The Dow Chemical Company

Johnny Chavez, Jr

Raymond A Plepys

Van A Kent

Hans R Friedli

Vaughn M Nace

Paul D Bettge

Randall K Whitmire

Craig A McClure

Richard N Gerstle

Andrew S Farnum

The concentration of propenyl ethers in a hydroxy-functional polyether having oxypropylene units is reduced by a process including the step of contacting the polyether with an acid ion exchange resin for a time and at a temperature sufficient for the conversion of at least some of the propenyl ethers to propionaldehyde and in the presence of sufficient water for the conversion. Optionally, the polyether is treated with an epoxy compound in an amount sufficient to reduce the acidity of the polyol.

Purified hydroxy-functional polyether compounds

A process for reducing the amount of propenyl polyethers in hydroxy-functional polyethers comprising (1) contacting a neutral hydroxy-functional polyether, containing a propenyl polyether and water, and an acid catalyst soluble in the hydroxy-functional polyether under reaction conditions sufficient to convert at least a portion of the propenyl polyether to propionaldehyde; (2) contacting the product of step (1) and an epoxy compound to substantially scavenge the acid catalyst; and (3) stripping the product of step (2) to substantially remove the epoxy compound the the propionaldehyde. The resulting hydroxy-functional polyethers contain reduced amounts of propenyl polyethers and can therefore be used to prepare polyurethane foams having a reduced tendency to discoloration.

Process to reduce propenyl polyethers in hydroxyfunctional polyethers

Growing community of inventors

Lake Jackson, TX, United States of America

Johnny Chavez, Jr