and fluorine-containing polymer

A fluororesin composition containing a melt moldable fluororesin and a silica, wherein the fluororesin has 25 or more carbonyl group-containing functional groups per 10main-chain carbon atoms; the silica is a spherical silica; and the fluororesin composition has a linear expansion coefficient of 100 ppm/° C. or lower. Also disclosed is a fluororesin sheet including the fluororesin composition, a laminate including a copper foil layer and a layer including the fluororesin composition and a substrate for circuits including a copper foil layer and a layer including the fluororesin composition.

A molded body which is formed from a shaping material containing a fluororesin powder. The fluororesin powder has a D50 of 30 μm or more and 200 μm or less and a D10 of 12 μm or more. Also disclosed is a method for forming a molded body from a shaping material containing the fluororesin powder, the method including controlling the temperature of the fluororesin powder; and irradiating the fluororesin powder with a laser at the controlled temperature to fuse the same.

Molding powder

A fluorine-containing elastomer composition for a heat dissipation material, including a fluorine-containing elastomer being VdF-based fluoroelastomer having a Mooney viscosity at 121&#xb0; C. of 10 or lower and an insulating thermal conductive filler. Also disclosed is a sheet obtained by molding the fluorine-containing elastomer composition.

Fluorine-containing elastomer composition for heat dissipation material and sheet thereof

A shaping material for a powder bed fusion method, including a powder of a fluororesin, wherein the fluororesin has a D50 of 30 &#x3bc;m or more and 200 &#x3bc;m or less, and the fluororesin has a D10 of 12 &#x3bc;m or more.

The present invention provides a hose excellent in mechanical properties at high temperatures. The hose of the present invention comprises a cross-linked fluororubber layer obtainable by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B). The cross-linked fluororubber layer has a loss modulus E&#x2033; of 400 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test (measurement temperature: 160&#xb0; C., tensile strain: 1%, initial force: 157 cN, frequency: 10 Hz).

Hose

The present invention aims to provide a laminate in which a fluororesin layer and a fluororubber layer are firmly bonded even when the fluororesin layer contains a fluororesin having excellently low fuel permeability. The present invention relates to a laminate including a fluororubber layer (A) and a fluororesin layer (B) stacked on the fluororubber layer (A). The fluororubber layer (A) is a layer formed from a fluororubber composition. The fluororubber composition contains a fluororubber (a1) and a basic multifunctional compound having at least two nitrogen atoms in the molecule with a distance between the nitrogen atoms in the molecule of 5.70 &#x212b; or greater. The fluororubber (a1) has an absorption coefficient at 1720 cm, determined after being brought into contact with triethyl amine, of 0.35 or lower. The fluororesin layer (B) is formed from a fluororesin (b1) having a fuel permeability coefficient of 2.0 g&#xb7;mm/m/day or lower.

Laminate, method for manufacturing same, and fluororubber composition

An aqueous perfluoroelastomer dispersion and method for producing a perfluoroelastomer using a specific fluorosurfactant and capable of achieving a sufficient number of particles and a sufficient polymerization rate. The method includes providing an aqueous dispersion containing perfluoroelastomer particles by emulsion-polymerizing a perfluoromonomer in an aqueous medium in the presence of a specific fluorosurfactant in an amount of 2 parts by mass or more for 100 parts by mass of the aqueous medium.

Method for producing aqueous perfluoroelastomer dispersion, and method for producing perfluoroelastomer

A diaphragm including a cross-linked fluororubber layer obtained by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B), the cross-linked fluororubber layer having a loss modulus E&#x2033; of 400 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test under conditions of measurement temperature: 160&#xb0; C., tensile strain: 1%, static tension under a constant static load condition for measuring strain distribution: 157 cN, and frequency: 10 Hz.

Diaphragm

To provide a sealing material which is excellent in sealability under high-temperature conditions as well as crack resistance at high temperatures and high compression. A sealing material comprising a cross-linked fluororubber layer obtainable by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B), the cross-linked fluororubber layer having a loss modulus E&#x2033; of 600 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test under conditions of measurement temperature: 160&#xb0; C., tensile strain: 1%, initial force: 157 cN, and frequency: 10 Hz.

Growing community of inventors

Settsu, Japan

Junpei Terada