Sunallomer Ltd.

Showa Denko Kabushiki Kaisha

Hiroshima University

Basell Poliolefine Italia, S.p.a.

Junichiro Washiyama

Takeshi Nakajima

Masamichi Hikosaka

Kiyoka Okada

Anteo Pelliconi

Koji Yamada

Hideharu Kimura

Akihiro Otsubo

Kaori Watanabe

Tetsuo Yasuda

Yutaka Yokoyama

Hiroshi Takenouchi

Enea Garagnani

Motoyuki Hirata

Kazuhiko Minowa

Shingo Ueno

Shigenobu Ishihara

Masamitsu Yamauchi

Chikara Aoyama

Yuka Akiyama

A method for secondary-molding a polymer nano oriented crystal material in accordance with an embodiment of the present invention includes the steps of: heating the polymer nano oriented crystal material so that the polymer nano oriented crystal material changes into a mobile phase or a melt having a dense entanglement network structure; molding the polymer nano oriented crystal material which changed into the mobile phase or the melt including the dense entanglement network in the step; and cooling the polymer nano oriented crystal material, which has undergone the step, until the polymer nano oriented crystal material changes into an ordered phase.

Method for secondary molding of polymer NANO oriented crystal material

A process and apparatus for manufacturing a crystalline resin film or sheet. This manufacturing apparatus includes: an extruder that melts crystalline resin while supplying it; a gear pump that is provided on the downstream side of the extruder; a die which is provided on the downstream side of the gear pump, and which has a slit-shaped aperture; a cooling apparatus which cools film-shaped or sheet-shaped crystalline resin (A) discharged in a melted state from the die to a temperature which is not less than the crystallization temperature but not more than the melting point; and a pair of pinch rolls that press-roll between them the film-shaped or sheet-shaped crystalline resin (B) which has passed through the cooling apparatus (), wherein the pair of guide rolls are positioned such that the thickness of the film-shaped or sheet-shaped crystalline resin (B) which has passed through the cooling apparatus is between 1.3 and 8.0 times the thickness of the film or sheet (C, D) after it has been press-rolled.

Process and apparatus for producing crystalline resin film or sheet

A polymer sheet according to at least one embodiment of the present invention is a polymer sheet whose main component is oriented nanocrystals of a polymer, and which satisfies the following conditions (I), (II), and (III): (I) having a crystallinity of not less than 70%; (II) having a tensile strength at break of not less than 100 MPa and a tensile modulus of not less than 3 GPa; and (III) having an average thickness of not less than 0.15 mm. According to at least one embodiment of the present invention, it is possible to provide a polymer sheet excelling in properties such as mechanical strength, heat tolerance, and transparency, particularly a polymer sheet having excellent properties such as mechanical strength, heat tolerance, and transparency in general-purpose plastics such as polypropylene.

Polymer sheet and method for producing same

A masterbatch composition comprising (1) 10-50 wt % of a crystalline propylene homopolymer and (2) 50-90 wt % of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt %, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 d/Lg, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.

Polyolefin masterbatch for preparing impact-resistant polyolefin articles

A masterbatch composition, a polyolefin composition prepared from the masterbatch and articles prepared from the polyolefin composition. The masterbatch contains (percent by weight) from 20% to 90% of A) a crystalline polypropylene containing from 25% to 75% of a fraction A having a melt flow rate MFR of from 0.5 to 10 g/10 min., and from 75% to 25% of a fraction A having a melt flow rate MFR such that MFR /MFR is from 30 to 2000; and from 10% to 80% of B) a copolymer of ethylene and at least one C -C &agr;-olefin, the copolymer containing from 10 to 70% of ethylene, the copolymer being soluble in xylene at room temperature, and having an intrinsic viscosity &lsqb;&eegr;&rsqb; of from 4 to 9 dl/g. Articles prepared from the polyolefin composition exhibit a good balance of physical properties and reduced surface defects such as tiger striping.

Polyolefin masterbatch and composition suitable for injection molding

A resin composition comprising (A) at least one heat-resistant resin, (B) at least one thermoplastic resin, (C) an antimony oxide, (D) at least one bromine-containing reaction product selected from the group consisting of (1) a compound having a molecular weight of from 1,200 to 6,000 and a bromine content of from 5.0 to 60% by weight which is obtained by reacting a bromine-containing epoxy compound and 1,3,5-tribromophenol, and (2) a compound obtained by reacting a bromine-containing epoxy compound having an epoxy equivalent of from 450 to 7,000 and a bromine content of from 5.0 to 52% by weight and an acrylonitrile-butadiene copolymer having a carboxyl group at the both terminals thereof and a molecular weight of from 1,000 to 10,000, and (E) at least one silicon-containing compound selected from the group consisting of (1) silicone oil, (2) a ladder silicone resin, and (3) an alkoxysilane having a mercapto group, a vinyl group or a methacryloyl group, is disclosed. The resin composition is excellent in heat resistance, impact resistance, flame retardancy, and molding properties.

Heat-resistant resin composition

An optical disk substrate is disclosed, which is molded from a terpolymer composed of (A) an aromatic vinyl monomer, (B) cyclohexylmaleimide, and (C) at least one compound selected from the group consisting of (meth)acrylonitrile, isobornyl (meth)acrylate and cyclohexyl (meth)acrylate, with the cyclohexyl maleimide being copolymerized in an amount of from 5 to 60 wt % of said terpolymer. The optical disk substrate exhibits high heat resistance, low water absorption and low birefringence.

Optical disk substrate

Growing community of inventors

Kawasaki, Japan

Junichiro Washiyama