The Uab Research Foundation (the University of Alabama at Birmingham)

525 Solutions, Inc.

Streamline Automation LLC

Julia L Shamshina

Robin Don Rogers

Gabriela Gurau

Oleksandra Zavgorodnya

Roberto DiSalvo

Marcin Smiglak

Patrick S Barber

Rajkumar Kore

H Waite Dykes, Jr

Chris S Griggs

Steven P Kelley

Waduge Indika S Galpothdeniya

Methods for making metal particle-chitin composite materials are described. The methods can comprise contacting an ionic liquid with chitin, thereby forming a mixture; contacting the mixture with a non-solvent, thereby forming a chitin substrate in the non-solvent; collecting the chitin substrate from the non-solvent; deacetylating the collected chitin substrate, thereby forming a deacetylated chitin substrate; contacting the deacetylated chitin substrate with a metal salt, thereby forming an impregnated precursor composite material; and contacting the impregnated precursor composite material with a reducing agent, thereby reducing the metal salt to form a plurality of metal particles dispersed on the chitin substrate and forming the metal particle-chitin composite material.

Metal particle-chitin composite materials and methods of making thereof

Methods for separating chitin from a chitinous biomass are described, the methods comprising contacting the chitinous biomass with an ionic liquid to form a mixture comprising chitin; contacting the mixture with an aqueous solution of a kosmotropic salt, thereby coagulating the chitin and forming an biphasic system comprising an ionic liquid-chitin phase and an aqueous kosmotropic salt phase; separating the ionic liquid-chitin phase from the aqueous kosmotropic salt phase; and collecting the chitin from the separated ionic liquid-chitin phase, thereby forming a recycled ionic liquid.

Coagulation of chitin from ionic liquid solutions using kosmotropic salts

Disclosed are double salt ionic liquids that include at least one organic cation and at least two metal halide anions. Methods of making the double salt ionic liquids can include combining two or more metal halide containing salts, wherein the metal halide containing salts include at least one organic cation and at least two metal halide anions. The reaction between the two or more salts at any ratio allows fine tuning, rate of dissolution, solubility, and bioavailability of the double salt ionic liquids. The ionic liquids disclosed herein can be used as a catalyst for catalyzing a chemical reaction. The chemical reaction can be an acid catalyzed chemical reaction such as a Lewis acid catalyzed reaction, a Beckmann rearrangement reaction, a Meyer-Schuster rearrangement reaction, a heterocyclic synthesis, a reaction for biodiesel production, a mercury-catalyzed type reaction, or a hydrogen-fluoride catalyzed type reaction.

Mixed metal double salt ionic liquids with tunable acidity

Methods of separating chitin from a chitinous biomass that contains chitin and non-chitin material by a chemical pulping process that uses a protic ionic liquid or a composition comprising acid and base precursor molecules are described. Also described are methods for purifying chemically pulped chitin resulting in a pure chitin material with a high molecular weight and a higher degree of acetylation in comparison to traditional pulping and ionic liquid extraction based methods.

Chemical pulping of chitinous biomass for chitin

An energetic ionic liquid catalytic decomposition gas generator uses stoichiometric and nonstoiciometric mixtures of specific energetic ionic liquids and iridium catalyst. The catalyst temperature used and gas production versus ignition may be controlled by combining one or more cationic species with one or more anionic species of the ionic liquid(s).

Ionic liquid monopropellant gas generator

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Tuscaloosa, AL, United States of America

Julia L Shamshina