Rohm and Haas Company

Dow Global Technolgoies LLC

Joy L Mendoza

Philippe P Maillot

Michael Stanley DeCourcy

Mingyu Ye

James Elder

Robert Michael Mason

Stacy W Hoy, Iv

Mark T Vandersall

Keith Frederick Briegel

James Jerrick Juliette

Stephen Bass

Steven John Skoog

Karen Ann Shaw

Jon Busick

Alan E Sopchik

Jamie J Juliette

Joseph Atkins

Michael Gene Woody

Michel Gene Woody

The present invention provides materials for improving the ignition of gaseous reactants in metal catalyzed oxidation reactions comprising a metal catalyst gauze, preferably, a platinum/rhodium catalyst gauze, having in contact therewith, from 0.5 to 1.5 wt. %, based on the weight of the metal catalyst gauze, of one or more pieces of previously used metal catalyst gauze. Further, methods of making the metal catalyst materials comprise shaping the pieces of previously used metal catalyst gauze and placing them equidistant from each other in contact with or on the surface of the metal catalyst gauze. And methods of using the materials comprise feeding into the reactor a gas mixture of oxygen or air and one or more reactant gases, and igniting the gas mixture at the surface of one or more or all of the pieces of previously used metal catalyst.

Activation energy reducers for catalytic oxidation of gaseous mixtures

The present invention provides methods comprising washing or, preferably, washing and neutralizing a sulfur acid containing crude MMA stream to generate a two phase stream containing at least methacrylic acid, methacrylamide (MAM), water and methanol, and an organic component containing methyl methacrylate and thereby form an aqueous component; including in any of the organic component, the aqueous component of a neutralized sulfur acid containing crude methyl methacrylate (MMA) stream or the organic component of a neutralized sulfur acid containing crude methyl methacrylate (MMA) stream one or more N-oxyl compound polymerization inhibitor; followed by separating the aqueous component from the organic component, thereby forming a treated crude MMA stream and an aqueous stream to remove residual (meth) acrylic acid.

Methods of using N-oxyl polymerization inhibitor in a wash settler for preparing methyl methacrylate

Fouling of an MMA process is reduced by strategically removing an aqueous slip stream.

Reduced fouling process for the production of methyl methacrylate

The present invention provides materials for improving the ignition of gaseous reactants in metal catalyzed oxidation reactions comprising a metal catalyst gauze, preferably, a platinum/rhodium catalyst gauze, having in contact therewith, from 0.25 to 1.5 wt. %, based on the weight of the metal catalyst gauze, of one or more pieces of previously used metal catalyst gauze. Further, methods of making the metal catalyst materials comprise shaping the pieces of previously used metal catalyst gauze and placing them equidistant from each other in contact with or on the surface of the metal catalyst gauze. And methods of using the materials comprise feeding into the reactor a gas mixture of oxygen or air and one or more reactant gases, and igniting the gas mixture at the surface of one or more or all of the pieces of previously used metal catalyst.

Fouling of an MMA process is reduced by acidifying a stream comprising recycled components.

Provided is a method for removing deposited solid residue from equipment used in the processing of (meth)acrylic acid or esters, including the steps of dissolving the solid residue in a cleaning solution comprising an organic carboxylic acid to produce a solid residue slurry; and removing the solid residue slurry from the equipment.

Method for cleaning a (meth)acrylate ester process tank

The present invention relates to recovery of aqueous (meth)acrylic acid by condensation of a (meth)acrylic acid-containing stream to produce aqueous (meth)acylic acid having a higher concentration of (meth)acrylic acid and a lower concentration of formaldehyde, i.e., not more than 0.1 weight %, than the aqueous (meth)acrylic acid produced using hithertofore known separation methods. The (meth)acrylic acid-containing stream may be the raw product stream of catalytic oxidation at least one C-Calkane or alkene.

Method for production of aqueous (meth)acrylic acid

The present invention relates to reducing corrosion of distillation equipment during azeotropic distillation of (meth)acrylic acid in the presence of dissolved copper, by providing aqueous (meth)acrylic acid having not more than 0.1% by weight formaldehyde, based on the total weight of the aqueous (meth)acrylic acid. The source of the copper may, for example, be copper-based polymerization inhibitors added to the aqueous (meth)acrylic acid and/or distillation equipment.

Method for production of purified (meth)acrylic acid

This invention relates to a method for inhibiting polymerization of (meth)acrylic acid and its esters using a polymerization inhibitor which comprises at least one reduced halide-content azine dye-based compound. A process for producing reduced halide-content azine dye-based compounds using ion exchange resin technology is also provided.

Method for inhibiting polymerization of (METH) acrylic acid and its esters using an inhibitor and a process for making a compound useful as such an inhibitor

Method for inhibiting polymerization of (meth)acrylic acid and its esters using an inhibitor and a process for making a compound useful as such an inhibitor

This invention relates to an improved catalyst system utilizing flow through radiation shielding of the reaction zone and to processes for using the catalyst system for the production of hydrogen cyanide. The process has decreased methane usage while maintaining yield of cyanide.

Growing community of inventors

Seabrook, TX, United States of America

Joy L Mendoza