Ipsi, L.l.c.

D. M. International Ltd.

Other

Conocophillips Company

International Process Services, Inc.

Jong Juh Chen

Jame Yao

Douglas G Elliot

Rong-Jwyn Lee

Pallav Jain

Wesley R Qualls

Ying Zhang

Weldon L Ransbarger

Shawn S Huang

Irvin H Lutz

Rong-Jywn Lee

Doug Elliot

Douglas Gene Elliot

Process for efficiently operating a natural gas liquefaction system with integrated heavies removal/natural gas liquids recovery to produce liquefied natural gas (LNG) and/or natural gas liquids (NGL) products with varying characteristics, such as, for example higher heating value (HHV) and/or propane content. Resulting LNG and/or NGL products are capable of meeting the significantly different specifications of two or more markets.

LNG facility with integrated NGL recovery for enhanced liquid recovery and product flexibility

The present invention is directed to methods for improving the efficiency of processes for the recovery of natural gas liquids from a gas feed, e.g., raw natural gas or a refinery or petrochemical plant gas stream. These methods may be employed with most, if not all, conventional separation methods using distillation towers, e.g., a demethanizer and/or deethanizer column. The methods of the present invention involve installing an internal refrigeration system consisting of an open cycle refrigerant withdrawn from a distillation column and a closed cycle refrigerant derived from the open cycle refrigeration system. A separator is installed downstream of the recycle compressor discharge cooler in the open cycle refrigeration scheme. At least a portion of liquid withdrawn from this separator is used as a closed cycle refrigerant by indirect heat exchange with the inlet gas or other process streams. Thus a closed refrigeration cycle enhances the performance of the open refrigeration cycle.

Internal refrigeration for enhanced NGL recovery

A method and apparatus for enhancing the power output and operational efficiency of a combustion turbine system using a combined refrigerant substantially comprising a first refrigerant and a second refrigerant, whereby the combined refrigerant exhibits a total pressure substantially greater than each respective first and second refrigerant at a temperature inside an evaporative chiller. In a preferred embodiment, the combined refrigerant cools turbine inlet air through the exchange of heat from the inlet air, in an air chiller, with a coolant which is cooled by the combined refrigerant in the evaporative chiller. The combined refrigerant, after it is used to cool the coolant in the evaporative chiller, is separated through the use of a liquid absorbent which absorbs the second refrigerant to form a solution pair. The non-absorbed first refrigerant is compressed, condensed and then recirculated to eventually join the second refrigerant which is desorbed from the solution pair in a regenerator. The economic advantage of the present invention is enhanced by thermally linking the heat required to regenerate the second absorptive refrigerant from the solution pair with the hot exhaust of heat available from the gas turbine.

Hybrid refrigeration cycle for combustion turbine inlet air cooling

A process for enhancing the recovery of less volatile components, from a multi component gas mixture, in a cryogenic distillation column, which involves withdrawing a stream from the cryogenic distillation column and processing it to yield a stream leaner in the component to be recovered, which will be cooled and fed to the cryogenic distillation column as a reflux. The processing step may include heating or cooling the side draw and then further contacting the side draw with another stream which is substantially condensed.

Flexible reflux process for high NGL recovery

The present invention is directed to methods and apparatus for improving the recovery of the relatively less volatile components from a methane-rich gas feed under pressure to produce an NGL product while, at the same time, separately recovering the relatively more volatile components which are liquified to produce an LNG product. The methods of the present invention improve separation and efficiency within the NGL recovery column while maintaining column pressure to achieve efficient and economical utilization of the available mechanical refrigeration. The methods of the present invention are particularly useful for removing cyclohexane, benzene and other hazardous, heavy hydrocarbons from a gas feed. The benefits of the present invention are achieved by the introduction to the NGL recovery column of an enhanced liquid reflux lean on the NGL components. Further advantages can be achieved by thermally linking a side reboiler for the NGL recovery column with the overhead condenser for the NGL purifying column. Using the methods of the present invention, recoveries of propane and heavier components in excess of 95% are readily achievable.

Enhanced NGL recovery utilizing refrigeration and reflux from LNG plants

A process for enhancing recovery of ethylene, ethane and heavier components using a cryogenic distillation column which involves dividing the feed gas into a first gaseous stream and a main gaseous stream. The first gaseous stream is compressed and cooled, and then expanded and introduced into the cryogenic distillation column as main reflux stream, or is further processed to generate at least one reflux stream to the cryogenic distillation column.

Split feed compression process for high recovery of ethane and heavier components

A simple, efficient, and cost effective process for separating components of a feed gas, e.g., containing methane and heavier hydrocarbons has been devised. First, feed gas is condensed to provide a vapor component and a liquid component. The vapor component is divided into at least a first, major portion a second portion, and a remaining portion. The second portion is directed to a lean reflux absorber, and the remaining portion is condensed and fed to the top of the lean reflux absorber. A bottom fluid stream, generally a liquid intermediate product, is recovered from the bottom of the lean reflux absorber, and lean vapor is recovered from the top of the lean reflux absorber. The liquid component, the first, major portion of the first vapor component, the liquid product from the bottom of the lean reflux absorber, and the lean vapor from the top of the lean reflux absorber are all fed to different feed points on a cryogenic distillation column. An optional cold side reboiler may be used to bring the cooling and heating curves into a more parallel relationship to improve process efficiency.

