Largo Clean Energy Corp.

Raytheon Technologies Corporation

Vionx Energy Corporation

Joseph T Sullivan

Michael L Perry

Methods and systems for removing impurities from electrolyte solutions having three or more valence states. In some embodiments, a method includes electrochemically reducing an electrolyte solution to lower its valence state to a level that causes impurities to precipitate out of the electrolyte solution and then filtering the precipitate(s) out of the electrolyte solution. In embodiments in which the electrolyte solution is desired to be at a valence state higher than the precipitation valence state, a method of the disclosure includes oxidizing the purified electrolyte solution to the target valence.

Electrochemical-based purification of electrolyte solutions, and related systems and methods

A redox flow battery includes a redox flow cell, a supply/storage system external of the redox flow cell, and a controller. The supply/storage system includes first and second electrolytes for circulation through the redox flow cell. The first electrolyte is a liquid electrolyte having electrochemically active species with multiple, reversible oxidation states. The electrochemically active species can form a solid precipitate blockage in the redox flow cell. The controller is configured to identify whether there is the solid precipitate blockage in the redox flow cell and, if so, initiate a regeneration mode that reduces the oxidation state of the electrochemically active species in the liquid electrolyte to dissolve, in situ, the solid precipitate blockage.

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Hanover, NH, United States of America

Joseph T Sullivan