Kellogg Brown + Root LLC

Jon C Moretta

Murugesan Subramanian

Michael A Silverman

Raymond H Floyd

Harold D Sloan

Jim Yuen-Fong Low

Aldrich Holt Northup, Jr

Tayseer Abdel-Halim

Robert A Robinson

Chris W Taylor

Cameron O Olson

Pankaj M Shah

Disclosed is a pelletizer vessel and a prilling head assembly for use in the pelletizer vessel for prilling a hard resid material. The pellitizer vessel has an has an upright pelletizing vessel with an upper prilling zone, a sphere-forming zone below the prilling zone, a cooling zone below the sphere-forming zone, a bath below the cooling zone, and a prilling head in the prilling zone rotatable along a vertical axis and having a plurality of discharge orifices for throwing molten material radially outwardly. A vertical height of the sphere-forming zone is sufficient to allow material discharged from the prilling head to form substantially spherical liquid pellets. Nozzles are provided for spraying water inwardly into the cooling zone to cool and at least partially solidify the liquid pellets to be collected in the bath. The prilling head assembly has a a feed inlet to allow for the introduction of resid material, rotary union with a fluid tight seal, a rotatable pipe to convey a resid material to the prilling head, a drive wheel to provide rotation to the rotatable pipe, a support housing having a mount for attachment to the pellitizer vessel, and a prilling head with a flow passage in fluid communication with the rotatable pipe and radially offset orifices. Bearings are provided for stablizing and guiding the rotatable pipe. Inert gas is introduced into the annular spaces of the support housing to prohibit foreign matter.

Prilling head assembly for pelletizer vessel

Disclosed are an integrated process and plant for slurrying and gasification or combustion of a petroleum resid such as asphaltenes from to make a synthesis gas or steam and/or power. The resid is prilled into a gaseous medium as a liquid with a rotating prilling head to form particles which form into a spherical shape. The liquid particles are directly quenched with a water spray to form a slurry of resid particles in water. The slurry comprises a solids loading of 50 to 80 percent and can also include a minor amount of a dispersant.

Pelletization of petroleum resids

The invention is a process for making anode grade coke which comprises solvent deasphalting a residue feedstock to obtain an essentially asphaltene-free, resin-containing stream and coking the resin-containing stream in a delayed coker to make anode coke. The solvent deasphalting can make a deasphalted oil stream containing resin or separate deasphalted oil and resin streams. There can be hydrotreating of (1) a minor portion of the residue feedstock wherein the hydrotreated residue is fed to the delayed coker with the resin-containing stream, (2) the resin-containing stream wherein the hydrotreated resin stream is fed to the delayed coker, or (3) a major portion of the residue feedstock wherein the hydrotreated residue is fed to the solvent deasphalting unit.

Anode grade coke production

Disclosed are a method and apparatus for making substantially spherical, homogenous petroleum resid pellets having a size range between 0.1 and 10 mm, a penetration of essentially 0, a softening point temperature from about 200&deg; to about 400&deg; F., a residual water content of from 0.1 to 10 weight percent, and a sulfur content less than 10 weight percent. The process includes feeding the material in a molten state to a rotating prilling head to discharge the material into free space at an upper end of a pelletizing vessel having a diameter larger than a throw-away diameter of the discharged material, allowing the discharged material to break apart, form into substantially spherical liquid pellets, and fall downwardly into a liquid spray and/or bath to solidify the pellets. The apparatus has an upright pelletizing vessel with an upper prilling zone, a sphere-forming zone below the prilling zone, a cooling zone below the sphere-forming zone, a bath below the cooling zone, and a prilling head in the prilling zone rotatable along a vertical axis and having a plurality of discharge orifices for throwing molten material radially outwardly. A vertical height of the sphere-forming zone is sufficient to allow material discharged from the prilling head to form substantially spherical liquid pellets. Nozzles are provided for spraying water inwardly into the cooling zone to cool and at least partially solidify the liquid pellets to be collected in the bath. Also disclosed is pretreatment of a soft resid (softening point temperature below 200&deg; F.) by air oxidation to produce a hard resid suitable for feed to the prilling head.

Petroleum resid pelletization

Growing community of inventors

Northbrook, IL, United States of America

Jon C Moretta