National Institute of Clean-and-low-carbon Energy

China Energy Investment Corporation Limited

China Investment Corporation Limited

Junjun Shan

Lisa Nguyen

Hui Wang

Hua Liu

Joshua Ryan Miles

Jihong Cheng

Joshua Miles

Louis Guillen

Aihua Zhang

Qi Sun

Anthony Ku

Yizhi Xiang

John Matsubu

Amin Sardar

Saydul Sardar

A catalyst that includes heterogeneous metal carbide nanomaterials and a novel preparation method to synthesize the metal carbide nanomaterials under relatively mild conditions to form an encapsulated transition metal and/or transition metal carbide nanoclusters in a support and/or binder. The catalyst may include confined platinum carbide nanoclusters. The preparation may include the treatment of encapsulated platinum nanoclusters with ethane at elevated temperatures. The catalysts may be used for catalytic hydrocarbon conversions, which include but are not limited to, ethane aromatization, and for selective hydrogenation, with negligible green oil production.

Hydrocarbon conversion processes using metal carbide nanomaterial catalysts

The present disclosure relates to the catalytic field, and discloses a catalyst system and a light hydrocarbon aromatization method, a carbon dioxide hydrogenation process and a method for enhancing the catalytic activity and/or lifetime of the catalyst during a heterogeneous catalysis process, the catalyst system comprising a porous material layer containing an active metal component and a molecular sieve layer. The catalyst system provided by the present disclosure exhibits desirable catalytic activity, stability, renewability and selectivity, thus has significant benefits.

Catalyst system and light hydrocarbon aromatization method, carbon dioxide hydrogenation process and method for enhancing catalyst lifetime

A catalyst for converting hydrocarbon, a method of making the same, and a method of using the same are provided. Such a catalyst includes a zeotype microporous material, a binder material, and a metal phosphide, which can be in a range of from 0.01% to 10% by weight of a total weight of the catalyst. For example, such a catalyst can be used to convert light alkene or alkane into aromatic hydrocarbon such as benzene, toluene, xylenes, and a combination thereof. The alkene may be ethylene, propylene, butylene, or a combination thereof. The alkene may be supplied directly or from a stream converted from light alkane such as methane, ethane, propane, butane, or a combination thereof.

Catalyst for converting light olefin to aromatics, method of making and method of using the same

The present disclosure provides a modified catalyst, and preparation method and a method for producing aromatic hydrocarbons by aromatization of olefins using the modified catalyst. The modified catalyst comprises an acidic molecular sieve and an olefin aromatization active metal component, the total acid amount of the catalyst as measured by NH-TPD method is not higher than 0.35 mmol/g, and ratio of the strong acid to weak acid is within a range of 0.8-1.2.

Modified catalyst, method for preparing the same, and method for producing aromatic hydrocarbons by aromatization of olefins

Metal carbide nanomaterial catalysts and production method thereof

A method for aromatization of light alkanes, comprising: subjecting the light alkanes to dehydroaromatization reaction in the presence of aromatization catalysts including carriers and metal active components supported on the carriers, the metal active components include platinum, the carriers include zeolites and binders, and at least 80 wt. % of the metal active components are distributed on the zeolites. The method of the present disclosure may increase yield of the target product&#x2014;aromatic hydrocarbons, and the regenerated catalyst can still maintain high catalytic performance. In addition, the method of the present disclosure can meet the requirements of industrial applications.

Method for aromatization of light alkanes

A system and a method are provided for producing aromatics. Such a system includes a cracker unit configured to convert a light alkane into an olefin-containing hydrocarbon comprising at least one alkene, and an aromatization unit. The light alkane is selected from the group consisting of methane, ethane, propane, butane, and a combination thereof. The cracker unit is configured to at least partially feed the olefin-containing hydrocarbon into the aromatization unit. Such an olefin-containing hydrocarbon comprises at least 40 wt. % of the at least one alkene. The aromatization unit is used to convert the olefin-containing hydrocarbon therein into a product stream, which includes an aromatic hydrocarbon selected from the group consisting of benzene, toluene, xylenes, and a combination thereof.

System and process for converting light alkane to aromatics

The present discloses an aromatization catalyst, preparation process and application thereof and a low-carbon olefin aromatization process. The aromatization catalyst comprises a microporous material, a binder and a modifier; the microporous material is a zeolite molecular sieve, the binder is alumina, the modifier is phosphorus, and the molar ratio of the aluminum element in the binder to the phosphorus element is more than or equal to 1 and less than 5; the ratio of the acidity of the strongly acidic sites to the acidity of the weakly acidic sites of the olefin aromatization catalyst is less than 1.

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San Jose, CA, United States of America

Junjun Shan