Heraeus Quarzglas Gmbh & Co Kg

Heraeus Battery Technology Gmbh

Heraeus Deutschland Gmbh & Co Kg

Jörg Becker

Martin Trommer

Waltraud Werdecker

Christian Neumann

Sascha Pihan

Matthias Otter

Richard Walter

Jürgen Weber

Julie Michaud-Bernlochner

Evgeniia Komarova

Benjamin Krüner

Achim Hofmann

Florian Eweiner

Dominik Samuelis

Dietmar Hellmann

Andreas Kuhn

Walter Lässig

Wolfgang Stang

Rainer Kiemel

Thomas Hucke

Ulrich Kirst

Christian Breuer

Mark Neuschütz

Gerard Lebrun

Walter Laessig

Stephan Osinga

Markus Klose

Gabriele Przibilla

Sacha Pihan

Known processes for preparing a porous carbon material with a hierarchical porosity comprise the steps of a) providing at least one carbon source and at least one amphiphilic species, b) combining the carbon source and the amphiphilic species to obtain a precursor material, and c) heating the precursor material to obtain the porous carbon material having a modal pore size and a pore volume. In order to avoid a lengthy hydrothermal treatment and to allow tunability of the pore size, pore size distribution and pore volume in carbon material, it is proposed that the heating step c) comprises a low temperature treatment in which the precursor material is heated to a first temperature in the range between 300° C. and 600° C. to obtain a self-assembled porous carbonaceous material, and wherein heating to the first temperature comprises a first average heating rate in the range of 0.5° C./min to 5° C./min.

Process for preparing a porous carbon material and a porous carbon material obtainable by this process

Known processes for preparing a porous carbonaceous material require lengthy polymerization and washing steps involving solvents or neutralizing agents. The use of high quantities of pore formers leads to a lower carbon yield and higher costs, and use of sulphuric acid leads to sulphur contamination of the final material, but also to corrosion and corrosive by-products and a more complicated handling of the process. In order allows the manufacturing of a porous carbonaceous material with a high pore volume and avoiding the disadvantages of the known methods, a process is provide that comprise the steps of a) providing at least one carbon source and at least one amphiphilic species, b) combining at least the carbon source and the amphiphilic species to obtain a precursor material, c) heating the precursor material to a temperature in the range between 300° C. and 600° C. for at least 15 min so as to obtain a porous carbonaceous material, which is then cooled so as to form the porous carbonaceous material having a modal pore size and a pore volume and a skeleton density.

Process for the preparation of a porous carbonaceous material, porous carbonaceous material, and a catalyst made of the material

One aspect is a production process including feeding a feed material composition into a reaction zone at a feeding position, wherein the feed material composition is liquid or gaseous or both; reacting the feed material composition in the reaction zone into a first plurality of particles by a chemical reaction; depositing the first plurality of particles onto a substrate surface of a substrate, thereby obtaining a porous silicon dioxide material, having a pore structure, in the form of up to 20 layers superimposing the substrate surface; at least partially removing the porous silicon dioxide material from the substrate surface; and modifying the pore structure of the porous silicon dioxide material, thereby obtaining the porous silicon dioxide material having a further pore structure.

Production of a porous product including post adapting a pore structure

Known lithium-ion cells for a secondary battery including an electrode have an active material layer containing active material particles in contact with a non-aqueous electrolyte and a particulate, porous additive. Using this as a basis, it is desired to achieve an improvement in the lithium-ion cells in respect of their gravimetric and volumetric energy density and in respect of inexpensive and reproducible production, and in particular to ensure that the desired properties of the active material layer are not changed, or are not changed to an unacceptable degree, by compression during calendering. Accordingly, it is proposed to use, as an additive, porous carbon particles having a porosity in the range between 50% and 95% and having macropores which are fluidically connected to one another and which are delimited by carbon walls having an average wall thickness in the range of 5 to 500 nm.

Lithium ion cell for a secondary battery

A method for producing carbon particles having a core/shell structure includes infiltrating a pore-containing template material with a first precursor for carbon of a first variety, carbonizing the first precursor to form a deposit of the carbon of the first variety, infiltrating the remaining pore space with a second precursor for carbon of a second variety to form a second deposit of the carbon of the second variety which has a second porosity lower than the first porosity, and removing the template material to form the carbon particles. The template material is provided as template particles and the first precursor is provided as precursor particles of meltable and polymerizable material. The infiltration occurs in the molten phase so that the first precursor is foamed before or during the carbonization to form a pore-containing carbon foam. In an intermediate product, pores of the template material are at least partially filled.

Porous carbon particles having a core/shell structure, and method for producing same

The invention relates to a composite made of a porous carbon and an active material containing sulphur and to method for producing same. A method for producing a composite made of a porous carbon structure and sulphur is disclosed, said composite being characterized by a high capacitance and a low capacitance loss, when used as an electrode material for a lithium-sulphur secondary battery. According to the invention, a dispersion of carbon powder, an active material containing sulphur and an aqueous medium are treated hydrothermally at a temperature sufficient for melting sulphur. The liquid phase which forms, which contains the melted sulphur and water, infiltrates the pores of the porous carbon.

