Texaco Inc.

Joseph A Froelich

Paul H Lewis

Joseph A Durkin

An improved process for fluid catalytic cracking or hydrocarbons employing a Y zeolite in a silica-alumina matrix and containing from about 0.1 to about 5 weight percent fluorine. The catalyst is prepared by contacting a Y zeolite in a silica-alumina matrix with an aqueous solution of a fluorine compound, preferably an aqueous solution of hydrogen fluoride, for a period of 16 to 24 hours, followed by drying and calcining the resultant fluorided cracking catalyst. The process of cracking hydrocarbons with these catalysts produces improved yields of motor fuel fractions of improved octane number as compared with processes employing unfluorided cracking catalysts.

Catalytic cracking process

An improved zeolite-containing cracking catalyst prepared by treating a zeolite-containing cracking catalyst with an aqueous solution containing a fluorine compound, drying and calcining the fluorided catalyst. In a preferred embodiment, the fluorinating solution is an aqueous solution of hydrogen fluoride. The fluorided catalyst may be used per se as a cracking catalyst, or may be physically mixed with a metallic reforming catalyst for use as a cracking catalyst. The fluorided cracking catalysts exhibit improved activity and yield higher octane products than unfluorided cracking catalysts.

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Nederland, TX, United States of America

Joseph A Froelich