Bridgestone Corporation

Joshua S Dickstein

Steven Luo

Zengquan Qin

Joshua P Abell

Dennis R Brumbaugh

Kevin Michael McCauley

Laura S Kocsis

Hyeonjae Kim

Kevin Mccauley

A method for preparing cis-1,4-polydienes, the method comprising the steps of preparing a preformed, active lanthanide-based catalyst, aging the active lanthanide-based catalyst for more than 5 days to thereby formed an aged catalyst, and introducing the aged catalyst and conjugated diene monomer to be polymerized to thereby form an active polymerization mixture in which the conjugated diene monomer is polymerized to form a polydiene having a reactive chain end.

Aged lanthanide-based catalyst systems and their use in the preparation of cis-1,4-polydienes

Embodiments of 1,4-polybutadiene rubber compositions useful at low temperatures are provided, wherein the 1,4-polybutadiene incorporated therein comprises a cis content of at least 85 to about 92%, a vinyl content of at about 1% to about 5%, and a trans content of about 3 to about 12%, and wherein the 1,4-polybutadiene has an enthalpy of melting &#x394;Hof about 5 to about 25 J/g&#xb0; C. as measured via differential scanning calorimetry (DSC).

Polybutadiene polymers and rubber compositions incorporating same for low temperature applications

A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing monomer to form a reactive polymer, and (ii) reacting the reactive polymer with an imine compound containing a cyano group.

Polymers functionalized with imine compounds containing a cyano group

A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer, and (ii) reacting the reactive polymer with an imine compound containing a cyano group.

A method for preparing cis-1,4-polydienes having useful resistance to cold flow, the method comprising the steps of preparing a polymerization system including a reactive polymer by introducing a lanthanide-based catalyst and a conjugated diene monomer and adding a Lewis acid to the polymerization system including a reactive polymer.

Cis-1,4-polydienes with improved cold flow resistance

A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer, and (ii) reacting the reactive polymer with a protected oxime compound containing a cyano group.

Polymers functionalized with protected oxime compounds containing a cyano group

A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer, and (ii) reacting the reactive polymer with an imine compound containing a heterocyclic group and a hydrocarbyloxy-substituted or silyloxy-substituted aryl group.

Polymers functionalized with heterocyclic imines

A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer, and (ii) reacting the reactive polymer with an unsaturated heterocycle containing an azolinyl group.

Polymers functionalized with unsaturated heterocycles containing an azolinyl group

A novel class of lanthanide metal salen complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers.

Lanthanide complex catalyst and polymerization method employing same

A novel class of lanthanide metal phenoxyimine complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers.

A process for preparing a polydiene, the process comprising the steps of: polymerizing conjugated diene monomer with a metallocene complex catalyst system within a polymerization mixture that includes less than 20% by weight of solvent based on the total weight of the polymerization mixture, where the metallocene complex catalyst system includes the combination or reaction product of: (a) metallocene complex, (b) an alkylating agent, and optionally (c) a non-coordinating anion.

Bulk polymerization process for producing polydienes

A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer; and (ii) reacting the reactive polymer with a protected hydrazone compound containing an acyl group.

Polymers functionalized with protected hydrazone compounds containing an acyl group

A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomers to form a reactive polymer, and (ii) reacting the reactive polymer with a protected polyhydrazone compound.

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Copley, OH, United States of America

Joshua S Dickstein