Korea Research Institute of Chemical Technology

The University of Texas System

Centre National De La Recherche Scientifique

Université De Versailles—saint-quentin-en-yvelines

Total Petrochemicals France

Université De Caen Basse Normandie

Universidade Do Porto. (uporto) Faculdade De Engenharia

Ensicaen

Krict

Jong-San Chang

Young Kyu Hwang

Dong Won Hwang

Sang-Eon Park

U-Hwang Lee

Sung Hwa Jhung

Christian Serre

Do-Young Hong

You-Kyung Seo

Gerard Ferey

You-Kyong Seo

Young-Kyu Hwang

Yong Ki Park

Chul Wee Lee

Kyung Ho Cho

Anthony K Cheetham

Kyu-Wan Lee

Ji Woong Yoon

Min Seok Park

Jin-Soo Hwang

Ji Sun Lee

Pravin P Upare

Sung-Hwa Jhung

Jermim Noh

Woo Jin Lee

Sung-Kyun Chang

Jung Ho Lee

Francis Luck

Simon M Humphrey

Do Young Hong

Yun-Jo Lee

U Hwang Lee

Jong-Min Lee

Dae Sung Kim

Gérard Ferey

Su Kyung Lee

Alvaro Fernandez

Patricia Horcajada-Cortes

Marco Daturi

Philip Leslie Llewellyn

Eui-Yong Bang

Jung-Ho Lee

Seung-joon Lee

Thomas Devic

Youn-Sang Bae

Jaesung Kwak

Patricia Horcajada Cortes

Joungmo Cho

Catherine Leroi

Alirio Rodrigues

Jung Whan Yoo

Seong-Hee Han

Joung-mo Cho

Pandharinath Pravin Upare

Alexandre Vimont

Ana Mafalda Almeida Peixoto Ribeiro

Joao Carlos Godinho De Faria Dos Santos

Jean-Patrick Bonne

Min-Hee Jung

Deok-Kyu Kim

Hye-Young Lee

Gyung-Mi Kim

Sukyung Lee

Ji-Man Kim

Hee Seok Chai

Kyu Eun Shim

Hubert Chevreau

Florence Ragon

HyoJin Gwak

Hee-Sang Park

Yong Kyu Hwang

Ki-Young Lee

Seong-Yong Park

Sujing Wang

Guillaume Maurin

Patricia Horcajada

Alirio Egidio Rodrigues

Chrisitian Serre

G Ferey

C Serre

The present disclosure relates to a catalyst for preparing 1,2-pentanediol from furfural and/or furfuryl alcohol, and more particularly to a catalyst, which is configured such that a catalytically active metal containing both at least one transition metal and tin (Sn) is supported on a basic support and is capable of increasing reaction selectivity for 1,2-pentanediol, and a method of preparing 1,2-pentanediol using the same.

Catalyst for preparing 1,2-pentanediol and method for preparing 1,2-pentanediol by using same

Embodiments of the present disclosure pertain to methods of sorption of HO from an environment by associating the environment with a porous material such that the association results in the sorption of HO to the porous material. The porous material includes a (M)-2,4-pyridinedicarboxylic acid coordination polymer, where M is a divalent metal ion selected from the group consisting of Mn, Fe, Co, Ni, Mg, and combinations thereof. The coordination polymer has a one-dimensional pore structure and shows reversible soft-crystal behavior. The porous material may be a Mg(II) 2,4-pyridinedicarboxylic acid coordination polymer (i.e., Mg-CUK-1). The methods of the present disclosure may also include one or more steps of releasing the sorbed HO from the porous material and reusing the porous material after the releasing step for sorption of additional HO from the environment.

Use of metal organic frameworks for H2O sorption

The invention relates to a cyclical method for producing a nitrogen fraction, the purity of which is greater than or equal to 95 mol %, and a hydrocarbon-enriched fraction from a filler containing nitrogen and a hydrocarbon, said method using a specific class of porous hybrid solids as an adsorbent in a pressure-swing adsorption (PSA) process. The invention also relates to equipment for implementing said method.

