Lg Chem, Ltd

Jung-A Lee

Eun-Jung Lee

Boram Lee

Choong-Hoon Lee

Seung-Whan Jung

Jong-Joo Ha

Bo-Ram Lee

Bun-Yeoul Lee

Don-Ho Kum

Dong-Kyu Park

Ki-Su Ro

Byung-Kwon Lim

Seong-Jin Kim

Sung-Soo Park

Cheon-Il Park

Beom-Doo Seo

Choong-Hoon c/o Lg Chem Ltd Lee

The present invention relates to a method of producing an elastomer. Specifically, the method of producing an elastomer according to the present invention comprises a step of polymerizing ethylene, propylene, and optionally, a diene monomer in the presence of a catalyst composition containing a transition metal compound. The method of producing an elastomer according to the present invention makes it possible to prepare a high molecular weight, ethylene-propylene or ethylene-propylene-diene, elastic copolymer at a high temperature.

Method for producing an elastomer using a transition metal catalyst

The present invention provides a novel transition metal complex where a monocy-clopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex.

Method for preparing transition metal complexes, transition metal complexes prepared using the method, catalyst composition containing the complexes

The present invention relates to a preparation method of olefin polymers using a catalyst composition containing a transition metal compound. In detail, the present invention provides a preparation method of olefin polymer using a catalyst composition comprising a transition metal compound, wherein the preparation method comprises introducing a scavenger to a continuous solution polymerization reactor in a specific range of amount to give the olefin polymer with good productivity.

Process for preparation of olefin polymers

The present invention relates to an ethylene-alpha olefin copolymer comprising long chain branches (LCB), while having a narrow molecular weight distribution. The ethylene-alpha olefin copolymer can be prepared by a continuous solution polymerization process using an activated catalyst composition containing a Group 4 transition metal compound having a monocyclopentadienyl ligand, to which a quinoline amino group is introduced.

Long chain-branched ethylene-alpha olefin copolymer

The present invention relates to a novel cyclopentadienyl compound, a fourth group transition metal compound having the cyclopentadienyl compound, a method of preparing the fourth group transition metal compound, a method of preparing an olefin polymer by using the fourth group transition metal compound, and an olefin polymer prepared by using the method.

Fourth group transition metal compound having cyclopentadienyl ligand, method of preparing compound, and method of preparing olefin polymer using compound

The present invention provides a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex.

The present invention relates to a catalyst composition comprising a novel structure of a Group 4 transition metal compound, to a method for preparing the same, and to a method for preparing a polyolefin using the catalyst composition. The method for preparing a polyolefin according to the present invention can be used for preparing a polyolefin having a high molecular weight and high copolymerizability with a high activity even at a high polymerization temperature and for preparing a polyolefin having a double composition distribution.

Catalyst composition comprising Group 4 transition metal complexes and method for preparing polyolefins using the same

The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound according to the present invention is configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge. The binuclear transition metal compound according to the present invention is configured such that the two bridged mononuclear transition metal compounds configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge are linked via a bridging group located at the phenylene bridge. According to the present invention, the mononuclear transition metal compound, the binuclear transition metal compound, the organic amine or phosphorous compound can be prepared in a simple manner by using suzuki-coupling reaction with a high yield.

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Daejeon, South Korea

Jung-A Lee