Kennecott Corporation

The Carborundum Company

Kennecott Copper Corporation

Stemcor Corporation

Jonathan J Kim

Viswanathan Venkateswaran

Paul R Ammann

Thomas A Myles

Joel D Katz

Randolph Kujawa

Carl H McMurtry

Chih-Chung Wang

Francis J Frechette

Alan R Lebold

Bruce J Dover

Roger S Storm

Jagdish Chandra Agarwal

Peter B Crimes

Lewis M Koppel

Viswanathan Venkatswaren

Viswanathan Venksteswaran

Thomas A Loose

John F Elliott

Richard C Phoenix

A method for forming a polycrystalline ceramic fiber which comprises blending about 5 to about 25 weight percent polymer, about 70 to about 95 weight percent silicon carbide powder and greater than 1 weight percent sintering aid; forming a fiber from the blend; and sintering the formed fiber. Preferably, the sintering aid is boron carbide. In addition, the fiber is preferably pre-sintered at a first temperature of from about 1700.degree. C. to 2300.degree. C. and then subsequently sintered at a second temperature of approximately 2000.degree. C. to about 2300.degree. C.

Process for making silicon carbide ceramic fibers

A method of producing near net shape fusion cast refractories. The method includes the steps of continuously introducing refractory particles into a melting furnace, rapidly heating the particles, depositing the heated particles into a melt pool, continuously introducing the molten material into a mold, and continuously withdrawing a solidified body from the mold as the molten material continually solidifies. The above stated method produces a fusion cast refractory having a generally random, fine, uniform microstructure; uniform chemistry; and generally evenly distributed closed pores.

Method of producing near net shape fused cast refractories

A process for the manufacture of high purity, ultra-fine aluminum nitride powder by the carbo-nitridization of alumina. Agglomerates uniform in both size, chemical composition and porosity are formed containing a stoichiometric mixture of alumina and carbon with the addition of a small amount of catalyst. The agglomerates are furnaced in a controlled manner in a well-mixed reaction vessel to achieve a uniform and consistent level of conversion. Milling of the as-reacted agglomerates under a controlled atmosphere will produce high purity, micron sized aluminum nitride powder.

Process for the continuous production of high purity, ultra-fine,

A process and apparatus for the manufacture of high purity, ultra-fine aluminum nitride powder by the carbo-nitridization of alumina. In the method, agglomerates uniform in both size, chemical composition and porosity are formed containing a stoichiometric mixture of alumina and carbon, and a small amount of catalyst, and furnaced in a controlled manner in a well-mixed two chamber reaction vessel having optional top or bottom fluidizing gas feed to achieve a uniform and consistent level of conversion. Milling of the as-reacted agglomerates under a controlled atmosphere will produce high purity, micron sized aluminum nitride powder. The reactor is an automatically controlled fluid bed reactor for treatment of refractory materials with a hot fluidizing gas having a two chamber design in which the lower furnace chamber and reactor bed are removable from the bottom of the reactor. With unique reactor, unusually high reaction temperatures of up to 2000.degree. C. are obtainable. Further, the bottom removal feature allows for easy servicing of the reactor. Still further, the fluidizing gas may be introduced via a conduit and a bubble cap from above or below the reactor. If from below, wear on the conduit will be reduced because in such a configuration the conduit will not extend through the bed of the reactor. If the gas is introduced from above, the gas will be preheated by means of countercurrent heat flow, enabling more efficient operation of the reactor.

Apparatus for the continuous production of high ultra-fine, aluminum

Fused cast refractory moldings having a random microstructure, which are near in size and configuration to the desired final shape, and process and apparatus used in their manufacture are described. The process includes rapid melting of the refractory material followed by controlled rapid cooling. Laminated composite fused cast refractories may be produced.

Near net shape fused cast refractories and process for their manufacture

An anode for plasma torch that has a primary section and a secondary section with a gradual transition between the sections. The diameter of the hollow primary section tapers down toward a transition zone, at which point the anode formed by the sections makes a gradual transition to the secondary section. The secondary section is cylindrical and has a diameter larger than that of the primary section from which the plasma exists the anode. The transition zone will describe a generally conical surface and may include a convex radius on the neck where the primary and transition sections meet.

Anode for a plasma arc torch

A fluid bed reactor for treatment of refractory materials with a hot fluidizing gas and a method to use same. Both the refractory materials and the fluidizing gas are introduced from the top of the reactor. Unusually high reaction temperatures of up to 2000.degree. C. are maintained in the reaction chamber due to the presence of heating elements within the reactor and due to countercurrent heat transfer.

Method and apparatus to produce a hot fluidizing gas

A furnace for the sintering of refractory or ceramic materials using plasma heated gases. The furnace comprises a sintering chamber with strategic positioning of the plasma torch inlets and exhaust outlet, a furnace temperature controlling device during sintering so that the article being sintered does not decompose. The devices which can be used for controlling the temperature of the furnace during sintering include: (1) Tangential injection of a secondary colder gas stream into the hot primary plasma gas stream; (2) Utilization of a plasma torch or torches which can be temperature controlled to achieve stable and lower plasma gas temperatures; and (3) Introduction of a secondary cooler gas directly into the furnace sintering chamber.

