Rohm and Haas Company

Dow Global Technolgoies LLC

Arkema France

Morton International, Inc.

Basf Corporation

Joseph James Zupancic

William J Harris

Kalyan Sehanobish

Francois M Casati

William Hoy Heath

David Elmer Vietti

Amira A Marine

Wenwen Li

Tuoqi Li

Thorsten Schmidt

Paul G Clark

Mai Chen

Daniele Vinci

Larry Frank Brinkman

Matthew Martin Yonkey

Ronald J Lewarchik

Jie Wu

Jorge Jimenez

Michael John Zajaczkowski

Nathan Wilmot

Marc L Smith

Ken Kawamoto

Thomas F Kauffman

Paul A Cookson

Yinzhong Guo

Timothy A Morley

Ronald Scott Beckley

Pankaj Vinubhai Shah

Bradley Anson Jacobs

Chenyan Bai

Melinda L Einsla

Qiuyun Xu

Kevin K Miyake

Pavel Shutov

Elodie Hablot

Jack C Allman

Jeffrey Harold Deitch

Jonathan Barrus

Ludwik S Cygan

Marco Frasconi

James V Lang

Donald J Algrim

Doanld J Algrim

Pavel L Shutov

Zhizhong Wu

Hanno Van Der Wal

Thomas Frederick Kauffman

Luis Zalamea

An epoxy terminated polyester; an adhesive formulation including the epoxy terminated polyester and a curative composition; a laminating adhesive prepared from the above adhesive formulation; a process of making a laminate; a laminate made by the above process; and a flexible package prepared from the above laminate.

Isocyanate-free laminating adhesive

Two-component solventless polyurethane adhesive compositions are disclosed comprising an isocyanate component comprising an isocyanate, and a polyol component comprising an amine-initiated polyol comprising two or more primary hydroxyl groups and a backbone incorporating tertiary amines, wherein the amine-initiated polyol comprises a functionality of from 2 to 12, a hydroxyl number of from 5 to 1,830, and a viscosity at 40° C. of from 500 to 20,000 mPa-s, and a silicone-based additive (e.g., an anti-foaming agent and/or a wetting agent). The adhesive compositions are formulated such that the isocyanate and polyol components can be applied to separate substrates prior to mixing. Laminate structures comprising the disclosed adhesive compositions and further comprising a metal or metallized substrate are also disclosed.

Two-component solventless adhesive compositions for adhesion to metal and/or metallized substrates

Provided is a composition comprising one or more epoxy phosphate esters wherein the structure comprises two or more polyester linkages. Also provided is a method of making the epoxy phosphate esters that comprises reacting one or more epoxy-terminated polyesters with one or more phosphoric acids. Further provided is an adhesive composition that comprises one or more epoxy phosphate esters, one or more multifunctional isocyanate prepolymers, and one or more multifunctional isocyanate-reactive compounds.

Epoxy phosphate ester

The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component; and (B) a polyol component containing (i) a polyester-polycarbonate polyol and (ii) a phosphate-terminated polyol. The present disclosure also provides a method of forming the two-component solvent-less adhesive composition.

Two-component solvent-less adhesive composition

The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component and (B) a polyol component containing a poly-ester-amide polycarbonate polyol. The present disclosure also provides a method of forming a two-component solvent-less adhesive composition.

Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) an epoxy-terminated polyester compound, (C) a phosphoric acid, and (D) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing an epoxy-terminated polyester compound, mixing the polyester-urethane resin, epoxy-terminated polyester compound, and phosphoric acid to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12. Laminates prepared comprising the solvent-based adhesives and according to the disclosed methods are also disclosed.

Solvent-based adhesive compositions

Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) a phosphate ester compound, and (C) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing a phosphate ester compound, mixing the polyester-urethane resin and phosphate ester compound to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content of from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12. Laminates prepared comprising the solvent-based adhesives and according to the disclosed methods are also disclosed.

The present disclosure provides a two-component solvent-based adhesive composition. The two-component solvent-based adhesive composition contains the reaction product of (A) an isocyanate component; (B) a polyol component containing a polyester-amide polycarbonate polyol; and (C) a solvent. The present disclosure also provides a method of forming the two-component solvent-based adhesive composition.

Two-component solvent-based adhesive composition

The present disclosure provides a two-component solventless adhesive composition comprising a polyol component and an isocyanate component. The polyol component comprises a phosphate functional compound, and at least one polyol selected from polyester, polyether, and the combination thereof; and the isocyanate component comprises isocyanate prepolymer that is the reaction product of at least one isocyanate monomer and at least one polyol selected from polyester, polyether, and the combination thereof.

Two-component solventless adhesive compositions and methods of making same

Solvent-based adhesive compositions are disclosed herein. In some embodiments, the solvent-based adhesive compositions include (A) an isocyanate component comprising an isocyanate curing agent and (B) a hydroxyl component comprising a polyester polyol, a polyether polyol, and a phosphate ester compound. The isocyanate curing agent of the isocyanate component (A) crosslinks the components of the hydroxyl component. In some embodiments, the phosphate ester compound has the structure (I): (I) wherein R1 is any organic group. Methods for preparing solvent-based adhesive compositions are also disclosed. The methods include providing an isocyanate component (A) comprising an isocyanate curing agent, providing a hydroxyl component (B) comprising a polyol blend, comprising a polyester polyol and a polyether polyol, and a phosphate ester compound, curing the hydroxyl component (B) with the isocyanate component (A) at a mix ratio ((A):(B), by weight) of from 100:8 to 100:15, thereby forming the solvent-based adhesive composition. 

Solvent based adhesive compositions

The instant invention provides a curable formulation suitable for laminating adhesive applications, and laminating adhesives made therefrom. The curable formulation suitable for laminating adhesive applications according to the present invention comprises a) a blend comprising i) an epoxy terminated polyester and at least one of ii) a maleate (poly) ester or iii) a diacrylate terminated oligomer or polymer and b) an aliphatic amine curing agent.

Curable formulations for laminating adhesives

The instant invention provides a curable formulation suitable for laminating adhesive applications, and laminating adhesives made therefrom.

Laminating adhesive&#x2014;polyester-polycarbonate-polyol systems

The instant invention provides a curable formulation suitable for laminating adhesive applications, and laminating adhesives made therefrom. The curable formulation suitable for laminating adhesive applications according to the present invention comprises a high molecular weight polyester resin, an epoxy-terminated polyester, an additive, a curing agent, and a solvent, wherein, upon curing under curing conditions, the curable formulation forms at least one interpenetrating polymer network.

Bisphenol-A-free cold draw laminating adhesive

A first aspect of the present invention is an adhesive composition comprising one or more polyisocyanates and one or more phosphate-functional polyols. A second aspect of the present invention is a method of bonding two substrates together to form a bonded article, said method comprising the steps of applying a layer of the composition of the first aspect to one of said substrates, contacting said layer of the composition of claimto a second substrate, and curing or allowing to cure the composition of claim. A third aspect of the present invention is a bonded article formed by the method of the second aspect.

Phosphate adhesion promoters

Growing community of inventors

Glen Ellyn, IL, United States of America

Joseph James Zupancic