Bayer Aktiengesellschaft

The University of Western Ontario

Other

Austin Venture Partners, LLC

Judit E Puskas

Gerhard Langstein

Wolfgang Baade

Werner Obrecht

Oskar Nuyken

Christophe Paulo

Prince P Antony

Karin Weiss

Shahzad Barghi

Thomas Mulder

Roland Heinrich

Prince Antony

The present invention provides highly branched block copolymers comprising branched soft segments with a low glass-transition temperature (T ) and hard segments with a high T or crystalline melting point that exhibit thermoplastic elastomeric properties. More particularly the invention provides a highly branched block copolymer of a polyisoolefin and a polymonovinylidene arene characterized by having thermoplastic elastomeric properties wherein the aforesaid block copolymer comprises a highly branched polyisoolefin block and some of the branches of the aforesaid polyisoolefin block terminate in polymonovinylidene arene endblocks.

Arborescent thermoplastic elastomers and products therefrom

The present invention is directed to a method and apparatus of determining the degree of saturation of a decontamination-removing substance or adsorbent such as an alumina absorbent or activated charcoal. The method and apparatus is sufficiently sensitive to detect changes in the bulk specific electrical conductivity of the adsorbent.

Method and apparatus for monitoring adsorbent activity in situ

Initiators for carbocationic polymerization of olefins

A new class of initiators for inducing the cationic polymerization of olefins was discovered. These initiators, in conjunction with Lewis acids as coinitiators, effectively initiate the carbocationic polymerization of olefins. The new initiators are epoxides with the general formula

Highly branched polyisoolefines are produced according to the invention by the polymerization of isoolefines in a single-stage process, in solution, suspension or in the gas phase in the presence of bifunctional monomers which contain at least one group capable of cationic polymerization and at least one group which serves as an initiator for the cationic polymerization of isoolefines (inimer), at temperatures from +20 to -100.degree. C., optionally in the presence of inert, organic solvents, and in the presence of alkylalumoxanes (coinitiator).

Process for producing highly branched polyisoolefins

Polyisoolefins are produced according to the invention by polymerizing isoolefins having 4 to 16 carbon atoms, optionally with conjugated diolefins having 4 to 6 carbon atoms and/or cationically polymerizable, mono- or polyunsaturated, organic compounds having 4 to 16 carbon atoms in the presence of mixtures of carbon dioxide and linear, branched and/or cyclic C.sub.4 -C.sub.8 alkanes and in the presence of catalysts at temperatures of -70.degree. C. to +20.degree. C. and pressures of 1 to 70 bar, wherein the weight ratio of carbon dioxide to alkanes is 10:90 to 90:10. The process according to the invention largely prevents the formation of fouling on the reactor walls, so ensuring better removal of heat. Moreover, in accordance with the process according to the invention, the polyisoolefins obtained may be directly chemically modified once the carbon dioxide has been removed.

Process for the production of polyisoolefins

The production of C.sub.4 -C.sub.16 alkyl rubbers using the slurry process by copolymerisation of isoolefins having 4 to 16 carbon atoms with conjugated diolefins having 4 to 6 carbon atoms and/or cationically polymerisable, mono- or polyunsaturated organic compounds having 4 to 16 carbon atoms in the presence of methyl chloride and in the presence of Friedel-Crafts catalysts proceeds particularly advantageously by performing copolymerisation in the presence of linear, branched and/or cyclic alkanes.

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London, Canada

Judit E Puskas