Composite made of porous carbon and sulfer-containing active material as well as method for producing same

A known method for producing porous graphitized carbon material covered with metal nanoparticles involves infiltrating a porous template framework of inorganic material with a carbon precursor. After thermal treatment of the precursor, the template is removed and the particulate porous carbon material is covered with a catalytically active substance. According to the invention, in order to keep the proportion of the noble metal loading at a low level, the thermal treatment of the precursor first involves carbonization, and the material is not graphitized into graphitized, particulate, porous carbon material until the template has been removed. The graphitized carbon material has a hierarchical pore structure with a pore volume of at least 0.5 cm/g and at least 75% of the pore volume is apportioned to macropores with, size 100 to 5000 nm. Before covering with catalytically active substance, the carbon material is subjected to an activation treatment in an oxidizing atmosphere.

Catalyst support and method for producing porous graphitized carbon material covered with metal nanoparticles

The invention relates to a method for economically producing a composite powder made of carbon and electrochemical active material. According to the invention, a melt made of a meltable carbon precursor substance having nanoparticles made of an active material distributed in the melt is provided, and said melt is divided into the composite powder, in which nanoparticles made of the active material are embedded in a matrix made of the carbon precursor substance. A porous composite material produced using the composite powder is used to produce an electrode for a secondary battery, in particular for use as an anode material. The production of the composite material comprises the following steps: providing template particles made of inorganic template material, producing a powder mixture of the composite powder and the template particles, heating the powder mixture and softening the composite powder in such a way that the composite powder penetrates the pores and is carbonated, and removing the template material to form the porous electrochemical composite material.

Method for producing composite powder, and for a porous composite material for electrochemical electrodes that is produced using the composite powder

In order to provide an inexpensive product composed of a porous carbon provided with electrochemical active material, said product being suitable particularly for use as a cathode or anode material for a secondary battery, a process comprising the following process steps is proposed: (a) producing a template from inorganic material by gas phase deposition, said template comprising a framework of pores and nanoparticles joined to one another, (b) coating the template framework with an electrochemical active material or a precursor thereof, (c) infiltrating the pores of the template with a precursor substance for carbon, (d) carbonizing the precursor substance to form a carbon layer, (f) removing the template.

Method for producing a composite structure composed of porous carbon and electrochemical active material

Methods for producing porous carbon product utilize template material in the form of template particles containing macropores and a polymerizable carbon precursor substance. The macropores of the template are infiltrated with the precursor substance in dissolved or melted form. After carbonization of the infiltrated precursor substance, the template is removed to form the porous carbon product. In order to obtain a carbon structure with hierarchical porosity having a high fraction of mesopores having pore sizes in the range of 2 to 50 nm, after the infiltration and before carbonization, the precursor substance within the macropores of the template is subjected to a treatment at a foaming temperature at which the precursor substance foams under polycondensation and fills the macropores as substantially mesoporous foam, in which at least 70% of the pores have pore sizes in the range of 10 to 150 nm.

Method for producing a porous carbon product

Inexpensive product consisting of porous carbon, with a pore structure which is suitable for retaining electrode parts which can be used in particular for a use as an electrode material for a lithium-sulphur secondary battery, and a method comprising the following method steps: (a) providing a template consisting of inorganic material which contains spherical nanoparticles and pores, (b) infiltrating the pores of the template with a precursor for carbon of a first variety, (c) carbonizing so as to form an inner layer on the nanoparticles with a first microporosity, (d) infiltrating the remaining pores of the template with a precursor substance for carbon of a second variety, (e) carbonizing the precursor substance, wherein an outer layer with a second microporosity which is lower than the first microporosity is produced on the inner layer, and (f) removing the template so as to form the carbon product with layer composite structure, comprising an inner layer consisting carbon with a first, relatively high microporosity, which has a free surface facing a cavity, and an outer layer consisting of carbon with a second, relatively low microporosity, which has a free surface facing away from the cavity.

Porous carbon product with layer composite structure

A known method for producing a porous carbon body comprises providing a template of inorganic template material which comprises interconnected pores, providing a precursor substance for carbon, infiltrating the pores of the template with the precursor substance, carbonizing the precursor substance and removing the template with formation of the porous carbon product. Starting therefrom, to provide a method which allows a cost-effective production of a porous carbon structure also with thick wall thicknesses, it is suggested according to the invention that precursor substance particles of fusible material and template particles are provided and a powder mixture is formed from the particles, and that the powder mixture is heated before or during carbonization according to method step (d) in such a manner that precursor substance melt penetrates into the pores of the template particles.

Porous carbon product and method for producing an electrode for a rechargeable lithium battery

Build-up granulation and compaction granulation methods are generally known for producing granules from porous inorganic material. In order to allow a cost-efficient yet also reproducible production of porous granules having a more pronounced hierarchical pore structure, the invention relates to a method comprising the following steps: (a) supplying a feedstock flow to a reaction zone in which the feedstock is converted to material particles by means of pyrolysis or hydrolysis, (b) depositing the material particles on a deposition surface () forming a soot layer (), (c) thermally hardening the soot layer () to form a porous soot plate (), and (d) comminuting the soot plate () to form porous granules ().

Growing community of inventors

Niddatal, Germany

Jörg Becker