Henkel Corporation

Joseph C Topping

William G Kozak

Kevin H Cornell

Jeffrey T Simpson

Thaddeus J Szynal

William M Neeb

A free fluoride ion sensitive electrode with longer service life can be obtained by eliminating the use of any cement or similar adhesive to hold the fluoride sensing crystal of the electrode in place within the rest of the structure of the electrode, using instead a pressure sealed combination of the fluoride sensing crystal and upper and lower elastomeric gaskets. This arrangement also permits replacing the crystal and sealing gaskets if needed, without replacing any of the other components of the electrode.

Electrode with reversibly sealed fluoride sensing crystal

A system automated for providing at least periodic removal of metal ions and contaminants from a chemical bath, consists of a microprocessor programmed for controlling fluid circuits of pumps and valves, for in one state of operation circulating a first predetermined quantity of the chemical bath from a first tank, through an ion exchange column, and back to the first tank; for in a second state of operation circulating deionized water from a second tank into the IEX column for displacing residual chemical bath therefrom for return to the first tank; for in a third state of operation circulating deionized water through the IEX column, and discharging the rinse water from a waste port; for in a fourth state of operation circulating regenerant acid through the ion exchange column, and discharging the used acid from a waste port; for in a fifth state of operation circulating deionized water through the IEX column for rinsing acid regenerant therefrom and discharging the same out of a waste port; and for in a sixth state of operation circulating chemical bath into the IEX column for displacing residual rinse water therefrom, and discharging the same out of the waste port, in preparation for a cycle of treatment of the chemical bath.

Apparatus for maintaining a stable bath for an autodeposition

Apparatus for transferring liquid from a first tank to a second tank having supply line coupled to the first tank, a fill line connected to the second tank, a return line leading to the first tank or a sump, a pump for causing liquid to flow from the supply line to the fill line when the apparatus is in a fill mode, from the fill line to the return line when the apparatus is in a purge mode, and a programmable control for placing the apparatus in a purge mode in response to any one of the following signals, a signal indicating that the fill line is not properly attached to the second tank, a signal indicating that the liquid in the second tank has reached a given level, and a signal that the volume of liquid delivered by the pump is that which will fill the second tank to the given level. The programmable control detects leaks and checks whether the rate at which the pump delivers liquid is within a given range.

Liquid transfer apparatus

The service life of a conventional free fluoride ion sensitive electrode can be improved by shielding the outer casing of the conventional electrode against contact with the liquid composition in which the free fluoride ions concentration is to be measured, particularly when the solution is a hot acid solution containing surfactants and/or oxidizing agents, such as is normally used for cleaning aluminum beverage containers or providing a protective surface treatment to aluminum surfaces.

Fluoride sensing electrodes with longer service life, retrofittable

A system automated for providing at least periodic removal of metal ions and contaminants from a chemical bath, consists of a microprocessor programmed for controlling fluid circuits of pumps and valves, for in one state of operation circulating a first predetermined quantity of the chemical bath from a first tank, through an ion exchange column, and back to the first tank; for in a second state of operation circulating deigned water from a second tank into the IEX column for displacing residual chemical bath therefrom for return to the first tank; for in a third state of operation circulating deigned water through the IEX column, and discharging the rinse water from a waste port; for in a fourth state of operation circulating regenerate acid through the ion exchange column, and discharging the used acid from a waste port; for in a fifth state of operation circulating deionized water through the IEX column for rinsing acid regenerate therefrom and discharging the same out of a waste port; and for in a sixth state of operation circulating chemical bath into the IEX column for displacing residual rinse water therefrom, and discharging the same out of the waste port, in preparation for a cycle of treatment of the chemical bath.

An automated system is disclosed for providing at least periodic removal of metal ions from a chemical complex and contaminants from a chemical bath. The chemical bath is a latex solution containing charged latex particles and having an acidic pH to form a coating by autodeposition, the charged particles tending to coagulate when subjected to a high shear circulation. The system uses an ion exchange column containing an iminodiacetate ion exchange resin for removal of the metal ion contaminants. The chemical bath is passed through the ion exchange column at a low velocity to prevent coagulation of the latex particles. Conductivity measurement devices and controllers are used to automate the operation of the system. Also, additional sensors, such as pressure and level sensors, controllers, filters, circulation pumps and tanks are used for performing rinsing and regeneration of the ion exchange column.

A test unit for a monitoring device includes reference and measuring electrodes coupled to a preamplifier and a temperature compensating resistor for the preamplifier. The test unit has components corresponding to those of the monitoring device as well as a power supply and a voltmeter coupled to the output of its preamplifier. Cables are provided for substituting either or both electrodes of the monitoring device for the electrodes of the test device, and a switch is provided for substituting a temperature compensation resistor of the monitoring device for the temperature compensation resistor of the test device. A cable is adapted for connection to either preamplifier for supplying it with operating potentials derived from the power supply and for coupling the output of either preamplifier to the voltmeter.

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North Wales, PA, United States of America

Joseph C Topping