Lubrizol Advanced Materials, Inc.

The B. F. Goodrich Company

Noveon IP Holdings Corp.

Julius Farkas

Charles P Jacobs

Ravi Ram Vedula

Joseph J Vontorcik

William F Masler, Iii

Carl J Long, Ii

Gary L Julian

William R Wilbur

Qiwei Lu

Donald A Meltzer

Dale R Hall

Joseph J Vontorcik, Jr

Dennis L Lawson

Gary F Wilson

Yona Eckstein

Yinbing Xia

Christopher A Sprague

A Donald Meltzer

James E Bryson, Jr

Chetan M Makadia

An Plessers

Mouh-Wahng Lee

Pallavi Kulkarni

Kenneth H Kim

Kyung J Kim

Ravi R Vedula

Alexander Jiaokai Jing

Ungyeong Jung

Larry E Hewitt

Anthony J Walder

Sridhar K Siddhamalli

A novel thermoplastic polyurethane composition is disclosed which comprise the reaction product of a polyisocyanate component, a polyol component, wherein the polyol component comprises a polyester comprising the reaction product of triethylene glycol and/or tetraethylene glycol with a diacid having 6 carbon atoms or fewer, and, optionally, a chain extender component.

Thermoplastic polyurethanes with high moisture vapor transmission and low water absorption

This technology relates to an integrated article that includes (a) a flexible foam region and (b) a non-foam region. The flexible foam region and the non-foam region are each made of a polyurethane composition. In some embodiments, the flexible foam region is a midsole, and wherein the non-foam region is an outsole. The flexible foam region is made from a flexible polyurethane injection molded foam. The non-foam region is made from a non-foamed polyurethane, which may be extruded or thermoformed. The invention relates to this integrated article, as well as the methods of making and using the same.

Integrated polyurethane article

A crystalline non-reinforced thermoplastic polyurethane composition having a high flexural modulus comprises 5% to 25% of a hydroxyl-functional polyol intermediate having a weight average molecular weight of 250 to 3000 and 75% to 95% hard segment comprising an unbranched, unsubstituted, linear chain diol and an aromatic isocyanate.

Crystalline high modulus thermoplastic polyurethane

The invention relates to a thermoplastic polyurethane fibers, and process of making the same, where the described fiber has good dyeability, and in some embodiments, good flame retardant properties. Such fibers are made from a composition that includes (a) a thermoplastic polyurethane itself comprising the reaction product of: (i) one or more polyols, (ii) one or more diisocyanates, (iii) one or more chain extenders, (iv) optionally one or more crosslinking agents, and (v) one or more functional modifiers wherein each said functional modifier is a reaction product of an aminodiol and a Bronsted acid.

Dyeable and flame-retarded thermoplastic polyurethane fibers

The present invention discloses a thermoplastic polyurethane which is comprised of the reaction product of (1) a hydroxyl terminated polyester intermediate, (2) a polyisocyanate, and (3) a glycol chain extender; wherein the hydroxyl terminated polyester intermediate is comprised of repeat units that are derived from 1,3-propylene glycol and a dicarboxylic acid; wherein the hydroxyl terminated polyester intermediate has a number average molecular weight from 500 to 10,000; and wherein the thermoplastic polyurethane includes hard segments that are the reaction product of the polyisocyanate and the glycol chain extender. This thermoplastic polyurethane is unique in that it has a greatly reduced tendency to bloom. This is highly desirable in applications where high clarity is desired because blooming causes articles containing the thermoplastic polyurethane to be hazy or foggy in appearance. Blooming can also reduce the ability of an article made with the thermoplastic polyurethane to be securely bound to another article with an adhesive.

