Nippon Paper Industries Co., Ltd.

Api Corporation

Nippon Paper Papylia Company, Limited

Junpei Natsui

Takashi Date

Kaoru Hamada

Akihito Ogino

Kenji Hirai

Yoshihide Kimura

Seiki Yoneshige

Yuji Tsuzuki

Masayuki Watanabe

Yoshimi Midorikawa

Tatsuo Nagai

Yoshiaki Ishino

Takanori Otsuhata

Mamoru Suga

Naoki Negishi

Jun Makihara

Yoshimune Aosaki

Mizuho Shimoyama

Hiroki Midorikawa

Hiroshi Kohama

Yoshiteru Kanomata

Aya Katoh

Provided is a thermal recording material superior in color development sensitivity, and having good preservation properties such as in heat resistance, moisture resistance, water resistance and the like. A thermal recording material comprising a support and a thermal recording layer comprising a colorless or pale basic leucodye and a developer to develop color of the basic leucodye, wherein the aforementioned developer comprises a first developer which is a condensate or condensed composition represented by the following formula (I) and a second developer other than the first developer, and the proportion of the first developer to the total amount of the developers is not less than 2 wt % and less than 50 wt %: wherein R is a hydrogen atom, a halogen atom, a hydroxyl group, a lower alkyl group, an alkoxyl group, a cyano group, a nitro group, an aryl group or an aralkyl group, R in the number of m may be the same or different, m is an integer of 0 to 3, n is an integer of 0 to 3, and X and Y are each a hydrogen atom, an alkyl group or an aryl group.

Thermal recording material

The present invention is a thermally sensitive recording medium containing a thermally sensitive color developing layer containing a colorless or pale colored basic leuco dye and a color-developing agent as the main components on a substrate, wherein the thermally sensitive recording layer contains an acrylic polymer obtained by the copolymerization of an alkyl acrylate, alkyl methacrylate and vinylsilane as monomer components and a colloidal. Further, the present invention is a thermally sensitive recording medium, wherein the colloidal silica possesses a chain structure.

Heat-sensitive recording material

A thermally-sensitive recording medium having a protecting layer formed on a thermally-sensitive recording layer containing a colorless or pale-colored electron-donating leuco dye and electron-accepting color-developing agent. The thermally-sensitive recording layer is formed on a substrate, and the protecting layer contains a resin that contains a carboxyl group, epichlorohydrin resin and modified polyamine/amide resin, and the thermally-sensitive recording medium exhibits sufficient resistant against water such as rain or humidity, and further is excellent in printing run-ability (head debris and sticking) and sensitivity.

Thermally-sensitive recording medium

A coating paper which can be removed by water comprising a substrate paper of single layer or lamellar structure having two or more layers which has at least one water decaying layer containing 5-100 wt % of water insoluble fibrous carboxy alkyl cellulose and a water base color is coated on said substrate paper, wherein a coating layer and at least a part of substrate paper which is a supporter of said coating layer has a characteristic of easily removing, dispersion and dissolving by contact with water, and can provide a water decaying coating paper used preferably for an use of label for a returnable container which may easily remove by contact with water and excellent in printing aptitude and a method for preparation thereof can be provided.

Coating paper which can be removed by water and a method for preparation thereof

A thermally sensitive recording medium whose luster of printed part is excellent can be provided by a thermally sensitive recording medium of single layer or multi layers having at least a thermally sensitive recording layer that contains a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate comprising, containing a pigment whose aspect ratio is 30 or more in at least one layer formed on a substrate.

Thermally sensitive recording medium

Provided is a thermally sensitive recording medium which exhibits high recording sensitivity, high heat resistance of ground color part and excellent preserving stability of images. A thermally sensitive recording medium, comprising a thermally sensitive recording layer containing a colorless or pale colored basic colorless dye and an organic color developing agent as main components on a substrate, wherein said thermally sensitive recording layer contains at least one compound represented by general formula (1) and contains at least one compound selected from the group consisting of 3-{[(phenylamino)carbonyl]amino}benzensulfoneamide represented by formula (2), an ureaurethane compound represented by formula (3) and a copolymer of glysidilmethacrylate and vinyl monomer (average molecular weight is 9000-11000, epoxy equivalent is 300-600 and melting point is 110&#xb0; C. or less) as a stabilizer. (in the formula, Ris a hydrogen atom, a halogen atom, an alkyl group or alkoxy group) As a color developing agent a compound represented by general formula (4) is desirable. (in the formula, Ris an alkyl group of carbon number 1-4, an alkoxy group, a phenyl group or a hydrogen atom).

Thermal recording medium

A thermally sensitive recording medium containing a thermally sensitive recording medium providing an undercoating layer containing a pigment and a binder as main components and a thermally sensitive recording layer containing a colorless or pale colored basic leuco dye and a color developing agent, which reacts with said basic leuco dye, as main components on a substrate, wherein the undercoating layer contains carboxymethyl cellulose having an etherification degree of from 0.55 to 0.75 and hydroxyethyl cellulose from the view point of high effectiveness.

A thermally sensitive recording medium including on a support a thermally sensitive color development layer containing: a compound represented by the following general formula (1) as an organic color developing agent; and an oxalate compound represented by the following general formula (2) as a sensitizer. (In the formula (1): M represents CO or NRCO; when M is CO, mis 1; and when mis 0 and M is NRCO, B is not 0.)

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Tokyo, Japan

Junpei Natsui