Zimpro Environmental, Inc.

The Standard Oil Company

Zimpro Passavant Environmental Systems, Inc.

Joseph A Momont

William M Copa

David A Beula

Bruce L Brandenburg

Richard W Lehmann

Kenneth P Keckler

A process for treating wastewaters containing carbonaceous COD and at least one nitrogen-containing compound is disclosed comprising wet oxidizing the wastewater with an oxidizing agent at a temperature less than 373.degree. C. and a pressure sufficient to maintain a liquid water phase, to produce an oxidized wastewater containing a reduced concentration of COD. The nitrogen of the nitrogen-containing compound is substantially converted to ammonia, nitrate and nitrite. Sufficient inorganic nitrogen-containing compound is added to the oxidized wastewater to produce essentially equal concentrations of ammonia-nitrogen and nitrite-nitrogen plus nitrate-nitrogen. Mineral acid is added to the oxidized wastewater to produce a pH between 4 and 7, and optionally, a transition metal salt is added, to catalyze a thermal denitrification step. The wastewater is heated at temperatures between about 100.degree. C. and 300.degree. C. to decompose the nitrogen compounds, producing a purified wastewater.

Removal of nitrogen from wastewaters

A process is described for monitoring pH in caustic liquor wet oxidation systems. An offgas carbon dioxide baseline value is established for the operating system where oxidized liquid effluent is at pH 7 or above. Offgas carbon dioxide content deviating by a selected proportion above the baseline vale indicates a drop in liquid effluent pH to 7 or less. Sufficient alkalinity is added to the raw wastewater to bring the effluent pH to 7 or above and prevent excessive corrosion to the materials of construction of the nickel-based or ferrous-based alloy wet oxidation system.

Method of monitoring pH in caustic liquor wet oxidation

A process for treatment of caustic sulfide liquor by wet oxidation in a ferrous-based alloy system at temperatures less than about 175.degree. C. is described. The liquor is first analyzed for alkalinity consuming species and for nonsulfidic alkalinity. If excess alkalinity consuming species is present compared to nonsulfidic alkalinity, then additional nonsulfidic alkalinity is added to the raw liquor such that excess alkalinity is present during wet oxidation treatment, thus preventing excessive corrosion to the ferrous-base alloy system.

Low temperature caustic sulfide wet oxidation process

A process is disclosed which limits the corrosion of the materials of construction of a wet oxidation system treating wastewaters. The process is particularly useful in the wet oxidation treatment of ammonium sulfate containing wastes such as acrylonitrile wastewaters. The wastewater is mixed with an oxygen containing gas such that a substantial residual oxygen gas concentration is maintained from before the stream-gas mixture is heated for wet oxidation until after the oxidized stream-gas mixture is cooled and separated. Preferably, in the treatment of acrylonitrile waste water the shutdown procedure comprises cooling said waste stream by introducing an aqueous liquid substantially free of organic impurities and containing a basic material.

Wet oxidation process for ACN waste streams

A process for treatment of caustic sulfide liquor by wet oxidation in a nickel-based alloy system is described. The liquor is first analyzed for alkalinity consuming species and for nonsulfidic alkalinity. If excess alkalinity consuming species is present compared to nonsulfidic alkalinity, then additional nonsulfidic alkalinity is added to the raw liquor such that excess alkalinity is present during wet oxidation treatment, thus preventing excessive corrosion to the nickel-base alloy system.

Growing community of inventors

Mosinee, WI, United States of America

Joseph A Momont