Lg Chem, Ltd

JungMin Han

Sung-Kyun Chang

WonSeok Chang

Je Young Kim

Hong Kyu Park

WonSeok Jang

Disclosed is an anode for secondary batteries comprising a combination of an anode active material having a relatively low charge/discharge voltage and a relatively low hardness (A) and an anode active material having a relatively high charge/discharge voltage and a relatively high hardness (B), wherein the anode active material (A) is surface-coated with carbon having a high hardness or a composite thereof, and a particle size of the anode active material (B) is smaller than a size of a space formed by the anode active materials (A) arranged in a four-coordination. The anode provides an electrode that prevents lithium precipitation caused by overvoltage, improves ionic conductivity as well as electric conductivity and exhibits superior capacity.

Anode for secondary battery

Disclosed is a method including (a) mixing a precursor of a material for preparing at least one material selected from the group consisting of low crystalline carbon and amorphous carbon with a hydrophilic material including an oxide capable of intercalating and deintercalating ions, followed by purification to prepare a mixture for coating, (b) mixing the mixture for coating with a crystalline carbon-based material to prepare a core-shell precursor in which the mixture for coating is coated on a core including the crystalline carbon-based material, and (c) calcining the core-shell precursor to carbonize the material for preparing the at least one material selected from the group consisting of low crystalline carbon and amorphous carbon into the at least one material selected from the group consisting of low crystalline carbon and amorphous carbon.

Method for preparing anode active material

Disclosed is a method including (a) mixing a precursor of a material for preparing at least one material selected from the group consisting of low crystalline carbon and amorphous carbon with a hydrophilic material, followed by purification to prepare a mixture for coating, (b) mixing the mixture for coating with a crystalline carbon-based material to prepare a core-shell precursor in which the mixture for coating is coated on a core including a crystalline carbon-based material, and (c) calcining the core-shell precursor to carbonize the material for preparing the at least one material selected from the group consisting of low crystalline carbon and amorphous carbon into the at least one material selected from the group consisting of low crystalline carbon and amorphous carbon.

Disclosed is a method including (a) mixing a precursor of a material for preparing at least one material selected from the group consisting of low crystalline carbon and amorphous carbon with a metal and/or a non-metal capable of intercalating and deintercalating ions, followed by purification to prepare a mixture for coating, (b) mixing the mixture for coating with a crystalline carbon-based material to prepare a core-shell precursor in which the mixture for coating is coated on a core including the crystalline carbon-based material, and (c) calcining the core-shell precursor to carbonize the material for preparing the at least one material selected from the group consisting of low crystalline carbon and amorphous carbon into the at least one material selected from the group consisting of low crystalline carbon and amorphous carbon.

Disclosed are an anode active material for secondary batteries, capable of intercalating and deintercalating ions, the anode active material including a core including a crystalline carbon-based material, and a composite coating layer including one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon, and a hydrophilic material containing oxide capable of intercalating and deintercalating ions, wherein the composite coating layer includes a matrix comprising one component selected from (a) the one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon and (b) the hydrophilic material containing oxide capable of intercalating and deintercalating ions, and a filler including the other component, incorporated in the matrix, and a secondary battery including the anode active material.

Anode active material and secondary battery comprising the same

Disclosed are an anode active material for secondary batteries, capable of intercalating and deintercalating ions, comprising a core comprising a crystalline carbon-based material and a composite coating layer comprising one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon, and a metal and/or a non-metal capable of intercalating and deintercalating ions, wherein the composite coating layer comprises a matrix comprising one component selected from one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon and a metal and/or a non-metal capable of intercalating and deintercalating ions, and a filler comprising the other component, incorporated in the matrix, and a secondary battery comprising the anode active material.

Disclosed are an anode active material for secondary batteries, capable of intercalating and deintercalating ions, the anode active material including a core including a crystalline carbon-based material, and a composite coating layer including one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon, and a hydrophilic material, wherein the composite coating layer includes a matrix comprising one component selected from one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon, and a hydrophilic material, and a filler including the other component, incorporated in the matrix, and a secondary battery including the anode active material.

Disclosed is a method for preparing an anode active material comprising a core composed of a crystalline carbon-based material, and a composite coating layer comprising (a) mixing a precursor for a raw material of one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon with silicon oxide enabling intercalation and deintercalation of ions, followed by purification, to prepare a mixture for coating, (b) mixing the mixture for coating with a crystalline carbon-based material to prepare a core-shell precursor comprising the raw material mixture for coating applied to the core composed of the crystalline carbon-based material, and (c) baking the core-shell precursor to carbonize the raw material of the one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon into the one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon.

Process for preparation of anode active material

Disclosed are an anode active material for secondary batteries, capable of intercalating and deintercalating ions, the anode active material including a core including a crystalline carbon-based material, and a composite coating layer including one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon, and silicon oxide capable of intercalating and deintercalating ions, wherein the composite coating layer includes a matrix comprising one component selected from (a) the one or more materials selected from the group consisting of low crystalline carbon and amorphous carbon and (b) the silicon oxide capable of intercalating and deintercalating ions, and a filler including the other component, incorporated in the matrix, and a secondary battery including the anode active material.

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Seoul, South Korea

JungMin Han