Wyoming Mineral Corporation

Westinghouse Electric Corporation

Jose G Lopez

Regis R Stana

Edward Mitchell

Joseph S Rudolph

Victor J Barnhart

Kenneth W Gould

An acidic solution containing metal values and also containing humic acid impurities, is purified by: (1) forming a gas in the acid solution, (2) adding high molecular weight anionic organic flocculant in a volume ratio of gas containing acid solution: flocculant of 1,000:0.002 to 0.10, to form a bottom, purified, aqueous acidic phase containing metal values and a top flocculated humic acid impurities froth phase and (3) removing the humic acid froth phase.

Humic flotation of wet process phosphoric acid as a pretreatment step in

A process to maintain a high iron +2/iron +3 concentration in the reductive stripping system for recovering uranium from wet-process phosphoric acid, comprises contacting partially oxidized strip acid, containing substantial amounts of iron +3, which had just previously stripped uranium values from an organic solvent, with elemental iron to reduce iron +3 to iron +2 and provide a Fe.sup.+2 /Fe.sup.o conversion ratio of from about 1.5 to 3.0.

Method to maintain a high Fe.sup.+2 /Fe.sup.+3 ratio in the stripping

Controlling the uranium extraction coefficient in uranium extraction processes involving wet process phosphoric acid feed is accomplished by monitoring the oxidation potential of the raffinate acid stream exiting the extractor, and maintaining the oxidation potential of the raffinate at a value above 350 mV.

Uranium extraction coefficient control in the process of uranium

Wet process phosphoric acid is oxidized with nitric acid so that uranium values therein are in the +6 state. The organic extractant which contacts the acid extracts the +6 uranium and nitrate and/or nitrite ions. Urea is added to the oxidized acid to react with the nitrate and/or nitrite ions so that the organic does not extract them. The organic is reductively stripped with an aqueous solution containing ferrous ions. The efficacy of the ferrous ions is not lost through reaction with nitrate and/or nitrite ions.

Growing community of inventors

Lakeland, FL, United States of America

Jose G Lopez