Lg Chem, Ltd

Lg Petrochemical Co., Ltd.

Jong-Hun Song

Jun-Han Kang

Jun-seon Choi

Byoung-gi Park

Si-hyun Noh

Chang-hoon Kang

Won-Ho Lee

Se-Won Baek

Sang-mun Jeong

Igor N Filimonov

Sul-Hee Yoo

Sang-Mun Jeong

This disclosure relates to a method of continuous recovery of (meth)acrylic acid and an apparatus used for the continuous recovery method. The continuous recovery method of (meth)acrylic acid according to the present invention may maintain a recovery rate of (meth)acrylic acid equivalent to that of the previous recovery method, and yet may significantly reduce energy consumption, and may minimize polymerization of (meth)acrylic acid in the recovery process, thus providing more improved operation stability.

Process for continuous recovering (meth)acrylic acid and apparatus for the process

A catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5&#x2266;j&#x2266;120, 0&#x2266;k&#x2266;50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.

Catalyst for hydrocarbon steam cracking, method of preparing the same and method of preparing olefin by using the same

The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5&#x2266;j&#x2266;120, 0&#x2266;k&#x2266;50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.

The present invention relates to an oxide catalyst and a phosphoric oxide catalyst for hydrocarbon steam cracking, method for preparing the same and a method for preparing olefin by using the same. More precisely, the present invention relates to an oxide catalyst for hydrocarbon steam cracking represented by formula 1 and a phosphoric oxide catalyst for hydrocarbon steam cracking represented by formula 3 which would be used for the production of olefin such as ethylene and propylene by hydrocarbon steam cracking, and a method for preparing the same. The present invention provides an oxide catalyst and a phosphoric oxide catalyst for hydrocarbon steam cracking that has excellent thermo-stability at high temperature and improved olefin yield.CrZrAO&#x2003;&#x2003;[Formula 1]CrZrAPO&#x2003;&#x2003;[Formula 3] Wherein, j, k, l and x are as indicated in the description.

Oxide catalyst and phosphoric oxide catalyst for hydrocarbon steam cracking, method for preparing the same and method for preparing olefin by using the same

The present invention relates to a hydrocarbon cracking catalyst and a method for preparing the same. The invention provides a hydrocarbon cracking catalyst in which a metal or a metal oxide is deposited only on the surface of zeolite and a method for preparing the hydrocarbon cracking catalyst comprising the steps of: a) dissolving a metal-hydrocarbon complex or an organometal larger than the pore size of a zeolite carrier; b) depositing the resultant solution on the zeolite surface; and c) drying and calcining the resultant zeolite catalyst. The hydrocarbon cracking catalyst of the invention can greatly improve production yield of olefins and aromatic compounds such as BTX.

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Daejeon, South Korea

Jong-Hun Song