Ecolab USA Inc.

John Wilhelm Bolduc

Junzhong Li

Robert J Ryther

Peter J Fernholz

David D McSherry

Richard K Staub

Catherine Hanson

Allison Brewster

Victor V Keasler

Chris Nagel

Renato De Paula

Eugene Tokhtuev

Anatoly Skirda

Anna Pilipchenko

Justin Scott Valenstein

Michael E Besse

Paul R Kraus

Paul Frazer Schacht

Anthony Wayne Erickson

Jeffrey S Hutchison

Stacy Fawbush

Amanda Bakken

Eric Victor Schmidt

Blake Roberts Otting

David Mcsherry

Jeffrey Hutchison

David D Mcsherry

Alison Brewster

Robert Ryther

Peroxyformic acid compositions for removal of biofilm growth and other contaminants and impurities from industrial processing hard surfaces are disclosed. In particular, peroxyformic acid compositions may be dosed on site and/or generated in situ for the reduction and prevention of biofilms on the hard surfaces. Methods of employing the peroxyformic acid compositions for removal of biofilm growth and other impurities such as aldehydes and alcohols from industrial COeffluent are also disclosed which beneficially provide ambient biofilm control and break down more rapidly than other peracids, allowing for extended runs between CIP cleaning, including a reduction and/or elimination of cleaning of the scrubbers and other industrial surfaces.

Performic acid biofilm prevention for industrial COscrubbers

The present invention relates generally to stable percarboxylic acid compositions comprising, inter alia, at least two stabilizing agents, and various uses for water treatments, including water treatments in connection with oil- and gas-field operations. The present invention also relates to slick water compositions and gel based compositions that comprise stable percarboxylic acid compositions and the use thereof in oil- and gas-field operations.

Stable percarboxylic acid compositions and uses thereof

Systems for quantifying one or more target analyte concentrations in a process solution are provided and can be used, for example, in methods for quantifying a target analyte concentration. These systems and methods include continuous and batchwise automated titration methods that use titration chemistries to measure the target analyte concentration in the process solution using a multiwavelength detector. The methods provide for efficient and robust automated titration methods for a variety of target analytes and can include methods that analyze more than one analyte and that provide for a dynamic range for measurement of more than one target analyte concentration.

Methods for colorimetric endpoint detection and multiple analyte titration systems

[object Object]

A method of detecting concentration of dipicolinic acid and terbium chloride in a chemical composition with a fluorometer, wherein the fluorometer comprises an excitation source for emitting electromagnetic radiation at one or more wavelengths, and a detector module for detecting fluorescence emitted by dipicolinic acid, emitting electromagnetic radiation from the excitation source at wavelengths that induce fluorescence in dipicolinic acid-terbium chloride combination present in the chemical composition, detecting the fluorescence emitted by the dipicolinic acid-terbium chloride combination via the detector module, and determining the concentration of dipicolinic acid using predetermined relationship between fluorescence emitted and the concentration of dipicolinic acid-terbium chloride combination.

Handheld fluorometer

A method of fluorometrically detecting the concentration of chemical components in oxidizing formulations is disclosed. In a particular embodiment the detection is of the stabilizing component of picolinic acid, present in such formulations, although any component which fluoresces may be detected. According to the invention sample preparation of the oxidizing formulation includes adding to said sample an excess of reducing agent to bind peracid, and in the case of picolinic acid, adding to said sample an excess of terbium chloride. The sample then is subjected to radiation to induce fluorescence and the concentration of said chemical component is determined by a linear relationship between fluorescence emitted and the concentration of the target chemical.

Fluorescence assay for quantification of picolinate and other compounds in oxidizers and oxidizing compositions

A fluorometer for measuring fluorescence of a sample includes an excitation source for emitting electromagnetic radiation along a first beam path to induce fluorescence in the sample. An excitation filter transmits electromagnetic radiation from the excitation source toward the sample. An excitation filter holder supports the excitation filter and defines an aperture for passage of electromagnetic radiation from the excitation source. The aperture is positioned asymmetrically relative to the first beam path such that the aperture allows an asymmetrical portion of the electromagnetic radiation in the first beam path to pass toward the sample and the excitation filter holder blocks passage of a corresponding asymmetrical portion of the electromagnetic radiation in the first beam path. The blocked passage of the corresponding asymmetrical portion of the electromagnetic radiation in the first beam path reduces the amount of electromagnetic radiation oriented directly from the emitter module to the detector module.

A system and method for performing automated titrations. An automatic titrator utilizes control devices and sensors adapted for various chemical reactions to perform titrations and determine the content of a desired component of a solution. Batch and continuous mode titrations are possible. Titrant is added to a sample either in varying amounts or rates and a titration endpoint is observed via sensors. Control devices detect when the titration endpoint occurs and calculates the desired content. Various reactions within the solution may be suppressed in order to titrate isolated components individually.

Automatic titrator

The present invention relates to compositions of peracids, such as peroxycarboxylic acids, having improved antimicrobial efficacy due to ethanol solubilization of the compositions. The enhanced antimicrobial efficacy of the peracid compositions beneficially have a lower use concentration. The invention further relates to methods employing such compositions.

Enhanced microbial peracid compositions and methods of use at reduced temperatures in aseptic cleaning

The present invention relates to methods for removing or preventing scale formation in a liquid food processing operation. The present invention also relates to methods and compositions for increasing the solubility of insoluble calcium salts in an acidic environment. Aqueous antiscalant solutions comprising soluble magnesium salts are used to prevent the precipitation of insoluble calcium salts and/or to increase the solubility of insoluble calcium salts.

MG++ chemistry and method for fouling inhibition in heat processing of liquid foods and industrial processes

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Eagan, MN, United States of America

John Wilhelm Bolduc