Ruhrchemie Aktiengesellschaft

Hoechst Aktiengesellschaft

Ruhrchemie Aktiengesellachaft

John V Hobes

Wolfgang Payer

Werner Reimann

Wilhelm Zoller

Detlef Deymann

Walter Spaleck

Hermann Morguet

Boy Cornils

Michael Feustel

Roland Bohm

Ludger Bexten

Karl Heinz Heier

Mufit Bahadir

Winfried Materne

Christiane Barth

Karl H Heier

Copolymers of ethylene, a vinyl ester of a tertiary saturated monocarboxylic acid and optionally a further monomer, and a process for making them. The copolymers are suitable for producing films of high mechanical strength and excellent optical properties.

Copolymers of ethylene

A graft polymer based on an ultrahigh molecular weight polyethylene having a molecular weight of at least 1,000,000 g/mol and an alkenecarboxylic acid or alkenecarboxylic anhydride as the graft monomer; the polymer has modified and improved properties compared with ultrahigh molecular weight polyethylene. The preparation and use thereof are also described.

Graft polymer based on ultrahigh molecular weight polyethylene

Terpolymers which are copolymers of ethylene, vinyl acetate, and vinyl neononanoate or vinyl neodecanoate, a process for their preparation, and a method of their use as additives for mineral oil distillates.

Terpolymers of ethylene, their preparation, and their use as additives

A graft copolymer based on ultrahigh-molecular-weight polyethylene having a molecular weight .gtoreq. 1,000,000 g/mol, an ethylene copolymer and a graft monomer; and the preparation and use thereof. The ethylene copolymer contains ethylene and vinyl acetate or ethylene and an alkenecarboxylic acid ester. The graft monomer is an alkenecarboxylic acid or an alkenecarboxylic anhydride. The resultant graft polymers posses improved properties compared with the materials from which they are derived.

Graft copolymer based on an ultrahigh-molecular-weight polyethylene and

For the preparation of copolymers of ethylene, ethylene is polymerized with esters of vinyl alcohol in the absence of solvents and emulsifiers and in the presence of free radical acceptors. The addition of free radical acceptors makes it possible to increase the polymerization temperature in comparison to a procedure without the use of free radical acceptors.

Process for the preparation of ethylene/vinyl ester copolymers

Novel copolymers of ethylene containing per 100 parts by weight ethylene 0.2 to 5.0 parts by weight of 2,4,4-trimethylpentene-(1) and optionally 2.0 to 20 parts by weight of vinyl ester or vinyl ether or ester of acrylic acid or methacrylic acid with alcohols of 1 to 8 carbon atoms having a melt index MFI (190/2.16) of 0.4 to 20 g/10 min. a density of 0.915 to 0.960 g/ml and an impact tensile strength of 850 to 2,600 mJ/mm.sup.2 and a process for their preparation useful for making transparent films.

Copolymers of ethylene and 2,4,4-trimethylpentene-1

Waxy highly branched copolymers having a molecular weight of 500 to 20,000 comprised of at least 60% by weight of ethylene, 1 to 39% by weight of an alkene carboxylic acid ester and/or a vinyl ester and 1-30% by weight of a vinyl ketone produced by polymerization at 100 to 350.degree. C. and a pressure of about 1,000 to 8,000 bar in the presence of a radical forming initiator and in the absence of a solvent useful as oil additives to improve flow characteristics of crude oils and middle distillates derived from crude oil.

Ethylene copolymers

The homo- or copolymerization of ethylene at temperatures of 150.degree. C. to 350.degree. C. and pressures of 300 to 3500 bar is carried out in the presence of catalysts having an organometallic compound of a metal of Group III of the Periodic Table of the Elements and a titanium compound. The titanium compound is the reaction product of (a) a titanic acid ester and (b) the product of the reaction of a magnesium alcoholate and a halogen-containing aluminum alkyl compound.

Process for the homo- and copolymerization of ethylene

A process for improving the flow properties of mineral oils by adding a copolymer consisting of from 66 to 99.9 weight % of ethylene and of from 0.1 to 40 weight % of vinylic acid amide and optionally of further comonomers.

Process for improving the flow properties of mineral oils

The invention relates to the preparation of free-flowing homopolymer and copolymer waxes by heating the solid or molten waxes in aqueous ammonia solution.

Process for preparing free-flowing ethylene homopolymers or copolymer

The present invention relates to the stabilization of a carbonaceous combustible solid-diesel fuel suspension by inclusion therein of wax-like polymers in an amount of at least 0.2% by weight of the stabilized suspension. The polymers preferred are homopolymers of .alpha. -olefins, and copolymers of ethylene and at least one other monomer copolymerizable therewith wherein the ethylene portion constitutes at least 60% by weight of the copolymer.

Coal/diesel fuel suspensions containing wax-like polymers

A process for preparing pulverulent ethylene homopolymers or copolymers with a grain size of less than 200 .mu.m which comprises contacting coarse-particled ethylene homopolymers or copolymers in the form of a suspension with an aliphatic ketone containing 3 to 10 carbon atoms, heating the same with a mixture of said ketone up to a temperature above the softening point of the polymer and thereafter cooling the same.

Process for preparing pulverulent ethylene polymers

A foamable copolymer comprising 40 to 98 percent by weight units of ethylene, 1 to 30 weight percent units of vinyl alcohol, 1 to 30 weight percent units of acrylic acid ester of a secondary or tertiary alcohol, and up to 2 percent by weight of vinyl acetate units is described together with a process for the manufacture thereof. The same is useful in the formation of a foamed mass which is relatively highly cross-linked. The copolymer can be foamed to form a foam by heating the same at 250.degree. to 350.degree. C. for 5 to 60 minutes in the absence of oxygen.

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Dinslaken, Germany

John V Hobes