Chinese Academy of Sciences

Ningbo Juhua Chemical & Science Co., Ltd.

Junliang Zhong

Hui Chen

Jian Zhang

Jie Yang

Yong Yang

Yexin Zhang

Qiang Zhou

Linbing Xia

Chengjun Mu

Gang Wu

Jili Du

Xiuxiu Wang

A catalyst for continuous production of 1,1,1,3-tetrachloropropane through gas-solid reaction as well as a preparation method and use thereof are provided. The catalyst includes a zero-valent iron and phosphorus co-modified carbon material which includes a carbon material as a carrier, a zero-valent iron supported onto the carrier and serving as an active component, and a phosphate functional group formed on the surface of the carbon material. The preparation method includes: co-modifying a carbon material using a ferric salt and organic phosphorus to obtain the catalyst for continuous production of 1,1,1,3-tetrachloropropane through gas-solid reaction. The present application further provides a method for continuous production of 1,1,1,3-tetrachloropropane through gas-solid reaction. The catalyst provided in the present application integrates active component zero-valent iron and auxiliary component phosphate functional group on the carbon material, thereby realizing the continuous production of 1,1,1,3-tetrachloropropane on a gas-solid fixed bed reactor.

Catalyst for continuous production of 1,1,1,3-tetrachloropropane through gas-solid reaction as well as preparation method and use thereof

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Ningbo, China

Junliang Zhong