General Electric Company

Jonathan D Rich

Philip J McDermott

Peter P Policastro

Pamela K Hernandez

Thomas Link Guggenheim

Gary Charles Davis

Jeffrey H Wengrovius

Timothy Brydon Burnell

David C Gross

Terry E Krafft

James Anthony Cella

Sharon J McCormick

Alice M Colley

Connie L Haig

Karen A Regh

Daniel Joseph Brunelle

Larry Neil Lewis

Eugene Pauling Boden

Thomas L Evans

Thomas G Shannon

Luca P Fontana

Gary R Faler

Virginia M Van Valkenburgh

Joseph W Guiles

James M Fukuyama

Wan-Li Liu

Sandra A Swint

Tony C Chang

Siegfried H Schroeter, Deceased

The present invention is directed to solvent free particulated platinum group metal silicone resin catalyst resulting from the spray drying of an organic solvent mixture of a platinum group metal complex, and an alkenyl containing organosiloxane resin. Heat curable organopolysiloxane compositions containing such particulated platinum group metal silicone resin catalyst are also provided.

Particulated platinum group metal containing silicone resin catalyst,

Silicone-polycarbonate block copolymers are provided resulting from the reaction of certain siloxy aromatic imide siloxanes or hydroxyaromatic ester siloxanes which are made by effecting reaction between an organosiloxane having terminal aromatic anhydride groups or aromatic haloacyl groups which are each attached to silicon by silicon arylene linkages with an appropriate bishydroxyarylene compounds or hydroxyarylene amino compound. The aforementioned hydroxyaromatic imide siloxanes or hydroxyaromatic ester siloxanes are then phosgenated with a dihydric phenol or an aromatic bischloroformate. The silicone-polycarbonate block copolymers have been found to be flame retardant and useful as dielectric films and membranes, and as flame retardants in aromatic polycarbonates.

Hydroxyarylestersiloxanes

Silicon hydrides substituted with oxygen containing radicals such as alkoxy, can be silylformylated with alkynes and carbon monoxide in the presence of a rhodium catalyst to produce silyl alkenyl acetals. The silyl alkenyl acetals are useful as plasticizers for organosilicon copolymers.

Method for silylformylating alkynes and products obtained therefrom

Silicone copolymers, such as silicone polyimides, silicone polyamides silicone polyesters and silicone polycarbonates are provided having condensed tetraorganodisiloxy groups. These silicone copolymers and anhydride or acylaromatic organic terminated intermediates are crosslinkable by heat or electron beam radiation.

Silicone copolymers having tetraorganodisilyloxy groups and

Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.

Macrocyclic oligomers containing spiro(bis)indane moietes

A moisture curable solventless organopolysiloxane composition is provided useful as an adherent construction sealant. Improved cure rate, higher elongation at break values and lower modulus RTVs are achieved by using a bis(ureido)silane as a coupler and an aminoxysiloxane as a crosslinker for a silanol-terminated polydiorganosiloxane base polymer.

RTV silicones having bis(ureido)silane chain extenders and aminoxy

An improved method for making biaryl compounds is disclosed, in which an aromatic acid halide having at least one strong electron-withdrawing group attached to or within the aromatic ring is reacted with at least one polysilane in the presence of an effective amount of a transition metal catalyst.

Method for preparing biaryl compounds

Linear polyamide and polyimide copolysiloxane compositions are prepared by contacting a strongly acidic catalyst, basic catalyst or alkali metal fluoride with a macrocyclic spirobiindane polyamide or polyimide disiloxane, either alone or in combination with a cyclic polysiloxane such as octamethylcyclotetrasiloxane.

Spiro(bis)indane polyamide and polyimide copolysiloxanes and method of

There is provided by the present invention aromatic polyester-siloxane block copolymers which can be made by effecting the condensation between tetramethyldisiloxane bisbenzoic acid or acid chloride with a dihydric phenol such as bisphenol A or in combination with a mixture of such tetramethyldisiloxane bisbenzoic acid and aromatic acids, such as terephthalic acid or isophthalic acid. The aromatic polyester-siloxane block copolymers can be used as molding compounds, extruded films, in making composite matrix materials and as flame retardants for aromatic polycarbonates.

Aromatic polyester-siloxane block copolymers and method for making

Silicone-polycarbonate block copolymers

Silicone foams are provided which have increased tensile strength as the result of using an effective amount of a silicone polyimide block copolymer having chemically combined organovinylsiloxy units in the silicone block.

High strength silicone foam, and methods for making

A method is provided for silylating aromatic acylhalide by effecting reaction between an aromatic acylhalide and halogenated polysilane in the presence of an effective amount of a supported transition metal catalyst, such as a transition metal catalyst supported by an organic or inorganic substrate.

Silylation method

Flame retardant aromatic polycarbonate compositions are provided resulting from the use of certain poly(arylene silicon) materials in combination with aromatic polycarbonates. Included among the poly(arylene silicon) materials are aromatic polyester silioxanes, aromatic polyimide siloxanes and aromatic polysilphenylenes.

Flame retardant aromatic polycarbonate blends

Polyimidesiloxane coating compositions resulting from the intercondensation in the presence of methylanisole of various dianhydrides such as 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]-propane dianhydride or bis(phthalicanhydride)tetramethyldisiloxane, or mixtures thereof with organic diamine such as toluenediamine, aminoalkyl terminated polydimethylsiloxane or oxydianiline.

Growing community of inventors

Rexford, NY, United States of America

Jonathan D Rich