Lg Energy Solution, Ltd.

Lg Chem, Ltd

Korea Advanced Institute of Science and Technology

Jong-Keon Yoon

Hyun-Woong Yun

Hoe-Jin Hah

Kyung-Hwa Woo

Jae-Hyun Lee

Hyun-Jun Choi

Kyoung-Ho Ahn

Sol-Ji Park

Hee-Tak Kim

Jeong-In Yu

Hye-jin Lee

Young-Il Roh

Hyun-Soo Jin

Disclosed is a method for manufacturing a lithium metal secondary battery including a lithium metal electrode as a negative electrode, wherein the lithium metal electrode has a protective layer formed thereon, and the lithium metal secondary battery is discharged before its initial charge during an activation step of the lithium metal secondary battery so that stripping occurs on the surface of the lithium metal electrode.

Method for fabrication of lithium metal secondary battery comprising lithium electrode

A negative electrode for a lithium metal battery which includes: a current collector; a negative electrode active material layer formed on the surface of a current collector; a heat conductive layer formed on a surface of the negative electrode active material layer wherein the heat conductive layer comprises a heat conductive material having a heat conductivity of 25 W/m·K to 500 W/m·K; and a protective layer formed on a surface of the heat conductive layer, wherein the protective layer includes at least one of a porous polymer layer and a ceramic layer. An electrochemical device including the negative electrode for a lithium metal battery. The negative electrode for a lithium metal battery includes a heat conductive layer and a protective layer, and can inhibit growth of lithium dendrite in a negative electrode for a lithium metal battery and improve the cycle life of an electrochemical device.

Anode for lithium metal battery, and electrochemical device comprising same

A separator for an electrochemical device comprising a porous polymer substrate, and a porous coating layer on at least one surface of the porous polymer substrate. The porous coating layer comprises inorganic particles and an ion conducting polymer. The ion conducting polymer comprises a fluorine-based copolymer comprising fluoroolefin-based segments with anionic functional groups present in side chains or terminals, and an electrochemical device comprising the same. It is possible to provide a separator with high ionic conductivity and an increased peel strength between the porous polymer substrate and the porous coating layer, and an electrochemical device with improved properties.

Separator for electrochemical device and electrochemical device comprising the same

Disclosed is a lithium metal secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a protective layer interposed between the negative electrode and the separator. The protective layer comprises an additive, and wherein the additive comprises a mixture of hexagonal boron nitride (BN) flakes and an ionomer comprising a sulfur (S)-containing anionic group and fluorine (F). The sulfur (S)-containing anionic group is at least one selected from the group consisting of SOand SO.

Lithium metal secondary battery having improved life characteristics

Provided is a casing for a lithium metal secondary battery including: a battery casing material; at least one releasable capsule attached at least partially or totally to the inner surface of the casing material to cover the inner surface of the casing material; and a release solution supported in the releasable capsule, wherein the releasable capsule includes a capsule coating film and a capsule inner space surrounded with the capsule coating film, the release solution is supported in the capsule inner space, and the release solution includes a release agent and a solvent. A lithium metal secondary battery including the casing and a method for manufacturing the same are also provided. It is possible to increase releasability of the negative electrode in a lithium metal secondary battery and to improve nail safety by using the releasable capsule according to the present disclosure.

Case for lithium metal secondary battery, lithium metal secondary battery comprising same, method for manufacturing same

A negative electrode for a lithium metal battery which includes: a current collector; a negative electrode active material layer formed on the surface of a current collector; a heat conductive layer formed on a surface of the negative electrode active material layer wherein the heat conductive layer comprises a heat conductive material having a heat conductivity of 25 W/m&#xb7;K to 500 W/m&#xb7;K; and a protective layer formed on a surface of the heat conductive layer, wherein the protective layer includes at least one of a porous polymer layer and a ceramic layer. An electrochemical device including the negative electrode for a lithium metal battery. The negative electrode for a lithium metal battery includes a heat conductive layer and a protective layer, and can inhibit growth of lithium dendrite in a negative electrode for a lithium metal battery and improve the cycle life of an electrochemical device.

A lithium metal secondary battery including: an electrode assembly including a positive electrode, a lithium metal negative electrode, a separator interposed between the positive electrode and the lithium metal negative electrode, a protective layer interposed between the lithium metal negative electrode and the separator; and a non-aqueous electrolyte injected to the electrode assembly, wherein the protective layer includes a polymer having a sulfur chain group. A battery module including the lithium metal secondary battery is also disclosed.

Lithium metal secondary battery having improved safety and battery module including the same

A lithium metal secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a protective layer interposed between the negative electrode and the separator. The protective layer includes an additive, wherein the additive comprises a mixture of hexagonal boron nitride (BN) flakes with an ionomer having a sulfur (S)-containing anionic group and fluorine (F).

Disclosed is a lithium metal secondary battery which includes: an electrode assembly including a negative electrode, a positive electrode and a separator interposed between the negative electrode and the positive electrode; a non-aqueous electrolyte with which the electrode assembly is impregnated; and a battery casing in which the electrode assembly and the non-aqueous electrolyte are received, wherein the negative electrode includes a negative electrode current collector and a lithium metal layer formed on at least one surface of the negative electrode current collector, the charge/discharge condition of the lithium metal secondary battery includes charging the lithium metal secondary battery under a pressurized state and discharging the lithium metal secondary battery under a non-pressurized or pressurized state, and when the lithium secondary battery is discharged under a pressurized state, the pressure applied during discharge is controlled to be smaller than the pressure applied during charge. A battery module including the lithium metal secondary battery is also disclosed.

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Daejeon, South Korea

Jong-Keon Yoon