Toyo Soda Manufacturing Co., Ltd.

Junji Arika

Hiroshi Miyazaki

Keiji Itabashi

Kazushige Igawa

Michiyuki Aimoto

Kazuaki Yamamoto

Masaru Takitani

Takaaki Tsukidate

Keiji Mitarai

Kosuke Takeshige

Mitsunobu Kashibe

Tadaaki Mori

Eiji Shiota

Yoshio Tamura

Susumo Otsuki

Disclosed is a zeolite having a composition of the following formula: xM.sub.2/n O.Al.sub.2 O.sub.3.(5-10)SiO.sub.2.yH.sub.2 O wherein M is at least one cation having a valency of n, and x is 0.8-2 and y is 0-10, and exhibiting an X-ray powder diffraction pattern shown in Table 1. This zeolite is prepared by a process wherein a reaction mixture comprising a silica source, an alumina source, an alkali source, a potassium source and water and having a composition satisfying the following molar ratios: SiO.sub.2 /Al.sub.2 O.sub.3 =6-40, OH/SiO.sub.2 =0.3-1, K.sub.2 O/M.sub.2 O=0.1-0.9 (M: the total of alkali metals), and H.sub.2 O/SiO.sub.2 =10-70, is crystallized at 120.degree. to 200.degree. C. with stirring. The zeolite is also prepared by a process wherein a granular amorphous aluminosilicate containing aluminum in an amount of 4 to 22 wt. % as Al.sub.2 O.sub.3 (on the anhydrous base), which is obtained by reacting an aqueous alkali metal silicate solution with an aqueous aluminum-containing solution, is incorporated in an aqueous alkali metal hydroxide solution and/or an aqueous alkali metal silicate solution, to form a mixture having a composition defined by the above-mentioned molar ratios, and the mixture is crystallized with stirring.

Process for preparation of zeolite OE having an offretite type structure

A faujasite zeolite of a high purity and a desired silica/alumina ratio is prepared by crystallizing at an elevated temperature a reaction mixture comprising a silica source, an alumina source, and an alkali metal source, wherein a transparent faujasite germ solution obtained by mixing and aging aqueous alkali metal silicate solution, an aqueous alkali metal aluminate solution and an aqueous alkali metal hydroxide solution is made present in the reaction mixture. The faujasite germ solution has an oxide molar composition represented by the following molar ratios:

Process for preparation of faujasite zeolite

A mordenite type zeolite having a high purity and a high SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio is prepared without using an organic or inorganic mineralizer, by a process wherein a homogeneous aluminosilicate containing 3 to 14% by weight, expressed in terms of Al.sub.2 O.sub.3 (calculated as the anhydride), of aluminum is crystallized in an aqueous solution of an alkali metal hydroxide.

Process for preparation of mordenite type zeolite

A ferrierite type zeolite having a high purity and a high SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio is prepared by reacting simultaneously and continuously an aqueous sodium and/or potassium silicate solution with an aluminum-containing solution to obtain a homogeneous phase compound of a granular amorphous aluminosilicate containing Al in an amount of 3 to 14 wt. % as calculated as anhydrous Al.sub.2 O.sub.3 and Na and/or K in an amount of 1 to 17 wt. % as calculated as anhydrous Na.sub.2 O and/or K.sub.2 O; and then, crystallizing the homogeneous phase compound in the form of a slurry in water or in an aqueous sodium hydroxide and/or potassium hydroxide solution. The molar ratio of K.sup.+ to the total of (K.sup.+ +Na.sup.+) in the slurry is 0.1 to 0.9.

Process for preparation of ferrierite type zeolites

A faujasite type zeolite having a high SiO.sub.2 /Al.sub.2 O.sub.3 ratio is prepared by simultaneously and continuously supplying an aqueous solution of an alkali metal silicate and an aqueous solution of an aluminum-containing compound whereby the alkali metal silicate is continuously reacted with the aluminum-containing compound to prepare a homogeneous phase compound of a granular amorphous aluminosilicate containing aluminum in an amount of 10 to 16% by weight, as Al.sub.2 O.sub.3 and based on the anhydride; and then, crystallizing the granular homogeneous phase amorphous aluminosilicate in an aqueous alkali metal hydroxide solution having a concentration of 4 to 10% by weight.

Process for preparation of high-silica faujasite type zeolite

A zeolite similar to ZSM-5, having lattice spacings (d-values), shown in Table 1, of the X-ray powder diffraction pattern, and a ferrierite zeolite are prepared by crystallizing a homogeneous phase compound of a granular amorphous aluminosilicate in water or in an aqueous solution of an alkali metal hydroxide and/or an alkali metal silicate.

Process for preparation of zeolites

A spherical micro-porous silica gel, which is characterized by having a mean diameter of 3-20 .mu.m, a bulk density of 0.28-0.41 g/cm.sup.3, a pore size of 18,000-100,000 and a specific surface area of 1,000-1,400 m.sup.2 /g and a production process therefor is characterized by employing (a) an aqueous solution containing SiO.sub.2 in which the primary particle diameter is not larger than 6 nm and the molar ratio of SiO.sub.2 to Na.sub.2 O is not larger than 5.5, (b) either stearic acid or a mixture of stearic acid and a non-ionic surface active agent of which HLB ranges from 3.5 to 6.0 as an emulsifier and (c) an organic acid as a gelling agent.

Spherical micro-porous silica gel and a production process thereof

An L type zeolite of a high purity is prepared by crystallizing an amorphous sodium alminosilicate compound containing a silicon component in an amount of 67 to 91 wt. % as SiO.sub.2 on the anhydrous basis in an aqueous potassium hydroxide solution.

Process for preparation of L type zeolites

A finely divided zeolite powder of high flowability is provided. This zeolite powder is represented by the formula: Na.sub.2 O.Al.sub.2 O.sub.3.nSiO.sub.2.wH.sub.2 O (n=1.8.about.3.0 and w=1.about.6) and comprises at least 99 weight % of particles having a particle size of 1-5 microns and has an aerated bulk density of from 0.3 to about 0.5 g/cc, a degree of cohesiveness of not larger than 56%, and a general flow index (expressed as the sum of indexes of the repose angle, spatula angle, compressibility and degree of cohesiveness) of from 30 to about 50. The zeolite powder is prepared by adding an alkali metal aluminate to an aqueous zeolite slurry containing 3052 wt. % of zeolite (an anhydride) and having pH of not higher than 12.8; adjusting the pH of the slurry to a value not higher than 11; and then, drying the slurry. The zeolite powder is useful as a builder for detergent.

Zeolite powder having high flowability, process for preparing same and

Titanium carbonitride of a high purity and in a fine powder form can be produced by maintaining a mixture of titanium halide and carbon at a temperature of from 700.degree. C. to 1,800.degree. C. in the presence of a reducing substance, such as aluminum or an aluminum-titanium alloy, in a nitrogen-containing gaseous atmosphere.

Process for producing titanium carbonitride

Chain structured corpuscular calcium carbonate is produced by a carbonation of calcium hydroxide suspended in water in the presence of a chelating agent and a water soluble metal salt.

Process for producing chain structured corpuscular calcium carbonate

An alkali carbonate containing a fluorine compound is purified by dissolving the crude alkali carbonate in an aqueous solution or suspension of magnesium bicarbonate in order to transfer the fluorine impurity into the resulting colloidal flocculated precipitate whereby the fluorine is substantially separated from the aqueous solution of the alkali carbonate.

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Tokuyama, Japan

Junji Arika