Cyclical method of producing high-purity nitrogen and optionally a high-purity hydrocarbon from a feedstock containing nitrogen and a hydrocarbon

The present invention relates to a nitrogen adsorbent having nitrogen selective adsorptivity by including an organic-inorganic hybrid nanoporous material having a coordinatively unsaturated metal site with density of 0.2 mmol/g to 10 mmol/g in a skeleton, surface or pore; and use thereof, such as a device separating nitrogen from a gas mixture containing nitrogen and methane, a pressure swing adsorption separation device and a temperature swing adsorption separation device for separating nitrogen provided, a method for separating nitrogen and methane from a gas mixture containing nitrogen and methane, a device for separating nitrogen, oxygen or argon, a method for separating nitrogen, oxygen or argon from a gas mixture containing nitrogen, oxygen or argon, and a method for preparing nitrogen or high purity inert gas all separated from a gas mixture containing nitrogen and inert gas.

Inorganic-organic hybrid nanoporous material with nitrogen selective adsorptivity and method for separating nitrogen-containing gas mixture using the same

The present invention provides a method for directly producing lactide by subjecting lactic acid to a dehydration reaction in the presence of a catalyst comprising a tin compound, preferably, a tin (IV) compound, wherein lactide can be produced directly or by one step from lactic acid, without going through the step of producing or separating lactic acid oligomer. The method of the present invention has advantages of causing no loss of lactic acid, having a high conversion ratio to lactic acid and a high selectivity to optically pure lactide, and maintaining a long life time of the catalyst. Further, since lactic acid oligomer is not or hardly generated and the selectivity of meso-lactide is low, the method also has an advantage that the cost for removing or purifying this can be saved.

Method for producing lactide directly from lactic acid and a catalyst used therein

The present invention relates to a complex and a method for manufacturing same, the complex comprising: at least one crystalline hybrid nanoporous material powder, in which a metal ion, or a metal ion cluster to which oxygen is bound, and an organic ligand, or the organic ligand and a negative ion ligand are in a coordinate covalent bond; and at least one organic polymer additive, or at least one organic polymer additive and an inorganic additive, wherein the shape of the complex is spherical or pseudo-spherical, the size of the complex is 0.1 to 100 mm, a total volume of pores is 5 or more volume % based on the sum of a total volume of nanoporous material having a size of at most 10 nm and a total volume of pores having a size of at least 0.1 &#x3bc;m, and wherein a non-surface value per weight (m/g) of the complex as at least 83% of a non-surface value per weight (m/g) of the nanoporous material powder.

Complex comprising crystalline hybrid nanoporous material powder

The present invention relates to a method for preparing a porous organic-inorganic hybrid, which comprises gelling a reaction mixture containing a metal precursor, a water-soluble additive and water or water-containing organic solvent at a gelling temperature of 30&#xb0; C.&#x2dc;100&#xb0; C. to obtain an organogel-containing solution having a viscosity of 2 to 50,000 (cps), subsequently ageing the solution at said gelling temperature under stirring; and subsequently heating the organogel-containing solution at a temperature between said gelling temperature and 250&#xb0; C. to crystallize the solution. According to the method for preparation of the present invention, it is possible to commercially practice the present invention since the reaction can be carried out in water or a water-containing organic solvent at an ambient pressure or a slightly raised pressure under a reflux condition, as well as it is possible to mass-produce a porous organic-inorganic hybrid having a high crystallinity and a large surface even in a high mol ratio of 1:1&#x2dc;1:30 of solvent to metal.

Method for preparing porous organic-inorganic hybrid materials

The present disclosure provides an apparatus for treating air by using porous organic-inorganic hybrid materials as an absorbent, which comprises an inlet passage for receiving air from outside; a dehumidifying part comprising porous organic-inorganic hybrid materials as an adsorbent for removing moisture from the air receiving through the inlet passage; a regenerating unit for regenerating the adsorbent of the dehumidifying part; and an outlet passage for discharging the dehumidified air to outside. Said apparatus preferably comprises two dehumidifying parts of two-bed switching type and two switch valves, wherein said two dehumidifying parts are alternatively operated for dehumidification and for regeneration by switching said switch valves to convert direction of air flow.

