Lg Chem, Ltd

Jun Kyu Han

Dong Hyun Ko

Kyong Yong Cha

Ye Seul Hwang

Myung Ji Suh

Sang Jin Han

Dae Heung Choi

Jun Han Kang

Hyun Kil Nam

Joo Hyuck Lee

Sun Hwan Hwang

Seong Min Kim

Sunhwan Hwang

Seongmin Kim

Myungji Suh

Daeheung Choi

Dae Chul Kim

Se Won Baek

Yoon Jae Min

Kyung Moo Lee

Joohyuck Lee

Hyunseok Nam

Jaewon Jeong

Sung June Cho

San Jin Han

Kyoung Yong Cha

Hyun Seok Nam

The present specification relates to a method comprising: (A) mixing a ferrite-based catalyst molded article with diluent material particles; and (B) adding the mixture to a catalyst reactor, and a method for preparing butadiene using the same.

Catalyst loading method and method for preparation of butadiene by using same

A method for manufacturing a catalyst for oxidative dehydrogenation reaction, a catalyst for oxidative dehydrogenation reaction, and a method for manufacturing butadiene using the same.

Method for producing catalyst for oxidative dehydrogenation reaction, catalyst for oxidative dehydrogenation reaction, and method for producing butadiene using same

Provided is a catalyst for oxidative dehydrogenation, a method of preparing the catalyst, and a method of performing oxidative dehydrogenation using the catalyst. The catalyst for oxidative dehydrogenation has improved durability and fillability by including a porous support coated with a metal oxide (ABO) according to Equation 1:wt %+wt %=100 wt %,&#x2003;&#x2003;&#x3c;Equation 1&#x3e;

Catalyst for oxidative dehydrogenation, method of preparing catalyst, and method of performing oxidative dehydrogenation using catalyst

A method for preparing a metal complex catalyst by (A) obtaining a precipitate by bringing a metal precursor solution comprising a zinc (Zn) precursor, a ferrite (Fe) precursor, and water into contact with a basic aqueous solution; (B) obtaining a zinc ferrite catalyst by filtering and calcining the precipitate; and (C) supporting an acid onto the zinc ferrite catalyst, and a metal complex catalyst prepared thereby.

Method for producing metal complex catalyst, and metal complex catalyst produced by same

The present specification provides a method for preparing 1,3-butadiene, the method comprising: (A) obtaining a first product comprising a light component, 1,3-butadiene, and a heavy component from a reactant comprising butene; (B) separating the heavy component from a second product comprising the 1,3-butadiene and the light component by condensing the heavy component after heat exchanging the first product; and (C) separating concentrated heavy component by reboiling the condensed heavy component.

Method for preparing 1,3-butadiene

A method of preparing a catalyst for oxidative dehydrogenation that includes coprecipitation and injecting inert gas or air at a specific time point to reduce the ratio of an inactive &#x3b1;-FeOcrystal structure, thereby improving the activity of the catalyst. Also provided is a method of performing oxidative dehydrogenation using the catalyst. When oxidative dehydrogenation of butene is performed using the catalyst, side reaction may be reduced, and selectivity for butadiene may be improved, providing butadiene with high productivity.

Method of preparing catalyst for oxidative dehydrogenation and method of performing oxidative dehydrogenation using catalyst

The present invention relates to a catalyst for oxidative dehydrogenation and a method of preparing the same. More particularly, the present invention provides a catalyst for oxidative dehydrogenation having a porous structure which may easily control heat generation due to high-temperature and high-pressure reaction conditions and side reaction due to the porous structure and thus exhibits superior product selectivity, and a method of preparing the catalyst.

Catalyst for oxidative dehydrogenation and method of preparing the same

Provided is a method for producing a zinc ferrite catalyst, the method comprising: preparing a zinc precursor solution; preparing a ferrite precursor solution; obtaining a first precipitate by bringing the zinc precursor solution into contact with an alkaline solution; obtaining a second precipitate by adding the ferrite precursor solution to the first precipitate; and drying and firing the second precipitate after filtering the second precipitate.

