Calspan Corporation

Other

John W Raymonda

Howard P Groger

William F Sullivan

K Peter Lo

Joseph W Rich

Myron T Coolbaugh

Roger L Reynolds

John W Daiber

An instrument for total internal reflection fluorescence spectroscopy having modular probe that inexpensively monitors vapors and liquid-phase analytes under field conditions is described. The system is particularly helpful in evaluating multiple analytes using the fluorescence of a material immobilized in a thin sorbent polymer coating. At the same time, the system is capable of monitoring trace quantities of analyte using a fluorescence-read immunological reaction. The device includes a diode laser source, a shaped optical element (which may be as simple as a microscope slide), and one or more amplified photodiode detectors. The shaped optical element propagates light from the diode laser in a series of internally reflective bounces.

Modular probe for total internal reflection fluorescence spectroscopy

The generation of visible or ultraviolet chemical laser radiation is achieved by the vapor phase combustion of metal atoms. The vapor is formed in a precombustor and metal vapor is extracted from the precombustor and fed via a supersonic nozzle to the laser cavity where it is reacted with an oxidant to produce excited molecules and thereby lasing.

Method and apparatus for the continuous generation of metal vapor

Laser radiation is employed to initiate and promote chemical reactions by creating states of molecular vibrational mode excitation exceeding those appropriate to the translational temperature of the medium in one or more of the reactants. In favorable cases, vibrational excitation in a certain vibrational normal mode of a reactant will act to accelerate the rate of a desired chemical reaction. The reactants can be pressurized so that their vibration-rotation spectrum can be broadened to the point that laser radiation can be absorbed without the need for exact coincidence between a line or lines of the spectrum of the reactant and that of available lasers. Provision can be made for isolation and analysis of products, recycling of unused reactants, temperature control of reactants and real-time monitoring of the state of vibrational excitation of the reactants.

Method and apparatus for the initiation of chemical reactions

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Williamsville, NY, United States of America

John W Raymonda