Petroleo Brasileiro S.a. - Petrobras

Jose Luiz Zotin

Jefferson Roberto Gomes

Andrea De Rezende Pinho

Marcelo Edral Pacheco

Anilza De Almeida Lyra Correa

Rodrigo Caetano Chistone

Vitor Loureiro Ximenes

Jorge Roberto Duncan Lima

William Richard Gilbert

Donizeti Aurelio Silva Belato

Adriano Do Couto Fraga

Iris Medeiros Junior

Marlon Brando Bezerra De Almeida

Carlos Alberto De Araujo Monteiro

Dayse Lovatte Fonseca

Denise Barcellos Da Rocha Monteiro

Luiza Torres Abrantes

Sandra Shirley Ximeno Chiaro

Isa Santos Duarte

The present invention relates to a process for the production of bio-oil-based renewable streams for composing a diesel or aviation kerosene (AVK) pool by combining the technologies of hydroprocessing esters and fatty acids (HEFA) and thermochemical conversion of lignocellulosic biomass for generating bio-oil. The integration of conventional raw material from the HEFA pathway with a bio-oil fraction has the advantages of the use of a stream originating from the conversion of lignocellulosic material, which is widely available on the market, and also the production of a renewable stream containing aromatics in its composition.

Process for generating renewable streams from bio-oil and use thereof for the production of renewable fuels

The present invention relates to a process for converting vegetable oils, animal fats, residual edible oils and carboxylic acids into renewable liquid fuels, such as bionaphtha, bioJET-A1 and renewable diesel, for use in a mixture with fossil fuels. The process consists of two steps: hydrotreating and hydrocracking. The effluent from the hydrotreatment step presents aromatics, olefins and compounds resulting from the polymerization of esters and acids in its composition. This fact occurs due to the use of partially reduced catalysts and without injection of sulfide agent and allows obtaining a bioJET-A1 with adequate quality for use in a mixture with fossil kerosene. At the same time, the process generates, in addition to products in the distillation range of naphtha, kerosene and diesel, high molecular weight linear paraffins (with up to 40 carbon atoms).

Catalysts and selective process for the production of renewable aviation fuels and biofuel produced

The present invention refers to the processing of a 100% renewable load in FCC units, wherein the load comprises triglycerides of vegetable and animal source, free fatty acids, fatty acid esters, ketones, alcohols and long-chain aldehydes, using catalyst and appropriate operating conditions in order to obtain 100% renewable products with a high content of aromatic compounds, in the range of naphtha, kerosene, diesel and heavy gas oil. The product thus obtained complies with all the properties of the ASTM D1655 standard, even for contents of up to 10% renewable content. In addition, there is no need to reduce the freezing point of the fossil QAV for the introduction of the renewable component, with no impact on the yield and economy of the process.

Process for production of aviation kerosene from a stream rich in aromatic compounds of renewable source

The present invention relates to a catalyst for selective hydrodesulphurization of cracked naphtha streams in the form of an extrudate, which comprises a support based on an inorganic oxide and an outer layer bound to the support, wherein the outer layer comprises desulphurization metals dispersed therein forming a crown, the desulphurization metals being cobalt and molybdenum. The present invention also relates to the preparation of said catalyst by the incipient wetness impregnation method and to the process for selective hydrodesulphurization of cracked naphtha employing same.

Catalyst for selective hydrodesulphurization of cracked naphtha streams, method of preparation thereof, and process for selective hydrodesulphurization of cracked naphtha

The present invention describes a method for refining highly polyaromatic and nitrogenated charges, such as LCO streams, comprising hydrotreating (HDT) as the first reaction stage, followed by the intermediate separation of gases generated in the HDT section, then by a second reaction stage consisting in moderate hydroconversion/hydrocracking and in a rectifying and/or fractionating section, thus allowing more flexible production of fuels. In the rectification mode, the claimed method yields a diesel oil fraction with higher cetane content, reduced density and volumetric yield increase of at least 111% relative to the process charge, thus minimising yield losses through naphtha overcracking and contributing to the optimisation of the required hydrogen consumption. In the fractionating mode, different cuts and their compositions can be produced, such as naphtha, kerosene and diesel.

Refining process for highly (poly)aromatic and nitrogenated charges

Growing community of inventors

Rio de Janeiro, Brazil

Jose Luiz Zotin