Iowa State University Research Foundation, Inc.

Northwestern University

Brigham Young University

Jonathan Claussen

Suprem Das

John Hondred

Mark C Hersam

Brian D Iverson

Kshama Parate

Loreen Stromberg

Sonal V Rangnekar

Methods and systems of fabrication of high resolution, high-throughput electrochemical sensing circuits on a substrate. High resolution electrochemical sensing circuits are printed by an effective additive technique to the substrate. Optionally, post-print annealing converts electrochemically inactive printed graphene into one that is electrochemically active. The printing can be by aerosol jet printing, but is not necessarily limited thereto. An example is inkjet printing and then the post-print annealing. Ink formulation would be adjusted for effectiveness with inkjet printing. Optionally biorecognition agents can be covalently bonded to the printed graphene for the purpose of electrochemical biosensing. High throughput fabrication of high-resolution graphene circuits (feature sizes in the tens of microns <50 μm) for electrochemical biosensing is possible by chemical functionalization of the graphene surface with a biological agent.

Aerosol jet printed flexible graphene circuits for electrochemical sensing and biosensing

An apparatus, method, and system for post-processing a printed graphene ink pattern or other deposition on a substrate. A pulsed UV laser is tunable between various energy densities to selectively modify the printed ink or deposition in electrical or physical properties. In one example, radical improvements in electrical conductivity are achieved. In another example, controlled transformation from essentially 2D printed or deposited graphene to surface topology of 3D nanostructures are achieved. The 3D structures are beneficial in such applications as electrochemical sensors of different types and characteristics. In another example, hydrophobicity of the printed or deposited graphene can be manipulated starting from a hydrophilic to super hydrophobic surface.

Tunable nano-structured inkjet printed graphene via UV pulsed-laser irradiation for electrochemical sensing

The invention relates to a method of patterning a substrate with graphene-based or other electroactive-material-based solution that includes solid-phase particles as hard templates, reducing the solution, and processing the reduced solution to expose the particles. The exposed hard template particles are removed to leave a three-dimensional (3D) porous architecture that can be beneficially used for a variety of applications, including but not limited to bio sensors and supercapacitors. In one example, the exposure is by etching with a COlaser. The method can be practiced with scalable MEMS fabrication technologies.

Enhanced 3D porous architectured electroactive devices via impregnated porogens

In a general aspect, an apparatus can include a first carbon nanotube array that is patterned to define a first electrode having a first plurality of electrode segments. The apparatus can also include a second carbon nanotube array that is patterned to define a second electrode having a second plurality of electrode segments. The second plurality of electrode segments can be interdigitated with the first plurality of electrode segments. The apparatus can further include a biorecognition agent disposed on a surface of the first electrode and disposed on a surface of the second electrode. The first plurality of electrode segments can each have a height-to-width aspect ratio of at least 1 to 1.

Electrochemical immunosensors

Methods, systems, and compositions to produce high resolution, highly scalable patterns on a variety of substrates. A high resolution sacrificial negative of the desired pattern in inkjet printed on the substrate with an inkjet printable ink. A viscous solution is coated or deposited over the negative pattern and substrate. The solution is stabilized such as by drying and adheres to the substrate. The sacrificial negative is removed, leaving the dried solution in the high resolution form factor defined by the removed negative. This allows the solution to be formulated without regard to meeting inkjet printing requirements but results in a high resolution final positive pattern on the substrate.

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Ames, IA, United States of America

Jonathan Claussen