Method for manufacturing zinc ferrite catalyst and zinc ferrite catalyst manufactured thereby

Disclosed are a catalyst for oxidative dehydrogenation and a method of preparing the same. More particularly, a catalyst for oxidative dehydrogenation of butene having a high butene conversion rate and superior side reaction inhibition effect and thus having high reactivity and high selectivity for a product by preparing metal oxide nanoparticles and then fixing the prepared metal oxide nanoparticles to a support, and a method of preparing the same are provided.

The present invention relates to a method of preparing a catalyst for oxidative dehydrogenation. More particularly, the present invention provides a method of preparing a catalyst for oxidative dehydrogenation providing superior selectivity and yield for a conjugated diene according to oxidative dehydrogenation by constantly maintaining pH of a coprecipitation solution using a drip-type double precipitation method to adjust an &#x3b1;-iron oxide content in a catalyst in a predetermined range.

Method of preparing catalyst for oxidative dehydrogenation

Provided is a catalyst for oxidative dehydrogenation, a method of preparing the catalyst, and a method of performing oxidative dehydrogenation using the catalyst. The catalyst for oxidative dehydrogenation has improved durability and fillability by including a porous support coated with a metal oxide (ABO) according to Equation 1 of the present invention, wherein the metal oxide exhibits activity during oxidative dehydrogenation. Therefore, when the catalyst is used in oxidative dehydrogenation of butene, the conversion rate of butene and the selectivity and yield of butadiene may be greatly improved.

A ferrite catalyst for oxidative dehydrogenation and a method of preparing the same. The ferrite catalyst is prepared using an epoxide-based sol-gel method, wherein a step of burning includes a first burning step, in which burning is performed at a temperature of 70 to 200&#xb0; C.; and a second burning step, in which burning is performed after the temperature is raised from a temperature in the range of greater than 200&#xb0; C. to 250&#xb0; C. to a temperature in the range of 600 to 900&#xb0; C.

Ferrite catalyst for oxidative dehydrogenation, method of preparing ferrite catalyst, and method of preparing butadiene using ferrite catalyst

A method of preparing butadiene that includes supplying butene, oxygen, nitrogen, and steam into a reactor filled with a metal oxide catalyst, and performing an oxidative dehydrogenation reaction at a temperature of 300 to 450&#xb0; C. as a reaction step; after the reaction step, maintaining supplying the butene, oxygen, nitrogen, and steam within a range within which the flow rate change of the butene, oxygen, nitrogen, and steam is less than &#xb1;40%, or stopping supplying the butene, and cooling the reactor to a temperature range of 200&#xb0; C. or lower and higher than 70&#xb0; C. as a first cooling step; and after the first cooling step, stopping supplying the butene, oxygen, nitrogen, and steam or stopping at least supplying the butene, and cooling the reactor to a temperature of 70&#xb0; C. or lower as a second cooling step.

Butadiene preparation method providing excellent catalyst reproducibility

The present invention relates to a method of preparing a catalyst for oxidative dehydrogenation. More particularly, the method of preparing a catalyst for oxidative dehydrogenation includes a first step of preparing an aqueous iron-metal precursor solution by dissolving a trivalent cation iron (Fe) precursor and a divalent cation metal (A) precursor in distilled water; a second step of obtaining a slurry of an iron-metal oxide by reacting the aqueous iron-metal precursor solution with ammonia water in a coprecipitation bath to form an iron-metal oxide (step b) and then filtering the iron-metal oxide; and a third step of heating the iron-metal oxide slurry. In accordance with the present invention, a metal oxide catalyst, as a catalyst for oxidative dehydrogenation, having a high spinel phase structure proportion may be economically prepared by a simple process.

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Daejeon, South Korea

Jun Kyu Han