Matsushita Electric Industrial Co., Ltd.

Mitsui Minings & Melting Co., Ltd.

Kuraray Co., Ltd.

Fuji Seal, Inc.

Nihon Junyaku Co., Ltd.

Junichi Asaoka

Yuji Mototani

Toyohide Uemura

Jun Miyoshi

Tomotaka Motomura

Shuji Tsuchida

Tomiko Yamaguchi

Yuri Kojima

Yoji Kajikawa

Hiroyuki Kawai

Shigeto Noya

Hideo Hayashi

Yasuhiko Shoji

Takeshi Kyogane

Isao Kubo

Takeshi Okubo

Tetsuo Hata

Toshikazu Kaneko

Masakazu Hirayama

Hirofumi Iwaki

Shingo Nakanishi

Akira Ota

Masanobu Abe

Yoshio Kino

Tomoyasu Sonetaka

Joji Nishimura

Hitoshi Tanaka

Noriyuki Yanagawa

Carl David Walton

Hiroshi Touma

A heat sensitive jacket label for a battery is disclosed. It comprises a base made of a heat-shrinking film, a metal layer provided on a back surface of the base, a heat-resistant insulating layer provided on the metal layer, and a heat sensitive adhesive on the insulating layer. The base heat-shrinks at a temperature at least 15.degree. C. higher than a temperature for effecting adhesion of the heat sensitive adhesive.

Heat sensitive jacket label for battery and battery with the same

An alkaline battery using a mercury free zinc alloy powder as an anode active material is disclosed. It has a gelled anode which comprises silicon and zinc alloy powder containing at least one of a) aluminum and b) calcium, c) bismuth in combination with calcium.

Alkaline battery

Vibration and shock resistance of alkaline batteries provided with a gel type negative electrode comprising a zinc alloy powder, a gelling agent and an alkaline electrolyte can be improved by using the following three gelling agents in combination in the gel type negative electrode, namely, a crosslinked polyacrylate type water-absorbing polymer having a dispersion viscosity at 25.degree. C. of at least 15,000 cps as a 0.5 wt % aqueous solution and having a particle size of mainly 100-900 microns, a crosslinked and branched type polyacrylic acid or a salt thereof having a dispersion viscosity at 25.degree. C. of at least 15,000 cps as a 0.5 wt % aqueous solution and having a particle size of mainly 100 microns or smaller, and a granular crosslinked and branched type polyacrylic acid or a salt thereof having a dispersion viscosity at 25.degree. C. of at least 15,000 cps as 0.5 wt % aqueous solution and having a particle size of mainly 100-900 microns. The vibration and shock resistance can further be improved by further adding to the gel type negative electrode at least one of oxides, hydroxides and sulfides of a metal selected from indium, tin and bismuth.

Alkaline battery having a gelled negative electrode

An alkaline battery having excellent discharge characteristics and higher discharge capacity with an increase in its internal resistance being suppressed is disclosed. The alkaline battery has a positive electrode active material which comprises primarily manganese dioxide and electroconductive carbon material. The electroconductive carbon material comprises expanded graphite particles having an average particle size in the range from 0.5 to 15 .mu.m, and the content of the expanded graphite particles is in the range from 2 to 8% by weight based on the solids in the positive electrode active material.

Alkaline manganese battery

A separator for alkaline batteries comprising as at least part of the main fibers a fibrilated product of cellulose fiber obtained by dissolving cellulose in a solvent and depositing cellulose directly. As another main fiber, preferably an extra fine synthetic fiber, particularly preferably a polyvinyl alcohol synthetic fiber is used. The binder is preferably polyvinyl alcohol. Also provided is an alkaline battery wherein such a separator is used. Preferably, the above cellulose fiber is cellulose fiber whose wet Young's modulus is 20 g/d or more and orientation degree .DELTA.n is 42.times.10.sup.-3 or more.

Separator for alkaline batteries

A non-amalgamated zinc alloy powder for use in an alkaline cell which consists of elements component selected from among the following combinations (1) to (3):

Zinc alloy powder for alkaline cell and method for production of the same

A non-amalgamated zinc alloy powder for use in an alkaline cell which comprises 1 ppm or less of iron and an elemental component selected from among the following combinations (1) to (5):

An alkaline cell having a gelled zinc negative electrode solely or mainly using, as a gelling agent to hold a zinc powder in an alkaline electrolyte, a granular crosslinking type branched polyacrylic acid, polymethacrylic acid or salts thereof. This gelling agent, holding an alkaline electrolyte, swells and properly maintains the thickness of the electrolyte, whereby the electrolyte can be sufficiently fed to a cell reaction portion and the alkaline cell is imparted with excellent drop resistance and shelf stability.

Alkaline cell with gelled anode

The present invention provides a cylindrical alkaline battery comprising a positive electrode case of a cylindrical form having an opening at one end and accommodating an electricity-generating element comprising a positive electrode, a negative electrode, a separator and an alkaline electrolytic solution, an insulating gasket provided at the opening of the positive electrode case, a bottom plate being the negative electrode terminal provided on the gasket, and a heat-shrinkable member such as shrink tube or the like covering the outer surface of the positive electrode case. In this battery, the opening end of the positive electrode case and the outer surface of the battery extending therefrom are covered with an electrical insulating film. The presence of the electrical insulating film prevents the exterior short circuit between the positive electrode case and the bottom plate being the negative electrode terminal which may occur when the metal material of the case opening is exposed by the peeling or abnormal shrinkage of the heat-shrinkable member. The present invention also provides a cylindrical alkaline battery comprising a reinforcing washer provided between the bottom plate being the negative electrode terminal and the gasket. In this battery, electric insulation is established between the bottom plate being the negative electrode terminal and the washer or between the gasket and the washer and the presence or the electric insulation cuts off the possible electric reaction route forming a local cell and prevents the resultant leakage of the electrolytic solution.

Cylindrical alkaline batteries

A dry cell of the type enclosing therein an electrolyte mainly consisting of zinc chloride, wherein in order to ensure the more secure air- and liquid-tightness a filler or sealing agent is filled into the space between a plastic top seal and a metal top seal to seal a carbon electrode extended out of the plastic top and the upper end portion of a plastic tube covering the top surface of the plastic top seal, whereby the longer shelf life may be ensured.

Dry cell

Growing community of inventors

Ikoma, Japan

Junichi Asaoka