The Goodyear & Tire Rubber Company

Judy Chu

Paul Harry Sandstrom

David John Zanzig

Richard G Bauer

Joseph Frank Geiser

James Gregory Gillick

Dane Kenton Parker

David Andrew Benko

Thomas Walter Starinshak

Roger Neil Beers

Yen-How Huang

A method of treating a metallic cord to improve its ability to adhere to rubber is disclosed. The method involves contacting the metallic cord with a naphthenic oil containing from 1 to 53 percent by weight of a soluble cobalt salt and thereby deposit from 0.002 to 0.7 grams of cobalt per kilogram of steel to the metallic cord.

Method of treating metallic cord

Poly(p-phenylene-2,6-benzobisoxazole) (&ldquo;PBO&rdquo;) yarn or cord is first coated with a subcoat of a mixture of (a) an aliphatic polyglycidyl ether having a flash point greater than 150&deg; C. with enough OH-groups to be substantially water-soluble and (b) a vinyl pyridine-styrene-butadiene rubber latex (VPSBRL), then coated in a conventional RFL dip, yields a twice-coated PBO yarn; this yarn provides adhesive strength in sulfur-vulcanizable rubber which is substantially the same as, or better than, that provided by aramid yarn having the same physical dimensions and construction, and coated with an aromatic polyglycidyl ether.

Subcoat for poly (p-phenylene-2,6-benzobisoxazole) fibers

A process for adhering synthetic textile fibers to sulfur vulcanizable rubbers comprising the steps of (I) immersing the fibers in an aqueous solution which is comprised of (a) 1% to 4% by weight oxazoline polymer, (b) 0% to 4% alkylene glycol monoether and (c) 92% to 99% water to produce coated fibers; (II) drying the coated fibers to produce subcoated fibers; (III) subjecting the subcoated fibers to an RFL adhesive dip to produce dipped fibers; (IV) drying the dipped fibers to produce dried dipped fibers; (V) placing the dried dipped fibers in contact with a sulfur vulcanizable rubber; and (VI) curing the sulfur vulcanizable rubber while it is in contact with the dried dipped fibers. Also provided is a composite article made using the process.

Subcoat for fiber adhesion

This invention is based upon the discovery that cyclized polyisoprene polymers can be incorporated into tire tread compounds to improve traction, treadwear, and resistance to tear. It is further based upon the discovery that cyclized polyisoprene polymers can be blended with halobutyl rubber and/or natural rubber and can be utilized in tire innerliner formulations. The present invention more specifically discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of a sulfur cured rubber composition which is comprised of about 5 phr to about 50 phr of cyclized polyisoprene and about 50 phr to about 95 phr of at least one other rubbery polymer. The present invention further discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, an innerliner, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said innerliner is comprised of a sulfur cured rubber composition which is comprised of about 5 phr to about 50 phr of cyclized polyisoprene and about 50 phr to about 95 phr of at least one other rubbery polymer selected from the group consisting of natural rubber and halobutyl rubber.

Rubber blend containing cyclized polyisoprene

This invention relates to a latex for utilization in adhesive compositions for bonding synthetic fibers to natural or synthetic rubber. These latices can be produced at reduced cost and their utilization results in improved performance characteristics. This invention more specifically discloses a latex which is particularly useful for adhering synthetic fibers to rubber which is comprised of (a) water, (b) an emulsifier and (c) a polymer which is comprised of repeat units which are derived from (i) a conjugated diolefin monomer, (ii) a vinyl aromatic monomer, (iii) 2-vinylpyridine and (iv) a vinyl aldehyde monomer. The present invention further discloses a process for adhering synthetic textile fibers to sulfur vulcanizable rubbers comprising the steps of (I) immersing said fibers in an aqueous dispersion of (1) resorcinol, (2) formaldehyde and (3) a latex which is comprised of (a) water, (b) an emulsifier and (c) a polymer which is comprised of repeat units which are derived from (i) a conjugated diolefin monomer, (ii) a vinyl aromatic monomer, (iii) 2-vinylpyridine and (iv) a vinyl aldehyde monomer, to produce dipped fibers; (II) drying said dipped fibers to produce dried dipped fibers; (III) placing the dried dipped fibers in contact with the sulfur vulcanizable rubber; and (IV) curing the sulfur vulcanizable rubber while it is in contact with said dried dipped fibers.

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Hudson, OH, United States of America

Judy Chu