Plasma heated sintering furnace

A system to prevent, retard or reverse the decomposition of silicon carbide articles during high temperature plasma sintering. Preferably, the system comprises sintering a silicon carbide refractory or ceramic green body in a closed sintering environment, such as a closed tube, with strategic placement of the plasma torch or torches, exhaust outlet and tube. As sintering proceeds, a silicon vapor pressure builds up within the tube, retarding the decomposition of the silicon carbide body. The plasma torch, exhaust outlet, and tubes are positioned so that buoyant convective flow is maximized to increase the heat transfer and energy efficiency. In another embodiment, a 'sacrificial' source of silicon carbide is placed into the sintering furnace. The silicon carbide in the sacrificial source starts to decompose before the silicon carbide refractory or ceramic article, creating a supersaturated atmosphere of silicon vapor species in the furnace. This prevents, retards or reverses the silicon carbide decomposition reactions and thus maintains the integrity of the refractory or ceramic article being sintered. Preferably, the sacrificial source is placed in a closed sintering environment along with the silicon carbide articles being sintered.

Method for preventing decomposition of silicon carbide articles during

A process for the sintering of silicon carbide refractory or ceramic articles using plasma arc gases. In the process of the invention, a formed silicon carbide article is heated in a plasma fired furnace to a sintering temperature of between 2000.degree. C.-2500.degree. C. at a heating rate of 300.degree. C./hr-2000.degree. C./hr, and held at the sintering temperature for 0.1-2 hours. The enthalpy of the plasma gas is 2000 BTU/lb-4000 BTU/lb, when nitrogen is used as the plasma gas. The total cycle time for the process of the invention, including cooling and loading, is 1.5-20 hours. Silicon carbide articles, produced in accordance with the invention, have high strength, high density, high corrosion resistance and high dimensional stability.

Plasma arc sintering of silicon carbide

An improved process for sintering extruded powder shapes comprising drying or calcining an extruded shape in a microwave furnace and rapid sintering the shape in a plasma fired furnace. Alternatively, calcining or drying may take place within a furnace heated by the plasma furnace's exhaust. The process of the invention is especially useful for silicon carbide extruded materials and for tubular shapes. This process significantly reduces sintering times and costs. Use of the process yields a high strength sintered product.

Process for sintering extruded powder shapes

A system to prevent, retard or reverse the decomposition of silicon carbide articles during high temperature plasma sintering. Preferably, the system comprises sintering a silicon carbide refractory or ceramic green body in a closed sintering environment, such as a covered crucible, with strategic placement of the plasma torch or torches, exhaust outlet and crucibles. As sintering proceeds, a silicon vapor pressure builds up within the crucible, retarding the decomposition of the silicon carbide body. The plasma torch, exhaust outlet, and crucibles are positioned so that buoyant convective flow is maximized to increase the heat transfer and energy efficiency. In another embodiment, a 'sacrificial' source of silicon carbide is placed into the sintering furnace. The silicon carbide in the sacrificial source starts to decompose before the silicon carbide refractory or ceramic article, creating a supersaturated atmosphere of silicon vapor species in the furnace. This prevents, retards or reverses the silicon carbide decomposition reactions and thus maintains the integrity of the refractory or ceramic article being sintered. Preferably, the sacrificial source is placed in a closed sintering environment along with the silicon carbide article being sintered.

System for preventing decomposition of silicon carbide articles during

A process for sintering or reaction sintering ceramic or refractory materials with hot plasma gases. The hot plasma gases are produced by injecting a combined primary plasma arc with a secondary gas stream directly into a reaction furnace. The secondary gas stream is tangentially injected into the primary plasma arc gas stream to mix the gases for the required sintering temperature at the highest energy efficiency. The plasma torches are positioned in the furnace ports so that the plasma gas flow is perpendicular to the furnace process gas flow. This process is inexpensive and efficient and results in a superior quality sintered product. It may be adapted to continuous or periodic kilns to achieve a high furnace productivity.

Sintering or reaction sintering process for ceramic or refractory

Molten molybdenum-copper-iron-sulfur mattes or alloys, obtained, for example, by reacting slags or other copper-molybdenum containing oxide residues or waste materials witn an iron and/or sulfide reductant, are enriched in molybdenum and copper by a pyrometallurgical process. The molten matte or alloy material is first carburized whereupon a copper-rich matte phase separates from the alloy phase and is removed. The molten alloy phase is next treated one or more times by the addition of sulfur or pyrite resulting in the formation of additional copper-rich matte as a separate phase which is separated after each treatment, leaving an alloy of molybdenum and iron of reduced Cu content. Finally the alloy is desulfurized to provide a commercial product.

Growing community of inventors

Williamsville, NY, United States of America

Jonathan J Kim