Thermoplastic polyurethane with reduced tendency to bloom

The present invention discloses a thermoplastic polyurethane which is comprised of the reaction product of (1) a hydroxyl terminated intermediate, (2) a polyisocyanate, and (3) a glycol chain extender selected from the group consisting of ethylene glycol and propylene glycol; wherein the hydroxyl terminated intermediate is selected from the group consisting of hydroxyl terminated polyether intermediates and hydroxyl terminated polyester intermediates; wherein the hydroxyl terminated intermediate is comprised of repeat units that are derived from a branched glycol or is comprised of at least 2 different repeating units; wherein the thermoplastic polyurethane has a weight average molecular weight of at least 100,000 Daltons; wherein the thermoplastic polyurethane includes hard segments that are the reaction product of the polyisocyanate and the glycol chain extender; and wherein the hard segments represent from 10 to 40 weight percent of the total weight of the thermoplastic polyurethane.

Soft, elastic, plasticizer-free thermoplastic polyurethane and process to synthesize the same

Thermoplastic polyether polyurethane polymers are disclosed which are mixed with a crosslinking agent to achieve long run times in a melt spinning process to make elastic fibers. The crosslinking agent is preferably a polyether or polyester polyol reacted with a diisocyanate. A melt spinning process is also disclosed using a polyether polyurethane with a crosslinking agent. Long melt spinning run times can be achieved without experiencing excessive pressure buildup in the spinneret and fiber breakage. The thermoplastic polyether polyurethane polymers are made by reacting: (1) a blend of two or more hydroxyl terminated intermediates wherein one intermediate is a polyether intermediate and has a higher number average molecular weight than the other said polyether intermediates, and wherein the weighted average number average molecular weight of said blend is greater than 1200 Daltons; (2) at least one polyisocyanate; and (3) at least one hydroxyl terminated chain extender. Melt spun fibers disclosed have excellent dye pickup, bleach resistance, and color fastness. The melt spun fibers can be dyed with polyester fibers and retain excellent physical properties.

Melt spun polyether TPU fibers having mixed polyols and process

Breathable thermoplastic polyurethanes are prepared from the reaction of a polyol component, a polyisocyanate component, and a chain extender in the presence of a metal-free catalyst. The metal-free catalyst comprises a polyalcohol amine, a tertiary amine catalyst, or a combination thereof. The polyurethanes of the present invention are suitable for film applications as they form breathable films which are permeable to water vapor but not air or water. The polyurethane compositions are substantially metal-free, have low extractables, and excellent melt strength.

Organometallic-free polyurethanes having low extractables

A compatibilized blend of a thermoplastic elastomer and a polyolefin. The compatibilizer is a thermoplastic polyurethane formed by the reaction of a substantially hydrocarbon intermediate such as a polybutadiene polyol, a diisocyanate such as MDI, and an amine or diol chain extender such as neopentyl glycol. The compatibilizer has high amounts of soft segments therein and imparts improved properties to blends of a thermoplastic elastomer and polyolefin such as good impact resistance, good tensile strength, good tear resistance, and good delamination resistance.

Compatibilized blends of a thermoplastic elastomer and a polyolefin

The present invention discloses a novel polyurethane composition useful as a dispersing binder. The binder yields magnetic dispersions having high gloss values. Moreover, the polyurethane provides excellent hydrolytic stability. The polyurethane comprises a polyol, a diisocyanate a chain extender and an functional modifier formed of a reaction product of an aminodiol and Bronsted Acid.

Polyurethane composition for use as a dispersing binder

A low viscosity, diprimary amine-terminated reactive liquid polymer with low residual amine content, comprising the reaction product of a diprimary amine having the following formula

Low viscosity diprimary amine reactive modifiers for epoxy resins

The present invention is directed to a reactive diluent comprising a backbone portion and a pendant group portion. The backbone portion comprises at least two polymerizable sites, and the pendant group portion comprising a functional group having the following formula: ##STR1## wherein Z is an ethylenically unsaturated hydrocarbyl or substituted hydrocarbyl group containing from 2 to about 12 carbon atoms and wherein said pendant group is capable of a (2+2) cyclo-addition with another like pendant group of the above formula. The chain extending reaction site is preferably used in a polymerization reaction to provide a polymeric material, and the cross-linking reactive site is preferably used to create cross-linking as needed or desired.

Growing community of inventors

North Ridgeville, OH, United States of America

Julius Farkas