Lean reflux process for high recovery of ethane and heavier components

The present invention is directed to methods for separating and recovering propane, propylene and heavier hydrocarbons, i.e., the C.sub.3 + hydrocarbons, from a gas feed, e.g., raw natural gas or a refinery or petroleum plant gas stream. These methods employ sequentially configured first and second distillation columns, e.g., a de-methanizer tower followed by a de-ethanizer tower. A cooled gas feed condensate is separated in the first column into methane and a liquid phase comprising ethane and heavier hydrocarbons. The liquid phase is separated in the second column into a gas phase primarily comprising ethane and a second liquid phase primarily comprising the desired C.sub.3+ hydrocarbons. At least a portion of the second gas phase is introduced into the first distillation column as an overhead reflux to improve the separation of C.sub.3+ hydrocarbons. The methods of the present invention permit separation and recovery of more than about 99% of the C.sub.3+ hydrocarbons in the gas feed at higher operating pressures. Further, by cooling the second gas phase with a liquid condensed in a lower tray of the first column, significant capital and operating costs may be saved. By using the self refrigeration system, the need for external refrigeration is eliminated and the separation efficiency is improved in the first column. Accordingly, the processes of the present invention result in achieving higher liquid recovery levels with lower capital requirements and significant savings in operation.

Propane recovery methods

The present invention is directed to methods for improving the efficiency and economy of processes for the recovery of natural gas liquids (NGL) from a gas feed, e.g., raw natural gas or a refinery or petrochemical plant gas stream. These methods may be employed with most, if not all, conventional separation methods using a distillation tower, e.g., a demethanizer or deethanizer column. In the methods of the present invention, a portion of a hydrocarbon liquid condensed on a chimney tray disposed below the lowest feed tray of the column is withdrawn from the tower. This withdrawn liquid hydrocarbon is expanded and heated to produce a two-phase system for separation into a heavy, liquid hydrocarbon product and a vapor phase for recycle to the column, preferably as a stripping gas. The withdrawn hydrocarbon liquid is preferably heated by indirect heat exchange with the inlet gas, thus reducing or eliminating the external refrigeration requirements of the process. The expanded, heated vapor recycled to the column increases the ethane and propane concentration in the column, thus reducing the tray temperature profile and increasing the separation efficiency. Accordingly, the column may be operated at lower temperatures and higher pressures, resulting in significant energy savings and economies of operation.

Enhanced NGL recovery processes

A process for separating components of gas mixtures which have different hydrate forming characteristics which uses an aqueous liquid to absorb one of the gases preferentially by attaining conditions slightly above the catastrophic point at which gas hydrates form. Specifically, the separation of gas mixtures containing light hydrocarbons and carbon dioxide is accomplished without significantly reducing the pressure of the carbon dioxide or without requiring significant amounts of heat energy for regeneration.

Process for separating selected components from multi-component natural

Nitrogen and methane are separated in a nitrogen-methane cryogenic fractionator operating at a temperature between the boiling points of nitrogen and methane. A distillative aid or absorbent is injected into the nitrogen-methane cryogenic fractionator for enhancing separation, for enabling an increase in operating pressure, and for enabling a high separation rate at relatively high temperature.

Method and apparatus for purification of high N.sub.2 content gas

Disclosed is a method and apparatus for refrigeration utilizing a combined mechanical and absorption cycle. Two immiscible or only partly miscible refrigerants are mixed and evaporated in an evaporator to cool a process stream. The refrigerants are separated in an absorber which absorbs one of the refrigerants from the vapor mixture. The non-absorbed refrigerant vapor is compressed and condensed, while the absorbed refrigerant is desorbed and condensed to produce respective liquid refrigerant streams to the evaporator. Optionally the vapor mixture from the evaporator is compressed in a first stage of compression prior to passing to the absorber.

Refrigeration process and apparatus

Disclosed is a method and apparatus for separating and purifying carbon dioxide and natural gas contained in the associated gas of an oil well. Feed containing hydrocarbons, carbon dioxide, water and hydrogen sulfide, is fed to a stabilizer column where heavy hydrocarbons and water are removed. Hydrogen sulfide is then stripped from the gas in a carbon dioxide fractionator using a solvent which absorbs H.sub.2 S and increases the relative volatility of carbon dioxide to hydrogen sulfide. Overhead from the CO.sub.2 fractionator contains carbon dioxide and light hydrocarbons, which are then separated in a demethanizer column which produces liquid carbon dioxide as a bottoms product. The invention is particularly useful in recovering carbon dioxide from the associated gas of oil produced from enhanced oil recovery processes using carbon dioxide injection.

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Sugar Land, TX, United States of America

Jong Juh Chen