Apparatus for treating air by using porous organic-inorganic hybrid materials as an absorbent

A method for recovery of highly pure alkyl lactate and lactic acid is provided, which includes a step 1 for producing source liquid comprising lactic acid or ammonium lactate; a step 2 for dehydrating the source liquid product of step 1; a step 3 for producing liquid mixture by sequentially adding and stirring alcohol and acid solution to the dehydrated source liquid; a step 4 for separating and removing ammonium salt precipitation from the liquid mixture of step 3; a step 5 for producing alkyl lactate from ammonium salt-free liquid mixture by esterification reaction; and a step 6 for separating alcohol and alkyl lactate by distillation from the mixture of step 5.

Recovery method of highly pure lactic acid and alkyl lactate

The present invention relates to methods for absorbing and/or desorbing water by contacting water with hybrid inorganic-organic material having high surface area, and pores with the size of molecules or nanometers. More specifically, the water adsorbent has facile adsorption-desorption even below 100&#xb0; C., having high adsorption capacity, and having high desorption capacity when it is heated up to the temperature below 100&#xb0; C. The adsorbent of the present invention can be applied to a humidifier, dehumidifier, cooler and heater. The present invention also relates to a technology to control humidity using the adsorbent.

Adsorbent for water adsorption and desorption

The present invention relates to reducible porous crystalline solids, constituted of a metal-organic framework (MOF), for the separation of mixtures of molecules having different unsaturation degrees and/or a different number of unsaturations with a selectivity that can be adjusted by controlling the reduction of the MOF. The MOF solids of the present invention, after reduction, have a strong affinity for molecules containing at least one unsaturation. They can be used in various separation processes, especially those relating to hydrocarbons.

Reducible porous crystalline hybrid solid for the separation of mixtures of molecules having different degrees and/or a different number of unsaturations

The present invention relates to a method for preparing iron-containing porous organic-inorganic hybrid materials where the organic compound ligand is bonded to a central metal and has a large surface area and pores of molecular size or nano size, by irradiating microwaves instead of heat treatments such as the conventional electric heating, etc. as the heat source of the hydrothermal or solvothermal synthesis reaction, after reacting a metal or metal salt and organic compound to form crystal nuclei by a predetermined pre-treatment operation in the presence of a solvent. In another aspect, a method of the present invention further comprises the step of purifying the obtained porous organic-inorganic hybrid materials by treating them with inorganic salt. In particular, a method of the present invention is characterized by not using a hydrofluoric acid.

Method for preparing porous organic-inorganic hybrid materials, porous organic-inorganic hybrid materials obtained by the method and catalytic uses of the materials

Disclosed herein is a method of surface-functionalizing a porous organic-inorganic hybrid material or a organic-inorganic mesoporous material, in which organic substances, inorganic substances, ionic liquids and organic-inorganic hybrid substances are selectively functionalized on the coordinatively unsaturated metal sites of a porous organic-inorganic hybrid material or organic-inorganic mesoporous material, and thus the porous organic-inorganic hybrid material can be used for adsorbents, gas storage devices, sensors, membranes, functional thin films, catalysts, catalytic supports, and the like, and the applications of the surface-functionalized porous organic-inorganic hybrid material prepared using the method to catalytic reactions.

Preparation of surface functionalized porous organic-inorganic hybrid materials or mesoporous materials with coordinatively unsaturated metal sites and catalytic applications thereof

Porous organic-inorganic hybrid materials with crystallinity and a method for preparing the same are provided. The method comprises preparing a reaction solution containing a mixture of at least one inorganic metal precursor, at least one organic compound which may act as a ligand, and a solvent (step 1); and forming porous organic-inorganic hybrid materials with crystallinity by reacting the reaction solution (step 2), wherein the reaction is carried out under the pressure of about 3 atm or less.

Porous organic-inorganic hybrid materials with crystallinity and method for preparing thereof

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Daejeon, South Korea

Jong-San Chang