Toyo Seikan Kaisha, Ltd.

Junichi Matsuo

Kozaburo Sakano

Shigezo Nohara

Jinichi Yazaki

Sadao Hirata

Takeshi Sugimoto

Isao Tanikawa

Yoshimichi Ohkubo

Masami Hirano

Isamu Takeda

An injection-molded body comprising a layer of an olefin/vinyl alcohol copolymer having a very high molecular weight is obtained by melt-kneading a composition comprising (i) a high-molecular-weight olefin/vinyl alcohol copolymer having a melt flow rate of 0.4 to 6.0 g/10 min as determined at 190.degree. C. and a vinyl alcohol content of 40 to 80 mole % and (ii) a low-molecular-weight olefin/vinyl alcohol copolymer having a melt flow rate of 3.0 to 60 g/10 min as determined at 190.degree. C., which is higher by at least 0.5 g/10 min than that of the high-molecular-weight ethylene/vinyl alcohol copolymer (i), and a vinyl alcohol content of 45 to 85 mole % at a weight ratio of from 98/2 to 40/60, and injecting the melt-kneaded composition into a mold through an orifice.

Injection-molded body of olefin/vinyl alcohol copolymer and process for

Process for preparation of injection molded body of olefin/vinyl alcohol

A process for the production of a multi-layer pipe to be used for formation of a bottle by draw-blow-forming, comprising forming by co-extrusion a pipe having inner and outer layers of a polyester composed mainly of ethylene terephthalate units and an intermediate layer of an oxygen-barrier resin interposed between the inner and outer layers, an adhesive resin layer is preferably interposed between every two adjacent layers. The co-extruded multi-layer pipe in the molten state so that the diameter of the pipe is sized is uniform. The process continues by cooling the outer portion of the molten multi-layer pipe by contact with water and simultaneously introducing an inert gas or an inert gas containing a water mist into the interior of the pipe to thereby cool the inner portion of the pipe and prevent oxidation in the pipe A. Multi-layer pipe prepared according to this process is excellent in the transparency and the draw-formability into a multi-layer drawn bottle.

Laminate preform for a multi-layer polyester bottle

An improved liquid transfusing bottle made of flexible material of the type using no air venting needle. It includes a barrel portion, a shoulder portion and a bottom portion and parting lines extend on both the side faces in the vertical direction. The barrel portion is formed with ribs or recessed area of which contour line is so designed that a distance as measured from the parting line decreases toward the center part of the bottle from the shoulder portion or the bottom portion. As a residual volume of liquid in the bottle decreases, the barrel portion is deformed in the flattened configuration along the contour lines of the ribs or the recessed parts in such a manner that the shorter diameter thereof is reduced. Deformation of the barrel portion is achieved without any occurrence of twisting, breaking or the like of the bottle and liquid in the bottle is smoothly discharged therefrom at a constant speed during operation of transfusion.

Liquid transfusing bottle

A process for the production of a multi-layer pipe to be used for formation of a bottle by drawblow-forming, comprising forming by co-extrusion a pipe having inner and outer layers of a polyester composed mainly of ethylene terephthalate units and an intermediate layer of an oxygen-barrier resin interposed between the inner and outer layers. An adhesive resin layer is preferable interposed between every two adjacent layers. The co-extruded multi-layer pipe is sized in the molten state so that the diameter of the pipe is uniform. The process continues by cooling the outer portion of the molten multi-layer pipe by contact with water and simultaneously introducing an inert gas or an inert gas containing a water mist into the interior of the pipe to thereby cool the inner portion of the pipe and prevent oxidation in the pipe. A multi-layer pipe prepared according to this process is excellent in the transparency and the draw-formability into a multi-layer drawn bottle.

Process for production of multi-layer pipes for draw-forming

Disclosed is a hot-melt adhesive composed of a composition comprising an acid-modified olefin resin formed by graft modification of an ethylenically unsaturated carboxylic acid or its anhydride or a resin composition containing said modified olefin resin and an oxirane ring-containing compound, wherein said composition has a carbonyl group concentration of 1 to 600 millimoles per 100 g of the composition and an oxirane oxygen concentration of 0.01 to 50 millimoles per 100 g of the composition.

Hot-melt adhesive as intermediate layer of a laminate structure

Hot-melt adhesive

Disclosed is a multi-layer plastic vessel comprising a laminate including at least one layer composed mainly of a moisture-resistant thermoplastic resin, at least one layer composed mainly of an ethylene-vinyl alcohol copolymer and a thermoplastic resin adhesive layer interposed between both the resin layers, wherein said adhesive layer is composed of a composition comprising an acid- or acid anhydride-modified olefin resin and an epoxidized unsaturated carboxylic acid ester.

Growing community of inventors

Yokohama, Japan

Junichi Matsuo